1-{1-methyl-2-[1-methyl-2-(1-methyl-2-propoxy-ethoxy)-ethoxy]-ethoxy}-propan-2-ol | 58797-36-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-{1-methyl-2-[1-methyl-2-(1-methyl-2-propoxy-ethoxy)-ethoxy]-ethoxy}-propan-2-ol
• 英文别名: Tetrapropylene glycol monopropyl ether；1-[1-[1-(1-propoxypropan-2-yloxy)propan-2-yloxy]propan-2-yloxy]propan-2-ol
• CAS: 58797-36-7
• 化学式: C₁₅H₃₂O₅
• 分子量: 292.416
• InChiKey: GDDWCUCSVXSHAZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  20
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  57.2
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  sodium n-propoxide 、 methyloxirane 以 丙醇 为溶剂， 生成 1-{1-methyl-2-[1-methyl-2-(1-methyl-2-propoxy-ethoxy)-ethoxy]-ethoxy}-propan-2-ol
  参考文献：
  名称：

  Chlebicki,J., Roczniki Chemii, 1974, vol. 48, p. 1241 - 1253

  摘要：

  DOI：

文献信息

• LITHOGRAPHIC PRINTING PLATE PRECURSOR AND LITHOGRAPHIC PRINTING PROCESS
  申请人：OOHASHI Hidekazu

  公开号：US20110054212A1

  公开（公告）日：2011-03-03

  A lithographic printing plate precursor, which comprises: a support; an image-recording layer; and a protective layer, in this order, wherein at least one of the image-recording layer and the protective layer comprises a phosphonium salt having a specific structure, and a lithographic printing process, which comprises: exposing a lithographic printing plate precursor; supplying an oil-based ink and a fountain solution comprising a phosphonium salt having a specific structure to the exposed lithographic printing plate precursor on a printing machine to remove an unexposed area of an image-recording layer; and conducting printing.

  一种光刻印刷版前体，包括：支撑体；图像记录层；以及保护层，依次排列，其中图像记录层和保护层中至少有一层包含具有特定结构的磷酸铵盐；以及一种光刻印刷工艺，包括：曝光光刻印刷版前体；在印刷机上向曝光的光刻印刷版前体提供具有特定结构的磷酸铵盐的油墨和喷泉溶液，以去除图像记录层中未曝光区域；进行印刷。
• Curable liquid resin, process for the production thereof, and use thereof
  申请人：TOYO INK MANUFACTURING CO., LTD.

  公开号：EP0693507A2

  公开（公告）日：1996-01-24

  A curable liquid resin suitable for use as a coating composition capable of forming a film, the curable liquid resin is a copolymer obtainable from (A) a monomer of the formula (1) or (2)         CH₂=C (R¹) COO-R   (1)         CH₂=C(R³)COO(CnH2nO)m-R⁴   (2) and (B) at least one monomer chosen from (B1) a monomer obtainable by reacting an ethylenically unsaturated epoxide (a) with a fatty acid (b) of the formula (3)         R⁵COOH   (3) (B2) a monomer of the formula (4),         CH₂=C(R⁶)CONR⁷R⁸   (4) and (B3) a monomer whose molecule has at least two ethylenically unsaturated double bonds.

  一种可固化液态树脂，适合用作能够成膜的涂料组合物，该可固化液态树脂是一种共聚物，可从以下物质中获得 (A) 式(1)或(2)的单体 ch₂=c (r¹) coo-r (1) CH₂=C(R³)COO(CnH2nO)m-R⁴ (2) 和 (B) 至少一种单体，选自 (B1) 可通过乙烯基不饱和环氧化物 (a) 与式 (3) 的脂肪酸 (b) 反应获得的单体 R⁵COOH (3) (B2) 式(4)的单体、 ch₂=c(r⁶)conr⁷r⁸ (4) 和 (B3) 分子中至少有两个乙烯不饱和双键的单体。
• CURABLE LIQUID RESIN COMPOSITION
  申请人：TOYO INK MANUFACTURING CO., LTD.

  公开号：EP0842960A1

  公开（公告）日：1998-05-20

  A curable liquid resin composition containing 100 parts by weight of the following (meth)acrylic liquid resin (A) and 1 to 1,000 parts by weight of a (meth)acrylic monomer (B) having an unsaturated double bond in its molecule and having a number average molecular weight of 1,000 or less, the (meth)acrylic liquid resin (A) being a liquid resin which is obtained by polymerizing monomers containing an alkyl (meth)acrylate monomer (a-1-1) of the formula (1),         CH2 C(R1)COO-R2     (1)    wherein R1 is a hydrogen atom or CH3 and R2 is an alkyl group, and/or an alkylene glycol (meth)acrylate monomer (a-1-2) of the formula (2),         CH2=C(R1)COO(CnH2nO)mR3     (2)    wherein R1 is a hydrogen atom or CH3, R3 is an alkyl group or a phenyl group, n is an integer of 1 to 3, and m is an integer of 3 to 25, and other polymerizable vinyl monomer (a-2), an average of molecular weights of all the monomers being 100 to 1,500, the liquid resin having a number average molecular weight of 10,000 to 200,000 and a viscosity of 1 to 10,000 poise (measured at 50°C), or a modified product of the above liquid resin, the curable liquid resin composition can form a film as a film-forming material or as a resin for an adhesive without using a solvent and give a cured film.

