3-N(4-(fluoro) phenyl) imidazo[1,5a] pyridinium perchlorate | 848304-06-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 3-N(4-(fluoro) phenyl) imidazo[1,5a] pyridinium perchlorate
• CAS: 848304-06-3
• 化学式: C₁₃H₁₀FN₂*ClO₄
• 分子量: 312.685
• InChiKey: JHFNZODDGGSHPI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-(2-pyridylmethylene) 4-(fluoro) phenyl amine 、 {Ru(2,2'-bipyridyl)Cl3}n 、 sodium perchlorate 以 甲醇 为溶剂， 以31%的产率得到[Ru(bpy)(L4)2](ClO4)2*H2O
  参考文献：
  名称：

  Synthesis, spectroscopic and electrochemical properties of some heteroleptic tris-chelates of ruthenium (II) involving 2,2′-bipyridine (bpy) and N-(aryl) pyridine-2-aldimine(L): X-ray crystal structures of [Ru(bpy)(L2)2](ClO4)2·H2O and 3-N(4-tolyl) imidazo [1,5a] pyridinium perchlorate

  摘要：

  Four ruthenium (II) complexes of the formulae [Ru(bpy)(L-1)(2)](ClO4)(2) . H2O (A1), [Ru(bpy)(L-2)(2)](ClO4)(2) . H2O (A2), [Ru(bpy)(L-3)(2)](ClO4)(2) . H2O (A3), [Ru(bpy)(L-4)(2)](ClO4)(2) . H2O (A4) (where L-1 = N-(2-pyridylmethylene) phenyl amine, L-2 = N-(2-pyridylmethylene) 4-(methyl) phenyl amine, L-3 = N-(2-pyridylmethylene) 4-(chloro) phenyl amine, L-4 = N-(2-pyridylmethylene) 4-(fluoro) phenyl amine and bpy = 2,2'-bipyridyl) have been synthesized. In addition to these ruthenium complexes, we have also been able to isolate four imidazopyridinium perchlorate compounds B1-B4 from the same reactions. The X-ray crystal structures of one representative ruthenium complex (A2) and the imidazopyridinium perchlorate compound (B2) have been determined. The Ru(II) center in the complex is coordinated by six N donors with a distorted octahedral geometry. The imine ligands (L) act as bidentate N,N donors. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.11.011