1-(1-Decenyloxy)-2-propanon | 79032-85-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(1-Decenyloxy)-2-propanon
• 英文别名: 1-Dec-1-enoxypropan-2-one
• CAS: 79032-85-2；79032-86-3
• 化学式: C₁₃H₂₄O₂
• 分子量: 212.332
• InChiKey: KYVOMGAJNOUINU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-Methylen-2-nonyl-1,3-dioxolan 在 Lewatit S 100 作用下， 反应 4.0h， 以62%的产率得到1-(1-Decenyloxy)-2-propanon
  参考文献：
  名称：

  Mattay, Jochen; Thuenker, Walter; Scharf, Hans-Dieter, Liebigs Annalen der Chemie, 1981, # 6, p. 1105 - 1117

  摘要：

  DOI：

文献信息

• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC BODY, AND METHOD FOR PRODUCING POLYMERIZABLE COMPOUND
  申请人：ZEON CORPORATION

  公开号：US20150175564A1

  公开（公告）日：2015-06-25

  A polymerizable compound has a practical low melting point, excellent solubility in a general-purpose solvent, and can produce an optical film at low cost, exhibits low reflected luminance, and achieves uniform conversion of polarized light over a wide wavelength band, an optically anisotropic article. A carbonyl compound is useful as a raw material for producing the polymerizable compound. (In the formula (I), Y 1 to Y 8 represent —C(═O)—O—, G 1 and G 2 represent a C 1-20 divalent linear aliphatic group, Z 1 and Z 2 represent a C 2-10 alkenyl group that is unsubstituted, or substituted with a halogen atom, A x represents a C 2-30 organic group with at least one aromatic ring, A y represents a hydrogen atom or C 1-20 alkyl group, A 1 represents a trivalent aromatic group, A 2 and A 3 represent a C 3-30 divalent alicyclic hydrocarbon group, A 4 and A 5 represent a C 6-30 divalent aromatic group or the like, and Q 1 represents a hydrogen atom.)

  一种可聚合的化合物具有实用的低熔点、在通用溶剂中良好的溶解性，并且可以以低成本制备光学薄膜，表现出较低的反射亮度，并且在宽波长范围内实现偏振光的均匀转换，是一种光学各向异性材料。一种羰基化合物可作为制备可聚合化合物的原料。（在式（I）中，Y1至Y8代表—C(═O)—O—，G1和G2代表C1-20二价线性脂肪族基团，Z1和Z2代表未取代或取代有卤素原子的C2-10烯基基团，Ax代表至少具有一个芳香环的C2-30有机基团，Ay代表氢原子或C1-20烷基基团，A1代表三价芳香族基团，A2和A3代表C3-30二价脂环碳氢基团，A4和A5代表C6-30二价芳香族基团或类似物，Q1代表氢原子。）
• PHASE DIFFERENCE PLATE, CIRCULARLY POLARIZING PLATE, AND IMAGE DISPLAY DEVICE
  申请人：ZEON CORPORATION

  公开号：US20150277010A1

  公开（公告）日：2015-10-01

  A phase difference plate including an optically anisotropic layer obtained by curing a composition (A) containing a polymerizable liquid crystal compound with reverse wavelength dispersion and a polymerizable monomer, wherein the polymerizable liquid crystal compound with reverse wavelength dispersion has a main chain mesogen and a side chain mesogen bonded to the main chain mesogen in the molecule thereof; the main chain mesogen and the side chain mesogen are oriented in different directions, whereby a birefringence Δn of the optically anisotropic layer has reverse wavelength dispersion property; and retardations of a layer obtained by curing a composition (A0) in which the polymerizable monomer in the composition (A) is replaced by the polymerizable liquid crystal compound with reverse wavelength dispersion and retardations of the optically anisotropic layer satisfy specific relationship; and a circularly polarizing plate and a display device including the same.
• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICAL ANISOTROPIC BODY
  申请人：ZEON CORPORATION

  公开号：US20160200841A1

  公开（公告）日：2016-07-14

  The present invention relates to: a polymerizable compound represented by a formula (I), wherein each of Y 1 to Y 8 independently represents —O—, —O—C(═O)—, —C(═O)—O— or the like; each of A 2 , A 3 , G 1 , and G 2 independently represents a divalent linear aliphatic group having 1 to 20 carbon atoms or the like; each of Z 1 and Z 2 independently represents an alkenyl group having 2 to 10 carbon atoms or the like; A x represents an organic group having 2 to 30 carbon atoms that includes at least one aromatic ring; A y represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms or the like; A 1 represents a trivalent aromatic group or the like; each of A 4 and A 5 independently represents a divalent aromatic group having 6 to 30 carbon atoms or the like; and Q 1 represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms or the like; and others. According to the present invention, it becomes possible to provide: a polymerizable compound that have a practical low melting point, exhibit excellent solubility in a general-purpose solvent, can be produced inexpensively, can be dried at a lower temperature, has excellent energy efficiency, and can produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band; and others.
• US9586917B2
  申请人：——

  公开号：US9586917B2

  公开（公告）日：2017-03-07