glucosone | 184047-23-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: glucosone
• 英文别名: 3,4,5,6-Tetrahydroxy-2-oxohexanal
• CAS: 184047-23-2
• 化学式: C₆H₁₀O₆
• 分子量: 178.142
• InChiKey: DCNMIDLYWOTSGK-UHFFFAOYSA-N

物化性质

• 沸点：
  481.0±45.0 °C(Predicted)
• 密度：
  1.574±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -2.9
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  115
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  glucosone 、 4-甲基氨基硫脲 以 乙醇 为溶剂， 反应 2.0h， 以52%的产率得到1-methyl-3-[[3,4,5,6-tetrahydroxy-1-(methylcarbamothioylhydrazinylidene)hexan-2-ylidene]amino]thiourea
  参考文献：
  名称：

  Synthesis and biological activity of glucosone bisthiosemicarbazones and their copper complexes

  摘要：

  DOI：

  10.1007/bf00758298

文献信息

• STABILIZED BIOFILLER PARTICLES AND POLYMER COMPOSITIONS INCLUDING THE SAME
  申请人：Xinova, LLC

  公开号：EP3655466A2

  公开（公告）日：2020-05-27
• METHOD FOR PRODUCING FRUCTOSE
  申请人：ANNIKKI GMBH

  公开号：US20150353978A1

  公开（公告）日：2015-12-10

  A method for the enzymatic production of D-fructose from D-glucose in a one-pot synthesis, wherein D-glucose is oxidized enzymatically to D-glucosone and D-glucosone is reduced enzymatically to D-fructose and the use of the D-fructose produced in this way for the production of furan derivatives.
• SYSTEMS AND METHODS FOR ENZYMATIC OXYGEN REMOVAL
  申请人：SILVER BEAR, INC.

  公开号：US20200359660A1

  公开（公告）日：2020-11-19

  Systems and methods for packing solutions for oxygen-sensitive articles such as food, beverages, and pharmaceuticals, as well as biological samples and/or cultures are disclosed. In preferred systems and methods, oxygen is removed using a bi-enzymatic reaction sequence that recycles and depletes oxygen to extinction, preferably using an oxidase and a catalase as catalysts and a carbohydrate as co-substrate while at least one the enzymes is in a hydrogel or other polymeric formulation.
• [DE] VERFAHREN ZUR HERSTELLUNG VON FRUCTOSE<br/>[EN] METHOD FOR PRODUCING FRUCTOSE<br/>[FR] PROCÉDÉ DE PRODUCTION DE FRUCTOSE
  申请人：ANNIKKI GMBH

  公开号：WO2014122167A1

  公开（公告）日：2014-08-14

  Verfahren zur enzymatischen Herstellung von D-Fructose aus D-Glucose in einer Ein-Topf- Reaktion, wobei D-Glucose enzymatisch zu D-Glucoson oxidiert und D-Glucoson enzymatisch zu D-Fructose reduziert wird und die Verwendung der derart hergesteilen D- Fructose zur Herstellung von Furanderivaten.
• [EN] INSOLUBLE SACCHARIDE-COMPRISING COMPOSITIONS AND RELATED METHODS<br/>[FR] COMPOSITIONS CONTENANT UN SACCHARIDE INSOLUBLE ET PROCÉDÉS ASSOCIÉS
  申请人：[en]CAMBRIDGE GLYCOSCIENCE LTD

  公开号：WO2022223836A2

  公开（公告）日：2022-10-27

  Compositions comprising soluble oligosaccharides and insoluble saccharides are provided. Methods for the formation of the compositions, food products, baked goods, or sweeteners, including the enzymatic production of the saccharides, the mixtures with various ratios and properties of the saccharides, and the uses of the same are also provided.