α-fluoro-3-phenoxybenzyl 2,2-dimethyl-3-(β,β-dichlorovinyl)cyclopropane-1-carboxylate | 74569-26-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: α-fluoro-3-phenoxybenzyl 2,2-dimethyl-3-(β,β-dichlorovinyl)cyclopropane-1-carboxylate
• 英文别名: [Fluoro-(3-phenoxyphenyl)methyl] 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate
• CAS: 74569-26-9
• 化学式: C₂₁H₁₉Cl₂FO₃
• 分子量: 409.284
• InChiKey: OFOQBTJFHIZCOP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  27
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  α-fluoro-3-phenoxybenzyl bromide 、 二氯菊酸 在 盐酸 、 sodium hydroxide 、 三乙胺 作用下， 以 1,2-二氯乙烷 、 丙酮 为溶剂， 以87%的产率得到α-fluoro-3-phenoxybenzyl 2,2-dimethyl-3-(β,β-dichlorovinyl)cyclopropane-1-carboxylate
  参考文献：
  名称：

  Pesticidal fluorinated esters of the pyrethrin or pyrethroid type

  摘要：

  这项发明涉及新型杀虫酯，属于拟除虫菊酯或拟除虫菊酯类别，其中与酯基碳氧化物和/或酯基氧相结合的亚甲基基团带有氟取代基。该发明的化合物对包括苍蝇、飞蛾、蚜虫和甲虫在内的昆虫害虫以及包括蜱在内的螨类害虫具有活性。

  公开号：

  US04283414A1

文献信息

• HARNEY, D. W. G.;LEHMAN, P. G.;RUNDLE, J. C.
  作者：HARNEY, D. W. G.、LEHMAN, P. G.、RUNDLE, J. C.

  DOI：——

  日期：——
• Fluoro-substituted pyrethroid-type esters, processes for their preparation, intermediates for use in such processes, compositions for insecticidal use, and methods of combating insect pests
  申请人：ICI AUSTRALIA LIMITED

  公开号：EP0006354B1

  公开（公告）日：1984-09-26
• US4283414A
  申请人：——

  公开号：US4283414A

  公开（公告）日：1981-08-11
• US4376784A
  申请人：——

  公开号：US4376784A

  公开（公告）日：1983-03-15
• [EN] PESTICIDAL COMPOSITION COMPRISING EMAMECTIN<br/>[FR] COMPOSITION PESTICIDE A BASE D'EMAMECTINE
  申请人：NOVARTIS AG

  公开号：WO2000002453A1

  公开（公告）日：2000-01-20

  The invention accordingly relates to a composition for the control of insects or representatives of the order Acarina, which is characterised in that it contains a quantitatively variable combination of emamectin in free form or in salt form, as well as inter alia one or more of the compound: Aldicarb; Azinphos-methyl; Benfuracarb; Bifenthrin; Buprofezin; Carbofuran; Carbosulfan; Cartap; Chlorfluazuron; Chlorpyrifos; Cyfluthrin; Lambda-Cy-halothrin; Alpha-cypermethrin; zeta-Cypermethrin; Deltamethrin; Diflubenzuron; Endosulfan; Ethiofencarb; Fenitrothion; Fenobucarb; Fenvalerate; Formothion; Methiocarb; Heptenophos; Imidacloprid; Isoprocarb; Methamidophos; Methomyl; Mevinphos; Parathion; Parathion-methyl; Phosalone; Pirimicarb; Propoxur; Teflubenzuron; Terbufos; Triazamate; Fenobucarb; Tebufenozide; Fipronil; beta-Cyfluthrin; Silafluofen; Fenpyroximate; Pyridaben; Fenazaquin; Pyriproxyfen; Pyrimidifen; Nitenpyram; NI-25, Acetamiprid; Avermectin; an insect-active extract from a plant; a preparation containing insect-active nematodes; a preparation obtainable from Bacillus subtilis; Azinphos A; Azinphos M; Azocyclotin; Bendiocarb; Bensultap; Betacyfluthrin; BPMC; Tebufenpyrad; Tebupirimphos; Tefluthrin; Temephos; Terbam; Tetrachlor-vinphos; Thiafenox; Thiodicarb; or Spinosad, in free form or in salt form, and at least one excipient; a process for the control of pests, a process for the preparation of the composition, the use thereof and the plant propagation material treated therewith, as well as the use of emamectin in the preparation of the composition.