辛基甲烷硫代磺酸酯 | 7559-45-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 磺酰类
• 中文名称: 辛基甲烷硫代磺酸酯
• 英文名称: n-octyl methanethiosulfonate
• 英文别名: 1-Methylsulfonylsulfanyloctane
• CAS: 7559-45-7
• 化学式: C₉H₂₀O₂S₂
• 分子量: 224.389
• InChiKey: TUYNUTSGVHXNKX-UHFFFAOYSA-N

物化性质

• 沸点：
  350.6±11.0 °C(Predicted)
• 密度：
  1.057±0.06 g/cm3(Predicted)
• 溶解度：
  可溶于乙腈（少许）、氯仿（少许）

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  67.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1-溴辛烷 、 potassium methanethiosulphonate 以 水 、 丙酮 为溶剂， 生成 辛基甲烷硫代磺酸酯
  参考文献：
  名称：

  烷基和芳基硫代硫酸盐。

  摘要：

  DOI：

  10.1021/jm00335a028

文献信息

• Compositions, methods, systems, and kits for affinity purification
  申请人：Nicol R. Gordon

  公开号：US20070148721A1

  公开（公告）日：2007-06-28

  The invention provides a method of separating proteins and peptides of a sample comprising contacting the sample with a Pd coordination compound. The Pd coordination compound binds to sulfur and/or nitrogen groups and thus is useful for purifying biomolecules comprising cysteine, methionine, histidine amino acids or derivatized amino acids/residues comprising sulfur or nitrogen groups which bind to coordination sites on the Pd coordination compounds. The invention also relates to methods, systems and kits for using the Pd coordination compound.
• [EN] COMPOSITIONS, METHODS, SYSTEMS, AND KITS FOR AFFINITY PURIFICATION<br/>[FR] COMPOSITIONS, PROCEDES, SYSTEMES, ET KITS POUR PURIFICATION D'AFFINITE
  申请人：AGILENT TECHNOLOGIES INC

  公开号：WO2006026416A1

  公开（公告）日：2006-03-09

  The invention provides a method of separating proteins and peptides of a sample comprising contacting the sample with a Pt coordination compound stably associated with a substrate. The Pt coordination compound binds to sulfur and/or nitrogen groups and thus is useful for purifying biomolecules comprising cysteine, methionine, histidine amino acids or derivatized amino acids/residues comprising sulfur or nitrogen groups which bind to coordination sites on the Pt coordination compounds, including their modified, unmodified, processed and unprocessed forms. Also disclosed are methods, systems and kits for using the Pt coordination compound. In certain embodiments the purified proteins and/or peptides may be analyzed using, for example, mass spectrometry to identify and quantify proteins and/or peptides in a sample, such as a proteome or peptidome.
• Alkyl and Aryl Thiolsulfonates
  作者：James P. Weidner、Seymour S. Block

  DOI：10.1021/jm00335a028

  日期：1964.9