Cd2(1-[2-(N,N-dimethylamino)ethyl]-5-mercapto-1H-tetrazole)2I4 | 1318743-30-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: Cd2(1-[2-(N,N-dimethylamino)ethyl]-5-mercapto-1H-tetrazole)2I4
• 英文别名: Cd2(MTZ)2I4
• CAS: 1318743-30-4
• 化学式: C₁₀H₂₂Cd₂I₄N₁₀S₂
• 分子量: 1078.92
• InChiKey: UROMTYPWICAABI-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1-(2-二甲基氨基乙基)-1H-5-巯基-四氮唑 、 cadmium(II) iodide 以 甲醇 、 水 为溶剂， 以65%的产率得到Cd2(1-[2-(N,N-dimethylamino)ethyl]-5-mercapto-1H-tetrazole)2I4
  参考文献：
  名称：

  Anion-mediated self-assembly: Five Cd(ІІ) coordination aggregates with a mercaptotetrazole ligand

  摘要：

  Five Cd(II) complexes, {[Cd-4(MTZ)(2)(H2O)(2)Cl-8]center dot 0.5H(2)O}(n) (1), [Cd(MTZ)(2)Br-2] (2), [Cd-2(MTZ)(2)I-4] (3), [Cd-2(MTZ)(2)(H2O)(8)] (SO4)(2) (4). {[Cd(MTZ)(2)(H2O)2](ClO4)2}(n) (5), based on different anions with the mercaptotetrazole ligand MTZ (MTZ = 1-(2-dimethylamino-ethyl)-5-mercapto-1H-tetrazole) have been synthesized. Employment of different anions can result in structural diversity in 1-5. In 1, the Cd(II) ions make use of mu(2)-Cl, mu(3)-Cl bridging each other to form a novel Cd4Cl8 inorganic network structure. On the other hand, the 2D structure is further stabilized by MTZ as a tridentate bridging organic ligand holding three adjacent Cd(II) ions. In 2, MTZ as a terminal ligand coordinates with a Cd(II) ion to form a mononuclear structure. As a mu(2), eta(2) bridging ligand, MTZ links Cd(n) ions to form a dimeric structures in 3 and 4, and a 1D infinite chain in 5. In addition, the luminescent properties of 1-5 have been investigated in the solid state at room temperature. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.05.038