Lubricant and functional fluids, and additive concentrates, are composed of a) at least one overbased zinc dialkyldithiophosphate characterized in that (i) each of the alkyl groups is a primary alkyl group containing from 6 to 10 carbon atoms, (ii) the overbased to neutral ratio of the dithiophosphate is 0.96 or above as determined by ³¹P nmr, (iii) the integrated ³¹P nmr spectrum of the dithiophosphate shows less than about 0.25 area percent phosphorus at about 80 ppm, (iv) the integrated ³¹P nmr spectrum of the dithiophosphate shows essentially no phosphate species at 5 to 15 ppm, and (v) the dithiophosphate exhibits a copper weight loss in ASTM Test Method D2619 of 0.70 maximum; b) at least one hindered phenolic antioxidant or at least one aromatic secondary amine antioxidant; and c) at least one overbased alkaline earth metal sulfurized alkyl phenate having a TBN as determined by ASTM Test Method D2896 of at least 200 or at least one alkaline earth metal alkyl aromatic sulfonate. Preferred zinc dithiophosphates are further characterized in that the integrated ³¹P nmr spectrum of the dithiophosphate shows essentially no phosphorus species at 95 to 98 ppm. High thermal and oxidative ability is achieved.
润滑剂和功能性液体以及添加剂浓缩物由a)至少一种过基
二烷基二硫代磷酸锌组成,其特征在于(i)每个烷基是含有6至10个碳原子的伯烷基,(ii)根据³¹P nmr测定,
二硫代磷酸锌的过基与中性之比为0.96或以上,(iii)
二硫代磷酸锌的³¹P nmr综合光谱在约80ppm处显示出小于约0.(iv)
二硫代磷酸酯的整合 ³¹P nmr 光谱在 5 至 15 ppm 时基本上不显示
磷酸盐种类,以及 (v)
二硫代磷酸酯在 ASTM 试验方法 D2619 中显示的
铜重量损失为 0.70 的最大值; b) 至少一种受阻
酚类抗氧化剂或至少一种芳香族仲胺
抗氧化剂;以及 c) 至少一种过基碱土
金属
硫化烷基
酚盐,其 TBN 经 ASTM 试验方法 D2896 测定至少为 200 或至少一种碱土
金属芳香族烷基
磺酸盐。优选的
二硫代磷酸锌的进一步特征是,
二硫代磷酸锌的综合 ³¹P nmr 光谱在 95 至 98 ppm 范围内基本上不显示
磷种类。热氧化能力强。