5-[(4-nitrophenyl)sulfonyl]-1-phenyl-1H-tetrazole | 1443384-55-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 5-[(4-nitrophenyl)sulfonyl]-1-phenyl-1H-tetrazole
• CAS: 1443384-55-1
• 化学式: C₁₃H₉N₅O₄S
• 分子量: 331.312
• InChiKey: OWNGGLHLMNYANE-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  5-(4-nitrophenyl)sulfanyl-1-phenyltetrazole 在 sodium periodate 、 ruthenium(III) chloride trihydrate 作用下， 以 水 、 乙腈 为溶剂， 反应 6.0h， 以85%的产率得到5-[(4-nitrophenyl)sulfonyl]-1-phenyl-1H-tetrazole
  参考文献：
  名称：

  Tetrazoles: LVII. Preparation and chemical properties of 1-substituted 5-arylsulfonyltetrazoles

  摘要：

  Oxidation of 1-substituted 5-arylsulfanyltetrazoles with m-chloroperoxybenzoic acid and NaIO4 in the presence of RuCl3 leads to the formation of the 5-arylsulfonyltetrazoles. The microwave activation significantly accelerates the oxidation with sodium periodate. The phenylsulfonyl group in compounds obtained underwent the nucleophilic substitution when treated with ethanol, phenol, or benzimidazole in acetonitrile in the presence of NaOH.

  DOI：

  10.1134/s1070428013050229