1-Butyl-3-methyl-2-phenylimidazol-3-ium;trifluoromethanesulfonate | 1207893-48-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-Butyl-3-methyl-2-phenylimidazol-3-ium;trifluoromethanesulfonate
• CAS: 1207893-48-8
• 化学式: CF₃O₃S*C₁₄H₁₉N₂
• 分子量: 364.389
• InChiKey: RINAKJBHSDOOEZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.83
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  74.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-苯基咪唑 在 四丁基碘化铵 、 sodium hydroxide 作用下， 以 水 、 甲苯 、 乙腈 为溶剂， 生成 1-Butyl-3-methyl-2-phenylimidazol-3-ium;trifluoromethanesulfonate
  参考文献：
  名称：

  Scope and limitations of imidazolium-based ionic liquids as room temperature glycosylation promoters

  摘要：

  The scope and limitations of imidazolium-based ionic liquids as room temperature glycosylation promoters have been studied. Herein, we report the effects of modifying the structure of the imidazolium cation and how important the choice of counter ion becomes on model glycosylation reactions of thioglycosides at room temperature in the presence of N-iodosuccinimide (NIS). (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2009.09.034
• 作为试剂：
  描述：

  苯基2,3,4,6-四-O-苄基-1-硫代-beta-D-吡喃葡萄糖苷 、 双丙酮半乳糖 在 N-碘代丁二酰亚胺 、 1-Butyl-3-methyl-2-phenylimidazol-3-ium;trifluoromethanesulfonate 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 生成 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->6)-[1:2,3:4]-di-O-isopropylidene-α-D-galactopyranoside 、 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranoside
  参考文献：
  名称：

  Scope and limitations of imidazolium-based ionic liquids as room temperature glycosylation promoters

  摘要：

  The scope and limitations of imidazolium-based ionic liquids as room temperature glycosylation promoters have been studied. Herein, we report the effects of modifying the structure of the imidazolium cation and how important the choice of counter ion becomes on model glycosylation reactions of thioglycosides at room temperature in the presence of N-iodosuccinimide (NIS). (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2009.09.034