tetrabutylammonium D-glucuronate | 695203-09-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: tetrabutylammonium D-glucuronate
• CAS: 695203-09-9
• 化学式: C₆H₉O₇*C₁₆H₃₆N
• 分子量: 435.602
• InChiKey: DYBFNKATMONOCP-HTJLRXQKSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.54
• 重原子数：
  30.0
• 可旋转键数：
  13.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  130.28
• 氢给体数：
  4.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  (1S,2S)-安非他酮N-1’-脱氧-beta-D-葡萄糖醛酸 、 四丁基氢氧化铵 以 乙醇 、 水 为溶剂， 反应 24.0h， 以80%的产率得到tetrabutylammonium D-glucuronate
  参考文献：
  名称：

  Biomass derived ionic liquids: synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes

  摘要：

  Ionic liquids with natural organic derived anions (L-lactate, L-tartrate, malonate, succinate, L-malate, pyruvate, D-glucuronate, D-galacturonate) were easily prepared from tetrabutylammonium hydroxide and an excess of the corresponding acid with good yields. Their characterization was realized through classical NMR, IR, and elemental analysis techniques; their viscosity and TGA (thermogravimetric analysis) parameters were also determined. These ionic liquids showed good performance and recyclability in the selective catalytic hydrogenation of 1,5-cyclooctadiene (1,5-COD) into cyclooctene (COD) at room temperature under atmospheric H-2 pressure.Antimicrobial toxicity assays toward a large panel of bacteria and fungi strains were also completed and biodegradation studies (Closed Bottle test, 28 days) were also performed. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.05.054