cis-di(4,5-diazafluoren-9-ylimino)dibenzo-18-crown-6 | 1156463-74-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: cis-di(4,5-diazafluoren-9-ylimino)dibenzo-18-crown-6
• 英文别名: N-[25-(3,13-diazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaen-8-ylideneamino)-2,5,8,15,18,21-hexaoxatricyclo[20.4.0.09,14]hexacosa-1(22),9(14),10,12,23,25-hexaen-11-yl]-3,13-diazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaen-8-imine
• CAS: 1156463-74-9
• 化学式: C₄₂H₃₄N₆O₆
• 分子量: 718.769
• InChiKey: LFDDJHBNCQPHHV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  54
• 可旋转键数：
  2
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  132
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  顺-双(2,2-二吡啶)二氯化钌(II) 水合物 、 cis-di(4,5-diazafluoren-9-ylimino)dibenzo-18-crown-6 、 hexafluorophosphate anion 以 乙二醇甲醚 为溶剂， 以46%的产率得到[(cis-di(4,5-diazafluoren-9-ylimino)dibenzo-18-crown-6)bis(bis(2,2'-bipyridine)ruthenium(II))] hexafluorophosphate
  参考文献：
  名称：

  Synthesis, photophysical, and electrochemical properties of three novel Ru(II) polypyridyl complexes containing dibenzo-18-crown-6

  摘要：

  Three polypyridyl bridging ligands cis-di(4,5-diazafluoren-9-ylimino)dibenzo-18-crown-6 (BL(1)), trans-di(4,5-diazafluoren-9-ylimino)dibenzo-18-crown-6 (BL(2)), and 1,4,7,10,13,16-hexaoxacycloctadecyl[2,3:11,12]bis-dipyrido[3,2-a:2'3'-c]phenazine (BL(3)), and corresponding dinuclear Ru(II) complexes [(bpy)(2)-RuBL(1-3) Ru(bpy)(2)](PF(6))(4) (1, 2, and 3) have been synthesized. Cyclic voltammetry of the complexes are consistent with one Ru(II)-centered oxidation and three ligand-centered reductions. Photophysical behaviors are investigated by UV-Vis absorption and fluorescence spectrometry. The three complexes show metal-to-ligand charge transfer absorption at 445-453 nm and emission at 571-593 nm. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2008.03.011