  一种可固化的液体树脂组合物，含有 100 重量份的下列(甲基)丙烯酸液体树脂(A)和 1 至 1,000 重量份的(甲基)丙烯酸单体(B)，(甲基)丙烯酸单体(B)的分子中含有不饱和双键，其平均分子量为 1,000 或更小，(甲基)丙烯酸液体树脂(A)是一种液体树脂，它是由含有式(1)的(甲基)丙烯酸烷基单体(a-1-1)的单体聚合而成、 CH2 C(R1)COO-R2 (1) 其中 R1 是氢原子或 CH3，R2 是烷基、 和/或式（2）的亚烷基二醇（甲基）丙烯酸酯单体（a-1-2）、 CH2=C(R1)COO(CnH2nO)mR3 (2) 其中 R1 是氢原子或 CH3，R3 是烷基或苯基，n 是 1 至 3 的整数，m 是 3 至 25 的整数、 和其他可聚合的乙烯基单体（a-2），所有单体的平均分子量为 100 至 1,500 ，液态树脂的数均分子量为 10,000 至 200,000 ，粘度为 1 至 10,000 泊（50°C 时测得），或上述液态树脂的改性产品，该可固化液态树脂组合物可作为成膜材料或粘合剂用树脂形成薄膜，而无需使用溶剂，并得到固化薄膜。
• Vinyl-group-containing dendrimer and curable composition
  申请人：TOYO INK MANUFACTURING CO., LTD.

  公开号：EP0899286A1

  公开（公告）日：1999-03-03

  A vinyl-group-containing dendrimer which can serve to decrease the amount of a low-molecular-weight compound having safety and performance problems and which can give a resin composition having a high molecular weight but a low viscosity and having excellent performances as a coating (film), the composition being capable of forming a film (coating) by a conventional coating method using a roll coater or knife coater or by a conventional printing method such as an offset printing method, a gravure printing method, a letterpress printing method or a screen printing method, the composition being curable by any one of conventional triggers such as heating, ultraviolet light, infrared light, electron beam and γ ray, the composition comprising a vinyl-group-containing dendrimer (A) comprising a core portion, branching portions, branches and at least 4 terminal portions and having a vinyl group as a terminal portion and a long-chain group and a curable unsaturated-group-containing compound (B), and the composition comprising a vinyl-group-containing dendrimer (A) obtained by reacting a polyfunctional compound (a) having at least three active-hydrogen-containing groups in a terminal per molecule and having at least five active hydrogen atoms per molecule with a long-chain-group-containing compound (b) having a functional group reactive with an active hydrogen atom so as to leave part of the active hydrogen atoms, thereby obtaining a long-chain-group-containing multi-branched compound (X), and reacting the long-chain-containing multi-branched compound (X) with a vinyl-group-containing compound (c) having a functional group reactive with an active hydrogen atom and a curable unsaturated-group-containing compound (B),

  一种含乙烯基的树枝状聚合物，它可以减少存在安全和性能问题的低分子量化合物的用量，并能得到一种分子量高但粘度低、作为涂层（薄膜）性能优异的树脂组合物，该组合物能够通过使用辊涂机或刀涂机的传统涂布方法或通过胶版印刷法等传统印刷方法形成薄膜（涂层）、该组合物可通过加热、紫外线、红外线、电子束和 γ 射线等任何一种常规触发器固化，该组合物包括含乙烯基的树枝状聚合物 (A)，该树枝状聚合物 (A) 包括一个核心部分、分支部分、至少 4 个末端部分和一个分支部分、和可固化的含不饱和基团的化合物（B）、该组合物包括含乙烯基的树枝状聚合物（A），该树枝状聚合物（A）是通过将每分子末端至少有三个含活性氢基团且每分子至少有五个活性氢原子的多官能团化合物（a）与含长链基团的化合物（b）反应而得到的，该化合物（b）具有与活性氢原子反应的官能团，从而留下部分活性氢原子、从而得到含长链基团的多支链化合物 (X)，并将含长链基团的多支链化合物 (X) 与具有与活性氢原子反应的官能团的含乙烯基基团的化合物 (c) 和可固化的含不饱和基团的化合物 (B) 反应、
• Multi-branched compounds and curable composition
  申请人：TOYO INK MFG. CO., LTD.

  公开号：EP0899287A1

  公开（公告）日：1999-03-03

  A compound obtainable by reacting a core compound obtainable from a Michael addition reaction of polyamino compound (a) having at least one primary or secondary amino group and an active-hydrogen-containing (meth)acrylic compound (b-1), with a vinyl-group-containing compound (c) having a functional group reactable with the active hydrogen, for use as a film forming material such as a coating composition or an ink or as a resin for a sealant, a molding material, an adhesive or tackiness agent or for use as a curing agent or a reactive diluent for a curable composition.

  一种化合物，可通过具有至少一个伯氨基或仲氨基的聚氨基化合物（a）与含活性氢的（甲基）丙烯酸化合物（b-1）的迈克尔加成反应得到的核心化合物，与具有可与活性氢反应的官能团的含乙烯基化合物（c）反应得到，可用作成膜材料，如涂料组合物或油墨，或用作密封剂的树脂、成型材料、粘合剂或增粘剂，或用作固化剂或可固化组合物的活性稀释剂。