bis(2,2,3,3-tetrafluoropropyl) phosphorobromidate | 71878-94-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 英文名称: bis(2,2,3,3-tetrafluoropropyl) phosphorobromidate
• 英文别名: 3-[Bromo(2,2,3,3-tetrafluoropropoxy)phosphoryl]oxy-1,1,2,2-tetrafluoropropane
• CAS: 71878-94-9
• 化学式: C₆H₆BrF₈O₃P
• 分子量: 388.977
• InChiKey: AIDIQKDQJNSKJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  19
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  bis(2,2,3,3-tetrafluoropropyl) trimethylsilyl phosphite 在 三溴乙醛 作用下， 生成 bis(2,2,3,3-tetrafluoropropyl) phosphorobromidate
  参考文献：
  名称：

  Mironov, V.F.; Sinyashina, T.N.; Ofitserov, E.N., Russian Journal of General Chemistry, 1994, vol. 64, # 8.2, p. 1225 - 1227

  摘要：

  DOI：

文献信息

• IMIDIC ACID COMPOUND HAVING DIVALENT ANION AND PROCESS FOR PRODUCING THE SAME
  申请人：Central Glass Co., Ltd.

  公开号：EP3222624A1

  公开（公告）日：2017-09-27

  Provided is a novel imidic acid compound having a divalent anion useful as a pharmaceutical intermediate, an agrochemical intermediate, an acid catalyst, a battery electrolyte or an antistatic agent. The imidic acid compound is a divalent imidic acid compound represented by the following general formula (1) or (2). [In formulae (1) and (2), R1 to R3 represent a fluorine atom or an organic groups selected from a linear or branched C1-10 alkoxy group, a C2-10 alkenyloxy group, a C2-10 alkynyloxy group, a C3-10 cycloalkoxy group, a C3-10 cycloalkenyloxy group and a C6-10 aryloxy group, and wherein a fluorine atom, an oxygen atom or an unsaturated bond may also be present in the organic group. M1 and M2 represent protons, metal cations or onium cations.]

  本文提供了一种具有二价阴离子的新型亚胺酸化合物，可用作医药中间体、农用化学品中间体、酸催化剂、电池电解液或抗静电剂。该亚胺酸化合物是由以下通式（1）或（2）表示的二价亚胺酸化合物。 [在式(1)和(2)中，R1 至 R3 代表一个氟原子或一个有机基团，该有机基团选自直链或支链 C1-10 烷氧基、C2-10 烯氧基、C2-10 烷炔氧基、C3-10 环烷氧基、C3-10 环烯氧基和 C6-10 芳氧基，其中有机基团中还可能存在一个氟原子、一个氧原子或一个不饱和键。M1和M2代表质子、金属阳离子或鎓阳离子]。
• Imidic acid compound having divalent anion and process for producing the same
  申请人：CENTRAL GLASS CO., LTD.

  公开号：US10287165B2

  公开（公告）日：2019-05-14

  Provided is a novel imidic acid compound having a divalent anion useful as a pharmaceutical intermediate, an agrochemical intermediate, an acid catalyst, a battery electrolyte or an antistatic agent. The imidic acid compound is a divalent imidic acid compound represented by the following general formula (1) or (2). [In formulae (1) and (2), R1 to R3 represent a fluorine atom or an organic groups selected from a linear or branched C1-10 alkoxy group, a C2-10 alkenyloxy group, a C2-10 alkynyloxy group, a C3-10 cycloalkoxy group, a C3-10 cycloalkenyloxy group and a C6-10 aryloxy group, and wherein a fluorine atom, an oxygen atom or an unsaturated bond may also be present in the organic group. M1 and M2 represent protons, metal cations or onium cations.]

  本文提供了一种具有二价阴离子的新型亚胺酸化合物，可用作医药中间体、农用化学品中间体、酸催化剂、电池电解液或抗静电剂。该亚胺酸化合物是由以下通式（1）或（2）表示的二价亚胺酸化合物。 [在式 (1) 和 (2) 中，R1 至 R3 代表氟原子或有机基团，这些有机基团选自直链或支链 C1-10 烷氧基、C2-10 烯氧基、C2-10 烷炔氧基、C3-10 环烷氧基、C3-10 环烯氧基和 C6-10 芳氧基，其中有机基团中还可能存在氟原子、氧原子或不饱和键。M1和M2代表质子、金属阳离子或鎓阳离子]。
• Shermolovich, Yu. G.; Kolesnik, N. P.; Markovskii, L. N., Journal of general chemistry of the USSR, 1986, p. 193 - 194
  作者：Shermolovich, Yu. G.、Kolesnik, N. P.、Markovskii, L. N.

  DOI：——

  日期：——
• Markovskii,L.N. et al., Journal of general chemistry of the USSR, 1979, vol. 49, p. 1547 - 1551
  作者：Markovskii,L.N. et al.

  DOI：——

  日期：——
• Ofitserov, E. N.; Mironov, V. F.; Sinyashina, T. N., Journal of general chemistry of the USSR, 1990, vol. 60, # 8, p. 1526 - 1532
  作者：Ofitserov, E. N.、Mironov, V. F.、Sinyashina, T. N.、Chernov, A. N.、Il'yasov, A. V.、et al.

  DOI：——

  日期：——