chloro[5-(1-methyl-2-imidazolyl)-10,15,20-tripentafluorophenylporphyrinato]iron(III)bis(1-methylimidazole) | 1115613-70-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: chloro[5-(1-methyl-2-imidazolyl)-10,15,20-tripentafluorophenylporphyrinato]iron(III)bis(1-methylimidazole)
• CAS: 1115613-70-1
• 化学式: C₅₀H₂₅F₁₅FeN₁₀*Cl
• 分子量: 1142.09
• InChiKey: PJHODAALGCRPCW-DBKZERRASA-M

反应信息

• 作为产物：
  描述：

  N-甲基咪唑 、 chloro[5-(1-methyl-2-imidazolyl)-10,15,20-tripentafluorophenylporphyrinato]iron(III) 以 氘代乙腈 为溶剂， 生成 chloro[5-(1-methyl-2-imidazolyl)-10,15,20-tripentafluorophenylporphyrinato]iron(III)bis(1-methylimidazole)
  参考文献：
  名称：

  Oxidation of adamantane catalysed by imidazolylporphyrinatoiron(III) complexes and structural studies of 5-coordinating iron(III) porphyrin

  摘要：

  Oxidation of adamantane with phenylperacetic acid was carried out in the presence of three imidazolyltriarylporphyrinatoiron(III) complexes having pentafluorophenyl, phenyl, and mesityl (2,4,6-trimethylphenyl) groups as meso-substituents and three corresponding tetraarylporphyrinatoiron(III) complexes. The yield of 1- and 2-adamantanols was 76% in the case of chloro-5-(1-methyl-2imidazolyl)-10,15,20-tri(pentafluorophenyl)porphyrinatoiron(III) (ImTPFPP-Fe(III)Cl), whereas the yield was only 26% in the case of chloro-5,10,15,20-tetra(pentafluorophenyl)porphyrinatoiron(III) in the presence of 100 eq. N-methylimidazole. The apparent effect of the appended imidazolyl group is discussed in terms of a 5-coordinated dimer of ImTPFPP-Fe(III)Cl, which was observed in the H-1 and F-19 NMR, and UV-vis spectra. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2007.12.016