1-methoxy-1-methyl-3-[4-(2-n-propoxy-2,4,4-trimethyl-2,3-dihydro-7-benzopyranyloxy)phenyl]-urea | 111578-25-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-methoxy-1-methyl-3-[4-(2-n-propoxy-2,4,4-trimethyl-2,3-dihydro-7-benzopyranyloxy)phenyl]-urea
• 英文别名: 1-methoxy-1-methyl-3-[4-[(2,4,4-trimethyl-2-propoxy-3H-chromen-7-yl)oxy]phenyl]urea
• CAS: 111578-25-7
• 化学式: C₂₄H₃₂N₂O₅
• 分子量: 428.528
• InChiKey: BUCLGRDHFWLXMC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  31
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  69.3
• 氢给体数：
  1
• 氢受体数：
  5

文献信息

• Process for the production of 1-lower alkoxy-1-lower alkyl-3-substituted phenylurea, and intermediate thereof and process for the production of the intermediate
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0434074A2

  公开（公告）日：1991-06-26

  A 1-lower alkoxy-1-lower alkyl-3-[4-(2-lower alkoxy-2,3-dihydro-7-benzopyranyloxy)phenyl]-urea is prepared by a process which comprises alkylating a novel 1-hydroxy-3-[4-(2-lower alkoxy-2,3-dihydro-7-benzopyranyloxy)phenyl]urea with a corresponding alkylating agent selected from the group consisting of a sulfuric acid ester and an alkyl halide in the presence of a basic compound. The 1-lower alkoxy-1-lower alkyl-3-[4-(2-lower alkoxy-2,3-dihydro-7-benzopyranyloxy)phenyl]urea has a herbicidal activity. New intermediates and processes for production thereof are also disclosed.

  一种 1-低级烷氧基-1-低级烷基-3-[4-(2-低级烷氧基-2,3-二氢-7-苯并吡喃氧基)苯基]脲的制备方法包括在碱性化合物存在下，将新型 1-羟基-3-[4-(2-低级烷氧基-2,3-二氢-7-苯并吡喃氧基)苯基]脲与选自硫酸酯和烷基卤化物组成的组中的相应烷基化剂烷基化。1-低级烷氧基-1-低级烷基-3-[4-(2-低级烷氧基-2,3-二氢-7-苯并吡喃氧基)苯基]脲具有除草活性。此外，还公开了新的中间体及其生产工艺。