2-(2-(4-(2-(4-(4-nitro-2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)phenyl)propan-2-yl)phenoxy)-5-nitrophenyl)-4,5-diphenyl-1H-imidazole | 1241047-48-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(2-(4-(2-(4-(4-nitro-2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)phenyl)propan-2-yl)phenoxy)-5-nitrophenyl)-4,5-diphenyl-1H-imidazole
• CAS: 1241047-48-2
• 化学式: C₅₇H₄₂N₆O₆
• 分子量: 906.997
• InChiKey: JXEWMRLFXIQDPN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.86
• 重原子数：
  69.0
• 可旋转键数：
  14.0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  162.1
• 氢给体数：
  2.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  2-(2-(4-(2-(4-(4-nitro-2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)phenyl)propan-2-yl)phenoxy)-5-nitrophenyl)-4,5-diphenyl-1H-imidazole 在 palladium 10% on activated carbon 、 一水合肼 作用下， 以 乙醇 为溶剂， 反应 5.0h， 以88%的产率得到4-(4-(2-(4-(4-amino-2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)phenyl)propan-2-yl)phenoxy)-3-(4,5-diphenyl-1H-imidazol-2-yl)benzenamine
  参考文献：
  名称：

  Synthesis and identification of organosoluble polyamides bearing a triaryl imidazole pendent: Thermal, photophysical, chemiluminescent, and electrochemical characterization with a modified carbon nanotube electrode

  摘要：

  A novel monomer containing a triaryl imidazole pendent group was successfully synthesized by nucleophilic substitution of bisphenol A with 2-(2-chloro-5-nitrophenyl)-4,5-diphenyl-1H-imidazole (I). A series of new polyamides (PAs) with inherent viscosities of 0.95-1.2 dL/g was prepared by direct polycondensation of the diamine with various dicarboxylic acids. These PAs were readily soluble in many organic solvents and gave tough and flexible films by solution casting. These PM exhibited T(g)s between 189 degrees C and 252 degrees C, and 10% weight loss temperatures in excess of 400 degrees C with up to 68% char yield at 600 degrees C in air. All of the PAs emitted a greenish-yellow light in dilute THF solution, with photoluminescence (PL) quantum yields in the range of 10-25%. The chemiluminescent activity and electrochemical oxidation of the PAs were also investigated. (c) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2010.02.004
• 作为产物：
  描述：

  联苯甲酰 在 ammonium acetate 、 potassium carbonate 、 溶剂黄146 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 36.0h， 生成 2-(2-(4-(2-(4-(4-nitro-2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)phenyl)propan-2-yl)phenoxy)-5-nitrophenyl)-4,5-diphenyl-1H-imidazole
  参考文献：
  名称：

  Synthesis and identification of organosoluble polyamides bearing a triaryl imidazole pendent: Thermal, photophysical, chemiluminescent, and electrochemical characterization with a modified carbon nanotube electrode

  摘要：

  A novel monomer containing a triaryl imidazole pendent group was successfully synthesized by nucleophilic substitution of bisphenol A with 2-(2-chloro-5-nitrophenyl)-4,5-diphenyl-1H-imidazole (I). A series of new polyamides (PAs) with inherent viscosities of 0.95-1.2 dL/g was prepared by direct polycondensation of the diamine with various dicarboxylic acids. These PAs were readily soluble in many organic solvents and gave tough and flexible films by solution casting. These PM exhibited T(g)s between 189 degrees C and 252 degrees C, and 10% weight loss temperatures in excess of 400 degrees C with up to 68% char yield at 600 degrees C in air. All of the PAs emitted a greenish-yellow light in dilute THF solution, with photoluminescence (PL) quantum yields in the range of 10-25%. The chemiluminescent activity and electrochemical oxidation of the PAs were also investigated. (c) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2010.02.004