bis(N,N-diethyldithiocarbamato)tin(II) | 17188-90-8

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: bis(N,N-diethyldithiocarbamato)tin(II)
• 英文别名: tin(II) diethyldithiocarbamate；Sn-DEDTC₂；diethyl-dithiocarbamic acid ; tin (II)-salt；Diaethyl-dithiocarbamidsaeure; Zinn(II)-Salz
• CAS: 17188-90-8
• 化学式: 2C₅H₁₀NS₂*Sn
• 分子量: 415.256
• InChiKey: KBOYRBQLZGISEE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.78
• 重原子数：
  9.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  bis(N,N-diethyldithiocarbamato)tin(II) 在 油胺 作用下， 反应 0.67h， 生成 tin (II) sulfide
  参考文献：
  名称：

  Phase-controlled synthesis and photocatalytic properties of SnS, SnS2 and SnS/SnS2 heterostructure nanocrystals

  摘要：

  A phase-controlled synthesis of well-defined tin sulphides, including SnS, SnS2 and SnS/SnS2 heterostructured materials, was developed by one-step pyrolysis method. Such a- phase-controlled process was realized by changing the amount of CS2 in the precursor, in which pure SnS and SnS2 flakes were obtained upon no CS2 involved or CS2 excessively existed, while SnS/SnS2 heterostructured material formed by adding a suitable amount of CS2 to the precursor, following the Ostwald ripening. As-prepared tin sulphides materials showed a wide-range UV-vis absorption (300-800 nm) and excellent photoresponse property; particularly, SnS/SnS2 heterostructured material showed improved photocatalytic performance on photodegrading organic dyes, compared with that of as-synthesized pure phases of SnS and SnS2 materials. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.materresbull.2013.02.082
• 作为产物：
  描述：

  tin(II) chloride dihdyrate 、 sodium N,N-diethyldithiocarbamate 以 乙醇 为溶剂， 反应 0.08h， 生成 bis(N,N-diethyldithiocarbamato)tin(II)
  参考文献：
  名称：

  Low-cost SnSx counter electrodes for dye-sensitized solar cells

  摘要：

  首次将SnS纳米片（NSs）、SnS纳米线（NWs）和SnS2纳米片作为对电极（CE）催化剂，在I3−/I−基染料敏化太阳能电池（DSC）系统中进行了合成和测试。研究发现，SnS NS基DSC的功率转换效率（Eff = 6.56%）与Pt（7.56%）相当，而SnS NW和SnS2 NS基DSC的Eff分别为5.00%和5.14%，表明SnSx在将三碘化物还原为碘化物方面具有优异的催化活性。

  DOI：

  10.1039/c3cc42679c

文献信息

• Crystal and molecular structure of a novel mixed ligand complex of tin(IV)
  作者：Suman Sharma、Rakesh Bohra、Ram C. Mehrotra

  DOI：10.1016/0277-5387(95)00391-6

  日期：1996.5

  Recrystallization of [BrSn(S2CNEt2)2(OC(CH3)CHCOCH3)] 1, formed from the reaction of Br2Sn(S2CNEt2)2 with Na(CH3COCHCOCH3) in 1:1 molar ratio yields 2, a unique derivative, which was characterized by X-ray crystallography. The geometry around tin(IV) is distorted octahedral, with the average SnS distance [2.548(4)Å] of the chelated dithiocarbamate being longer than the SnS distance [2.388(5)Å] of the

  由Br 2 Sn（S 2 CNEt 2）2与Na（CH 3 COCHCOCH 3）在1：1中反应形成的[BrSn（S 2 CNEt 2）2（OC（CH 3）CHCOCH 3）] 1重结晶。摩尔比产生2，这是一种独特的衍生物，其特征在于X射线晶体学。锡（IV）周围的几何形状呈八面体形，螯合的二硫代氨基甲酸酯的平均SnS距离[2.548（4）Å]长于五元螯合的SnS距离[2.388（5）Å]配体部分。