2-oxo-2-phenylethyl-2-dodecanoylhydrazinecarbodithioate | 1160227-22-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-oxo-2-phenylethyl-2-dodecanoylhydrazinecarbodithioate
• CAS: 1160227-22-4
• 化学式: C₂₁H₃₂N₂O₂S₂
• 分子量: 408.629
• InChiKey: GEORFVBAKGDHMS-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  potassium 2-dodecanoylhydrazinecarbodithioate 、 2-溴苯乙酮 以 乙醇 为溶剂， 反应 2.0h， 以68%的产率得到2-oxo-2-phenylethyl-2-dodecanoylhydrazinecarbodithioate
  参考文献：
  名称：

  Synthesis of corrosion preventive long-chain N-alkyl-2-(phenylthio)-acetohydrazides and 2-oxo-2-phenylethyl-2-alkanoylhydrazinecarbodithioates

  摘要：

  Long-chain N-alkyl-2-(phenylthio)acetohydrazides were synthesized via the reactions of 2-(phenylthio)acetohydrazide with long-straight-chain aldehydes and then reduction with sodium borohydride. The reactions of long-straight-chain hydrazides with carbon disulfide in alkaline media give the corresponding carbodithioate salts. Heating of potassium 2-alkanoylhydrazinecarbodithioates with phenacyl bromide do not yield cyclization and failed to give the corresponding long-chain thiazolidine-2-thiones, but gave the corresponding 2-oxo-2-phenylethyl-2-alkanoylhydrazinecarbodithioates via nucleophilic substitution reaction. In addition, the synthesized compounds were tested for their corrosion prevention capabilities in acidic or in mineral oil media.

  DOI：

  10.1007/s00706-008-0933-1