Tb(N-phenylanthranilate)3(1,10-phenanthroline) | 864810-44-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Tb(N-phenylanthranilate)3(1,10-phenanthroline)
• 英文别名: 2-anilinobenzoate;1,10-phenanthroline;terbium(3+)
• CAS: 864810-44-6；131135-70-1
• 化学式: C₅₁H₃₈N₅O₆Tb
• 分子量: 975.818
• InChiKey: SBRUUEHFIQNYSE-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 N-苯基邻氨基苯甲酸 、 terbium(III) chloride hexahydrate 在 氨 作用下， 以 乙醇 为溶剂， 生成 Tb(N-phenylanthranilate)3(1,10-phenanthroline)
  参考文献：
  名称：

  The study on the effect and mechanism of the second ligands on the luminescence properties of terbium complexes

  摘要：

  The binary complex of Tb(III) with N-phenylanthranilic acid (N-HPA) was synthesized, and the ternary complexes were synthesized by introducing 1, 10-phenanthroline (Phen), 2,2'-dipyridyl (Bipy), trioctylphosphine oxide (TPPO) as the second ligand, respectively. These complexes were characterized by infrared spectra, UV spectra and fluorescence spectra. The effect and mechanism of different second ligands on the fluorescent intensity of the terbium N-phenylanthranilic acid complexes was discussed. It showed that all the complexes exhibited ligand-sensitized green emission. The luminescence intensity increased in the sequence of Tb(N-PA)(3)Phen < Tb(N-PA)(3)(H2O)(2) < Tb(N-PA)(3)Bipy < Tb(N-PA)(3)(TPPO)(2). The second ligands TPPO and Bipy enhanced the luminescence intensity of the complexes while the Phen quenched it. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2007.08.014