6,7-dideoxy-L-galacto-hept-6-enonamide | 342896-29-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 6,7-dideoxy-L-galacto-hept-6-enonamide
• 英文别名: (2S,3R,4R,5S)-2,3,4,5-tetrahydroxyhept-6-enamide
• CAS: 342896-29-1
• 化学式: C₇H₁₃NO₅
• 分子量: 191.184
• InChiKey: HJTHGZDGBUEUMU-KCDKBNATSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.7
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  124
• 氢给体数：
  5
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  甲醇 、 6,7-dideoxy-L-galacto-hept-6-enonamide 生成 methyl 3,6-anhydro-7-deoxy-7-iodo-D-glycero-L-galacto-heptonate
  参考文献：
  名称：

  Synthesis of a building block for phosphonate analogues of moenomycin A 12 from d -tartaric acid

  摘要：

  An approach for the synthesis of moenomycin A(12) C-glycoside partial structures is reported based on allyltin chemistry. (C) 2001 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(01)00350-1
• 作为产物：
  描述：

  5-O-(tert-butyldimethylsilyl)-6,7-dideoxy-2,3-O-isopropylidene-L-galacto-hept-6-enonamide 在 Dowex 50-H⁽¹⁺⁾ 作用下， 以 乙醇 、 水 为溶剂， 以100%的产率得到6,7-dideoxy-L-galacto-hept-6-enonamide
  参考文献：
  名称：

  Synthesis of a building block for phosphonate analogues of moenomycin A 12 from d -tartaric acid

  摘要：

  An approach for the synthesis of moenomycin A(12) C-glycoside partial structures is reported based on allyltin chemistry. (C) 2001 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(01)00350-1

文献信息

• Synthesis of a building block for phosphonate analogues of moenomycin A12 from d-tartaric acid
  作者：Jalal Zahra、Lothar Hennig、Matthias Findeisen、Sabine Giesa、Peter Welzel、Dietrich Müller、William S Sheldrick

  DOI：10.1016/s0040-4020(01)00951-6

  日期：2001.11

  An approach for the synthesis of moenomycin A(12) C-glycoside partial structures is reported based on allyltin chemistry. (C) 2001 Elsevier Science Ltd. All rights reserved.
• Synthesis of a building block for phosphonate analogues of moenomycin A 12 from d -tartaric acid
  作者：Jalal Zahra、Lothar Hennig、Matthias Findeisen、Peter Welzel、Dietrich Müller、William S Sheldrick

  DOI：10.1016/s0040-4039(01)00350-1

  日期：2001.4

  An approach for the synthesis of moenomycin A(12) C-glycoside partial structures is reported based on allyltin chemistry. (C) 2001 Published by Elsevier Science Ltd.