Pt(2,9-dimethyl-1,10-phenanthroline)((Z)-MeO2CCHCHCO2Me)(HgMe)Cl | 153762-28-8

• 英文名称: Pt(2,9-dimethyl-1,10-phenanthroline)((Z)-MeO2CCHCHCO2Me)(HgMe)Cl
• CAS: 153762-28-8
• 化学式: C₂₁H₂₃ClHgN₂O₄Pt
• 分子量: 798.548
• InChiKey: PKXHTQZZDQXYMX-BQRHYOBJSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Pt(2,9-Me2-1,10-phentanthroline)(dimethylmaleate)] 、 氯化甲基汞 以 氯仿 为溶剂， 以>80的产率得到Pt(2,9-dimethyl-1,10-phenanthroline)((Z)-MeO2CCHCHCO2Me)(HgMe)Cl
  参考文献：
  名称：

  Trigonal-bipyramidal co-ordinatively saturated platinum(II) olefin complexes bearing an organomercury fragment in axial position

  摘要：

  The reactions of organomercury halides HgR'(Cl) (R' = Me, Et, Bu(t) or Ph) with complexes of the type [Pt(dmphen){(Z)-RO2CCH = CHCO2R}] (dmphen = 2,9-dimethyl-1,10-phenanthroline; R = Me, Et or Bu(t)) have been studied. The dmphen ligand with suitable 'in-plane' steric hindrance stabilizes five-co-ordinate adducts of general formula [PtCl(HgR')(dmphen){(Z)-ROCCH-CHCO2R}] when R' = alkyl. An influence of the nature of the Hg-bound hydrocarbyl group on the reaction course is observed. Thus, a cluster containing the Pt-Hg-Pt sequence was obtained when R' = Ph or Cl. The molecular structure of [PtCl(HgMe)(dmphen){(Z)-MeO2CCH=CHCO2Me}] (space group P2(1)/c; a = 13.079(2), b =1 3.167(2), c = 15.495(3) angstrom and beta = 94.18(2)-degrees] reveals a large trans influence of the organomercury fragment.

  DOI：

  10.1039/dt9930003421