3-(Nonafluoro-n-butyl)prop-2-enol | 83706-96-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-(Nonafluoro-n-butyl)prop-2-enol
• 英文别名: 1H,1H,2H,3H-Nonafluorohept-2-en-1-ol；(E)-4,4,5,5,6,6,7,7,7-nonafluorohept-2-en-1-ol
• CAS: 83706-96-1
• 化学式: C₇H₅F₉O
• 分子量: 276.102
• InChiKey: PJZRJKWUZCHGGW-OWOJBTEDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  2-Iodo-4,4,5,5,6,6,7,7,7-nonafluoroheptyl acetate 在 氢氧化钾 作用下， 以 乙醚 、 正己烷 为溶剂， 反应 7.5h， 生成 3-(Nonafluoro-n-butyl)prop-2-enol
  参考文献：
  名称：

  Highly selective synthesis of [(perfluoroalkyl) methyl] oxiranes (by the addition of iodoperfluoroalkanes to allyl acetate)

  摘要：

  Mixtures of regioisomeric adducts of monoiodoperfluoroalkanes R-F-I (R-F = C4F9, C6F13 C8F17) with allyl acetate, RFCH2CHICH2OAc (1a-1c) and rearranged adducts RFCH2CH(OAc)-CH2I (2a-2c), were converted chemoselectively to the corresponding oxiranes RFCH2CH(-O-)CH2 (3a-3c) in yields of 94-96% (total yields of the two-step synthesis starting from R-F-I were 85-87%). The chemoselectivity of the oxirane formation appeared to be very dependent on the solvent used. Dependence on the reaction conditions on formation of byproducts RFCH=CHCH2OAc (4a-4c) and RFCH=CHCH2OH (5a-5c) in the epoxidation reaction was studied. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-1139(97)00018-3

文献信息

• POLYCARBONATE-BASE POLYMER, PRODUCTION PROCESS, RESIN COATING FLUID PREPARED THEREFROM, AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR PREPARED THEREFROM
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0837085A1

  公开（公告）日：1998-04-22

  A polymer comprising mainly repeating units (1) and/or repeating units (2), containing optionally terminal groups (3) and/or repeating units (4), and having a reduced viscosity [ηsp/c] of 0.2 to 10.0 dl/g as measured in a 0.5 g/dl solution thereof in methylene chloride at 20°C; a resin coating fluid containing the polymer, a charge-transfer substance and a solvent; and an electrophotographic photoreceptor containing the polymer as a binder resin in a photosensitive layer, wherein Rf1 represents a group that is composed of at least carbon atoms and fluorine atoms and bonded directly to the two oxygen atoms of the carbonate linkage in the general formula (1) without any intervening arylene group; and Rf2 represents a group that is composed of at least carbon atoms and fluorine atoms and bonded directly to one of the oxygen atoms of the carbonate linkage in the general formula (3) without any intervening arylene group.

  一种主要由重复单元（1）和/或重复单元（2）组成的聚合物，含有任选的末端基团（3）和/或重复单元（4），在 0.其中 Rf1 代表至少由碳原子和氟原子组成并直接与通式（1）中碳酸酯连接的两个氧原子键合的基团，而没有任何芳基介入；Rf2 代表一个至少由碳原子和氟原子组成的基团，直接与通式（3）中碳酸酯链节的一个氧原子键合，中间不含任何芳烯基。
• MALEIMIDO-BEARING COMPOUNDS, RESIN COMPOSITIONS CONTAINING THE SAME AND CURED ARTICLES THEREOF
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：EP1460092A1

  公开（公告）日：2004-09-22

  The present invention provides (meth)acrylate compounds bearing a specific maleimide group and resin compositions containing said compounds that can be cured by irradiation of light in a practical dose even when a photoinitiator is not used or used in a smaller amount than that of the prior art, and cured articles of the resin compositions.

  本发明提供了带有特定马来酰亚胺基团的（甲基）丙烯酸酯化合物和含有上述化合物的树脂组合物，即使在不使用光引发剂或使用量少于现有技术的情况下，这些化合物也能通过实用剂量的光照射固化，本发明还提供了树脂组合物的固化物。
• Novel aerosol formulation containing a polar fluorinated molecule
  申请人：——

  公开号：US20030194378A1

  公开（公告）日：2003-10-16

  The present invention relates to a stable pharmaceutical aerosol formulation intended for inhalation. The formulation contains an active substance, an aerosol propellant, a polar flurorinated molecule and an excipient. The preferred propellant is HFA 134a or HFA 227 or a mixture thereof.

  本发明涉及一种用于吸入的稳定药用气溶胶制剂。该制剂含有一种活性物质、一种气溶胶推进剂、一种极性氟化分子和一种赋形剂。优选的推进剂是 HFA 134a 或 HFA 227 或它们的混合物。
• Maleimido-bearing compounds resin composition containing the same and cured articles thereof
  申请人：Ozaki Toru

  公开号：US20050009947A1

  公开（公告）日：2005-01-13

  The present invention provides (meth)acrylate compounds bearing a specific maleimide group and resin compositions containing said compounds that can be cured by irradiation of light in a practical dose even when a photoinitiator is not used or used in a smaller amount than that of the prior art, and cured articles of the resin compositions.

  本发明提供了带有特定马来酰亚胺基团的（甲基）丙烯酸酯化合物和含有上述化合物的树脂组合物，即使在不使用光引发剂或使用量少于现有技术的情况下，这些化合物也能通过实用剂量的光照射固化，本发明还提供了树脂组合物的固化物。
• NOVEL AEROSOL FORMULATION CONTAINING A POLAR FLUORINATED MOLECULE
  申请人：AstraZeneca AB

  公开号：EP1303258A1

  公开（公告）日：2003-04-23