chloro-(2-hydroxycyclohexyl)mercury | 29581-85-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: chloro-(2-hydroxycyclohexyl)mercury
• 英文别名: (+/-)-trans-2-hydroxy-cyclohexylmercury (1+), chloride；(+/-)-trans-2-hydroxy-cyclohexylmercury (1+); chloride；(+/-)-trans-2-Hydroxy-cyclohexylquecksilber(1+); Chlorid
• CAS: 29581-85-9；29682-55-1
• 化学式: C₆H₁₁ClHgO
• 分子量: 335.196
• InChiKey: MCFOHRBOYMRMOO-ILKKLZGPSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.95
• 重原子数：
  9.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  盐酸 、 chloro-(2-hydroxycyclohexyl)mercury 生成 环己烯
  参考文献：
  名称：

  烯烃氧汞化的可逆性

  摘要：

  已经表明，脱氧汞化（α-氧有机汞向烯烃的转化）是一种二级反应，取决于汞和脱氧汞酸的浓度。此外，脱氧汞的速率随着汞中烷氧基取代基的碱性强度而增加。这种趋势表明该速率取决于用于脱氧汞的酸的强度。该假设已通过使用三氟乙酸证明，三氟乙酸比盐酸分解 α-2-甲氧基环己基汞三氟乙酸盐的速度更慢。三氟乙酰氧基汞分解到 35% 的程度，而它的合成以 60% 的最大产率由环己烯和三氟乙酸汞合成。因此，在这种氧汞反应中达到了可测量的平衡，

  DOI：

  10.1139/v57-182
• 作为产物：
  描述：

  环己烯 在 mercury (II)-salt 、 水 作用下， 生成 chloro-(2-hydroxycyclohexyl)mercury
  参考文献：
  名称：

  Satellite-based detection of Canadian boreal forest fires: Development and application of the algorithm

  摘要：

  This study presents a comprehensive investigation of fires across the Canadian boreal forest zone by means of satellite-based remote sensing. A fire-detection algorithm was designed to monitor fires using daily Advanced Very High Resolution Radiometer (AVHRR) images. It exploits information from multichannel AVHRR measurements to determine the locations of fires on satellite pixels of about 1 km(2) under clear sky or thin smoke cloud conditions. Daily fire maps were obtained showing most of the active fires across Canada (except those obscured by thick clouds). This was achieved by first compositing AVHRR scenes acquired over Canada on a given day and then applying the fire-detection algorithm. For the fire seasons of 1994-1998, about 800 NOAA/AVHRR daily mosaics were processed. The results provide valuable nation-wide information on fire activities in terms of their locations, burned area, starting and ending dates, as well as development. The total burned area as detected by satellite across Canada is estimated to be approximately 3.9, 4.9, 1.3, 0.4 and 2.4 million hectares in 1994, 1995, 1996, 1997 and 1998, respectively. The peak month of burning varies considerably from one year to another between June and August, as does the spatial distribution of fires. In general, conifer forests appear to be more vulnerable to burning and fires tend to grow larger than in deciduous forests.

  DOI：

  10.1080/01431160050144956

文献信息

• Cleavage of (2-hydroxy- and 2-alkoxycycloalkyl)mercuric chlorides by hydrochloric acid
  作者：A.M. Kiwan、A.A. Abdel-Hamid、M.F.R. Fouda

  DOI：10.1016/s0022-328x(00)92789-x

  日期：1970.6

  The kinetics of the cleavage of (trans-2-methoxycyclohexyl)-, (trans-2-ethoxycyclohexyl)-, (trans-2-hydroxycyclohexyl)-, and (trans-2-methoxycyclopentyl)mercuric chlorides by hydrochloric acid have been investigated by a conductivity method. The reaction in alcohol/water mixtures were found to be pseudo-second-order. The enthalpies and entropies are discussed in relation to the nature of the organic

  研究了通过盐酸裂解（反式-2-甲氧基环己基）-，（反式-2-乙氧基环己基）-，（反式-2-羟基环己基）-和（反式-2-甲氧基环戊基）汞氯化物的动力学。电导率法。发现在醇/水混合物中的反应是假二级反应。关于有机自由基的性质，讨论了焓和熵。
• Brook; Wright, Canadian Journal of Research, Section B: Chemical Sciences, 1950, vol. 28, p. 623,634
  作者：Brook、Wright

  DOI：——

  日期：——