1-(4-Hydroxy-3,5-dimethoxyphenyl)-2-methyl-1-propanone | 1092101-56-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(4-Hydroxy-3,5-dimethoxyphenyl)-2-methyl-1-propanone
• 英文别名: 1-(4-hydroxy-3,5-dimethoxyphenyl)-2-methylpropan-1-one
• CAS: 1092101-56-8
• 化学式: C₁₂H₁₆O₄
• 分子量: 224.257
• InChiKey: FGSJHFZWJMRCTE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,1,1-trifluoro-N-(1-(4-((1-(4-hydroxy-3,5-dimethoxyphenyl)-2-methylprop-1-en-1-yl)oxy)-3,5-dimethoxyphenyl)-2-methylprop-1-en-1-yl)-N-phenylmethanesulfonamide 在 盐酸 作用下， 以 甲醇 为溶剂， 反应 0.25h， 以89%的产率得到1-(4-Hydroxy-3,5-dimethoxyphenyl)-2-methyl-1-propanone
  参考文献：
  名称：

  The Brosimum Allene: A Structural Revision

  摘要：

  Insight derived from a synthetic model, calculated C-13 NMR data, and comparison to experimental data indicate that the proposed allenic structure A, originally assigned to an isolate from Brosimum acutifolium Huber, should be revised to B, a natural product and nonallenic substance, mururin C.

  DOI：

  10.1021/ol802338z

文献信息

• METHOD FOR TIERED PRODUCTION OF BIOBASED CHEMICALS AND BIOFUELS FROM LIGNIN
  申请人：Peterson John R.

  公开号：US20130232852A1

  公开（公告）日：2013-09-12

  The present invention is directed generally to a method of production of value-added, biobased chemicals from lignin sources, including waste lignin. A method of using a depolymerization of lignin to create a tiered production of biobased aromatic chemicals and biofuels is also described herein. The method described herein may also allow for the selective production of the biobased aromatic chemicals and biofuels. Additionally, a reduction of waste products may also be provided from the present method.
• METHOD FOR SELECTIVE PRODUCTION OF BIOBASED CHEMICALS AND BIOFUELS FROM PLANT LIGNIN
  申请人：Peterson John R.

  公开号：US20130232853A1

  公开（公告）日：2013-09-12

  The present invention is directed generally to a method of production of biobased chemicals, biofuels, and lignin residues from lignin sources, including waste lignin. This method may allow for selectively producing biobased chemicals, biofuels, and lignin residues from lignin sources using certain processing methods. The methods for production of these biobased chemicals, biofuels, and lignin residues may be provided by chemical-induced processing, catalytic oxidative lignin depolymerisation processing, and catalytic hydroprocessing. Further, the catalytic hydroprocessing from processes including catalytic reduction processing, catalytic hydrodeoxygenation processing, and/or catalytic/dehydrogenation processing may also be used. The method described herein also provides a means in which waste from the process(es) may be reduced and/or recycled.
• [EN] A METHOD FOR TIERED PRODUCTION OF BIOBASED CHEMICALS AND BIOFUELS FROM LIGNIN<br/>[FR] PROCÉDÉ DE PRODUCTION ÉTAGÉE DE BIOPRODUITS CHIMIQUES ET DE BIOCOMBUSTIBLES À PARTIR DE LIGNINE
  申请人：VERTICHEM CORP

  公开号：WO2013134756A1

  公开（公告）日：2013-09-12

  The present invention is directed generally to a method of production of value-added, biobased chemicals from lignin sources, including waste lignin. A method of using a depolymerization of lignin to create a tiered production of biobased aromatic chemicals and biofuels is also described herein. The method described herein may also allow for the selective production of the biobased aromatic chemicals and biofuels. Additionally, a reduction of waste products may also be provided from the present method.
• [EN] METHOD FOR SELECTIVE PRODUCTION OF BIOBASED CHEMICALS AND BIOFUELS FROM PLANT LIGNIN<br/>[FR] PROCÉDÉ POUR LA PRODUCTION SÉLECTIVE DE PRODUITS BIOCHIMIQUES ET DE BIOCOMBUSTIBLES À PARTIR DE LIGNINE VÉGÉTALE
  申请人：VERTICHEM CORP

  公开号：WO2013173332A1

  公开（公告）日：2013-11-21

  The present invention is directed generally to a method of production of biobased chemicals, biofuels, and lignin residues from lignin sources, including waste lignin. This method may allow for selectively producing biobased chemicals, biofuels, and lignin residues from lignin sources using certain processing methods. The methods for production of these biobased chemicals, biofuels, and lignin residues may be provided by chemical-induced processing, catalytic oxidative lignin depolymerisation processing, and catalytic hydroprocessing. Further, the catalytic hydroprocessing from processes including catalytic reduction processing, catalytic hydrodeoxygenation processing, and/or catalytic/dehydrogenation processing may also be used. The method described herein also provides a means in which waste from the process(es) may be reduced and/or recycled.
• The Brosimum Allene: A Structural Revision
  作者：Gaojie Hu、Kai Liu、Lawrence J. Williams

  DOI：10.1021/ol802338z

  日期：2008.12.4

  Insight derived from a synthetic model, calculated C-13 NMR data, and comparison to experimental data indicate that the proposed allenic structure A, originally assigned to an isolate from Brosimum acutifolium Huber, should be revised to B, a natural product and nonallenic substance, mururin C.