3β-acetoxy-11-oxo-oleanadien-(12.18)-oic acid-(30) | 61878-51-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3β-acetoxy-11-oxo-oleanadien-(12.18)-oic acid-(30)
• 英文别名: 3β-Acetoxy-11-oxo-oleanadien-(12.18)-saeure-(30)；(2S,4aS,6aR,6aS,6bR,8aR,10S,12aS)-10-acetyloxy-2,4a,6a,6b,9,9,12a-heptamethyl-13-oxo-4,5,6,6a,7,8,8a,10,11,12-decahydro-3H-picene-2-carboxylic acid
• CAS: 61878-51-1
• 化学式: C₃₂H₄₆O₅
• 分子量: 510.714
• InChiKey: YPFUHSICTUUYKT-YRPKSFQCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  37
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  80.7
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3β-acetoxy-11-oxo-oleanadien-(12.18)-oic acid-(30) 210.0 ℃ 、1.33 Pa 条件下， 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Terpenoids. VII.¹ Experiments in the Glycyrrhetic Acid Series

  摘要：

  DOI：

  10.1021/ja01645a008
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 氢氧化钾 作用下， 生成 3β-acetoxy-11-oxo-oleanadien-(12.18)-oic acid-(30)
  参考文献：
  名称：

  Fire blight of pears in Israel: infection, prevalence, intensity and efficacy of management actions

  摘要：

  The Pear production area in Israel is 1500 ha, most of which (ca 1200 ha) is located in the northern part of the country. Fire blight (caused by the bacterium Erwinia amylovora (Burrill) Winslow et al.) was first observed in Israel in that region (in 1985) and the disease has prevailed there since then. In a comprehensive survey conducted in Israel in 1996-1999, data were collected and observations were made yearly in one-third to one-half of the pear production area. The aim was to document the prevalence and intensity of fire blight in commercial orchards and to use the data to evaluate the efficacy of management measures employed for its suppression, Regionwise, a severe fire blight epidemic developed in 1996, moderate epidemics developed in 1998 and 1999, and a mild epidemic developed in 1997. The intensity of fire blight in the preceding season in a specific orchard was more influential on current season severity in a season with a mild epidemic than in a season with a moderate epidemic. Analysis of disease onset records and weather data revealed that only a few (1-3) infection episodes occurred in individual orchards each year. Comparison of fire blight intensity in orchard-plots treated before green tip with copper hydroxide with nontreated plots revealed that the treatment had no effect on disease intensity during bloom. The efficacy of bactericide sprays applied during bloom was not related to the number of sprays applied but to the timing of spraying. Adequate control was achieved in orchard-plots sprayed soon before or after the occurrence of infection episodes.

  DOI：

  10.1007/bf02981831