(2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenyporphinato)palladium(II) | 340732-52-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: (2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenyporphinato)palladium(II)
• 英文别名: PdTPOEP；palladium(II) meso-tetraphenyl octaethylporphyrinate；(2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphinato)palladium(II)；(2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrinato)palladium(II)；Pd(meso-tetraphenyloctaethylporphyrin)；PdTetPOEP
• CAS: 340732-52-7
• 化学式: C₆₀H₆₀N₄Pd
• 分子量: 943.583
• InChiKey: GLXVOSFKXJPTAX-KCVIGMLFSA-N

反应信息

• 作为反应物：
  描述：

  (2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenyporphinato)palladium(II) 在 硫酸 作用下， 以 硫酸 、 溶剂黄146 为溶剂， 生成 (2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphinato)palladium(II)(1+)
  参考文献：
  名称：

  Acid-base and coordination properties of some palladium(II)porphyrins

  摘要：

  The speciation and reactions of palladium(II) complexes with meso-tetraphenylporphine (H2TPP) and meso-tetraphenyl-beta-octaethylporphine (H(2)TetPOEP) were studied in H2SO4-H2O and H2SO4-HOAc protic solvents. H-associated species of PdTPP and PdTetPOEP were found to exist in sulfuric acid with concentrations of 16.33-17.38 and 17.48-18.22 mol/L, respectively. The kinetics of one-electron oxidation of complexes in the coordinated aromatic macrocycle were studied. A third-order rate equation was determined, and the mechanism of the oxidation reaction was substantiated with kinetically significant stages of dioxygen coordination, electron transfer from the macrocyclic aromatic system to dioxygen, and H-association equilibrium between the complex and sulfuric acid. The effects of peripheral ethyl substituents in the macrocyclic ligand on the reactivity of palladium(II)porphyrins were revealed.

  DOI：

  10.1134/s0036023608090106
• 作为产物：
  描述：

  palladium dichloride 、 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin 以 N,N-二甲基甲酰胺 为溶剂， 生成 (2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenyporphinato)palladium(II)
  参考文献：
  名称：

  八乙基卟啉与钯（II）配合物的结构修饰和动力学稳定性

  摘要：

  比较2,3,7,8,12,13,17,18-八乙基-21H，23H-卟啉（H 2 OEP）中逐步取代内消旋苯基对与其Pd（II）配合物稳定性的影响到内消旋-tetraphenylporphyne复合物与未取代的C β原子被化学动力学和物理化学分析来调查。使用光谱方法，研究了ACOH -H 2 SO 4混合物中配合物的状态和反应，以了解广泛的组成。结果发现，配位中心在混合物中的H 2 SO 4含量高达100％时是稳定的。无论是在分子状态或与质子（和的PdOEP其单关联的内消旋-苯基衍生物），复合物经历由化学动力学研究转化。结果表明，配合物的大环中发生单电子氧化，而不是配位中心的通常解离。揭示了一种多级机理，涉及在H-缔合的配合物的形成与分子氧的不可逆配位之间的动力学上显着的平衡，然后是电子将其从芳族体系转移到该氧的酸辅助转移。确定了配合物的氧化稳定性，讨论了大环配体结构与配位中心电子结构之间的关系。

  DOI：

  10.1134/s0036024411060215
• 作为试剂：
  描述：

  双氧水 在 (2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenyporphinato)palladium(II) 氢氧化钾 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 氧气
  参考文献：
  名称：

  Modifications in structure of palladium(II) porphinate as a method of regulating the catalysis of hydrogen peroxide decomposition

  摘要：

  Results of kinetic, volumetric, and spectral study of the reaction of alkaline H2O2 decomposition in a water-dimethyl formamide medium catalyzed by (PdPf)-P-II (P-f is octaethylporphyrin and its monophenyl-, 5,15-diphenyl-, 5,10-diphenyl-, triphenyl-, and tetraphenyl-substituted in meso-positions derivatives) under polythermal conditions are presented. It was found that the catalysis is of the heterogeneous nature; intermediates and complete kinetic characteristics (rates, activation parameters, and the orders with respect to all reagents) were determined depending on the macrocycle structure. The sequence of the catalytic activity of palladium(II) porphyrinates was estimated.

  DOI：

  10.1134/s1070363208110212

文献信息

• The kinetics of disproportionation of hydrogen peroxide in the presence of palladium(II)porphyrins with regularly changing macroring structures
  作者：T. N. Lomova、M. E. Klyueva、O. V. Kosareva、M. V. Klyuev

  DOI：10.1134/s0036024408070066

  日期：2008.7

  The kinetics and spectral manifestations of alkaline decomposition of H2O2 in a water-dimethylformamide medium catalyzed by (PdP)-P-II (P is the dianion of octaethylporphyrin and its monophenyl, 5,15-diphenyl,5,10-diphenyl, triphenyl, and tetraphenyl derivatives substituted at meso positions) was studied over a wide range of reagent concentrations under polythermal conditions. A complete kinetic description of the reacting systems was given, and the rates and set of elementary reactions, intermediate compounds, and kinetically significant equilibria were determined. The ion-molecular mechanism of hydrogen peroxide decomposition was substantiated. According to this mechanism, the only stable radicals involved in the reaction are the pi radical cation forms of palladium(II)porphyhrin catalysts.