(2E,4E,6E,8E)-9-cyclohexylnona-2,4,6,8-tetraenal | 76080-85-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2E,4E,6E,8E)-9-cyclohexylnona-2,4,6,8-tetraenal
• CAS: 76080-85-8
• 化学式: C₁₅H₂₀O
• 分子量: 216.323
• InChiKey: JOSULPBJOHYCCP-RYNIPNPOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (Z)-1-methoxybut-1-en-3-yne 、 (2E,4E,6E,8E)-9-cyclohexylnona-2,4,6,8-tetraenal 生成
  参考文献：
  名称：

  Two- and four-carbon homologation of aldehyde by AgClO4-catalyzed addition of alkoxyalkenylzirconocene chloride

  摘要：

  Two- and four-carbon homologation of aldehyde is described, which is based on the AgClO4-catalyzed addition of zirconocene complexes, derived from hydrozirconation of 1-ethoxyethyne (1) and (Z)-1-methoxy-1-buten-3-yne (2) with Cp2Zr(H)Cl, followed by acidic hydrolysis.

  DOI：

  10.1016/s0040-4039(00)60583-x
• 作为产物：
  描述：

  环己烷基甲醛 生成 (2E,4E,6E,8E)-9-cyclohexylnona-2,4,6,8-tetraenal
  参考文献：
  名称：

  Two- and four-carbon homologation of aldehyde by AgClO4-catalyzed addition of alkoxyalkenylzirconocene chloride

  摘要：

  Two- and four-carbon homologation of aldehyde is described, which is based on the AgClO4-catalyzed addition of zirconocene complexes, derived from hydrozirconation of 1-ethoxyethyne (1) and (Z)-1-methoxy-1-buten-3-yne (2) with Cp2Zr(H)Cl, followed by acidic hydrolysis.

  DOI：

  10.1016/s0040-4039(00)60583-x

文献信息

• Two- and four-carbon homologation of aldehyde by AgClO4-catalyzed addition of alkoxyalkenylzirconocene chloride
  作者：Hideki Maeta、Keisuke Suzuki

  DOI：10.1016/s0040-4039(00)60583-x

  日期：1993.1

  Two- and four-carbon homologation of aldehyde is described, which is based on the AgClO4-catalyzed addition of zirconocene complexes, derived from hydrozirconation of 1-ethoxyethyne (1) and (Z)-1-methoxy-1-buten-3-yne (2) with Cp2Zr(H)Cl, followed by acidic hydrolysis.