| 1061244-37-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• CAS: 1061244-37-8
• 化学式: C₁₀H₂₁N₂Si*Cl
• 分子量: 232.829
• InChiKey: VCTRXXLRYXZFLE-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  N-甲基咪唑 、 叔丁基二甲基氯硅烷 在 碘 作用下， 以 氘代氯仿 为溶剂， 以32%的产率得到
  参考文献：
  名称：

  Iodine-promoted silylation of alcohols with silyl chlorides. Synthetic and mechanistic studies

  摘要：

  An efficient silylating system for 1 degrees, 2 degrees, and 3 degrees, alcohols, consisting of a silyl chloride/N-methylimidazole/iodine, was developed. Synthetic and mechanistic aspects of this new reagent system, and particularly the role of iodine were investigated in detail using H-1 NMR spectroscopy. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.06.070