9-(3-(9H-carbazol-9-yl)phenyl)-9H-pyrido[2,3-b]indole | 1443781-83-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-(3-(9H-carbazol-9-yl)phenyl)-9H-pyrido[2,3-b]indole
• 英文别名: 9-(3-Carbazol-9-ylphenyl)pyrido[2,3-b]indole
• CAS: 1443781-83-6
• 化学式: C₂₉H₁₉N₃
• 分子量: 409.49
• InChiKey: AAGNRRFWBQTTFW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  32
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  22.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-氨基-3-溴吡啶 在 potassium phosphate 、 copper(l) iodide 、 C₂₆H₃₅P 、 trans-1,2-Diaminocyclohexane 、 palladium diacetate 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 、 4,5-双二苯基膦-9,9-二甲基氧杂蒽 、 sodium t-butanolate 作用下， 以 1,4-二氧六环 、 N,N-二甲基乙酰胺 、 叔丁醇 为溶剂， 反应 36.0h， 生成 9-(3-(9H-carbazol-9-yl)phenyl)-9H-pyrido[2,3-b]indole
  参考文献：
  名称：

  Effect of the position of nitrogen in pyridoindole on photophysical properties and device performances of α-, β-, γ-carboline based high triplet energy host materials for deep blue devices

  摘要：

  研究人员合成了吡啶吲哚单元不同位置含氮的三种咔啉衍生物，并研究了氮的位置对光物理性质和器件性能的影响。δ-咔啉能有效获得高三重能并稳定能级，而δ-±-咔啉在量子效率方面优于其他咔啉。然而，δ-咔啉不能稳定 LUMO 电平，获得的量子效率较低。

  DOI：

  10.1039/c3cc42131g

文献信息

• Novel Organic Semiconductors Based on Phenyl and Phenylthienyl Derivatives for Organic Thin-Film Transistors
  作者：Eunsoo Lee、Bodakuntla Thirupathaiah、Jaeuk Han、Dahae Jung、Guhyun Kwon、Choongik Kim、SungYong Seo

  DOI：10.1166/jnn.2016.10748

  日期：2016.1.1

  New phenyl and phenylthienyl derivatives end-functionalized with carbazole and a-carboline, 9-(4(9-H-carbazol-9-yl)phenyl)-9H-carbazole, 9-(4-(9H-carbazol-9-yl)phenyl)-9H-pyrido[2,3-b]indole, 9(3-(9H-carbazol-9-yl)pheny1)-9H-carbazole, 9-(3-(9H-carbazol-9-yl)pheny1)-9H-pyrido[2,3-b]indole, 9-(4-(5-(9H-carbazol-9-yl)thiophen-2-yl)phenyl)-9H-carbazole, and 9-(3-(5-(9H-carbazol-9-yl) thiophen-2-yl)phenyl)-9H-carbazole were synthesized and characterized as organic semiconductors for organic thin-film transistors (OTFTs). Most compounds exhibited p-channel characteristics with carrier mobility as high as 1.7 x 10(-5) cm(2)Ns and a current on/off ratio of 10(2)-10(4) for top-contact/bottom-gate OTFT devices.
• LUMINESCENT MATERIAL FOR DELAYED FLUORESCENCE AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME
  申请人：Rohm and Haas Electronic Materials Korea Ltd.

  公开号：US20180190912A1

  公开（公告）日：2018-07-05

  The present invention relates to a luminescent material for delayed fluorescence and an organic electroluminescent device comprising the same. By using the luminescent material for delayed fluorescence according to the present invention, an organic electroluminescent device having long lifespan, low driving voltage, excellent color purity, and significantly improved luminous efficiency such as current efficiency is provided.
• [EN] LUMINESCENT MATERIAL FOR DELAYED FLUORESCENCE AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME<br/>[FR] MATÉRIAU LUMINESCENT POUR FLUORESCENCE RETARDÉE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE COMPRENANT CE DERNIER
  申请人：ROHM & HAAS ELECT MATERIALS KOREA LTD

  公开号：WO2017014546A1

  公开（公告）日：2017-01-26

  The present invention relates to a luminescent material for delayed fluorescence and an organic electroluminescent device comprising the same. By using the luminescent material for delayed fluorescence according to the present invention, an organic electroluminescent device having long lifespan, low driving voltage, excellent color purity, and significantly improved luminous efficiency such as current efficiency is provided.