2-[9]phenanthryl-ethylamine | 130752-14-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2-[9]phenanthryl-ethylamine
• 英文别名: 2-[9]Phenanthryl-aethylamin；9-(Aminoethyl)phenanthrene；2-phenanthren-9-ylethanamine
• CAS: 130752-14-6
• 化学式: C₁₆H₁₅N
• 分子量: 221.302
• InChiKey: OAFLPVFYZZCYLC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-[9]phenanthryl-ethylamine 在 间苯二甲腈 作用下， 以 水 、 乙腈 为溶剂， 反应 70.0h， 以30%的产率得到phenanthro<1,10-d,e>piperidine
  参考文献：
  名称：

  Photosensitized synthesis of phenanthrene heterocycles from 1- and 9-(aminoalkyl)phenanthrenes

  摘要：

  The photosensitized electron transfer reactions of several 1- and 9-(aminoalkyl)phenanthrenes with metadicyanobenzene have been investigated. These reactions provide an efficient method of synthesis for the skeletal structures of the aporphine, phenanthropiperidine, and phenanthroazepine alkaloids.

  DOI：

  10.1016/s0040-4039(00)75831-x
• 作为产物：
  描述：

  1-Nitro-2--aethen 在 盐酸 、 乙醇 、 溶剂黄146 作用下， 生成 2-[9]phenanthryl-ethylamine
  参考文献：
  名称：

  Occupational stress in universities: Staff perceptions of the causes, consequences and moderators of stress

  摘要：

  In recent years, the Australian university sector has undergone large-scale organizational change, including restructuring, downsizing and government funding cuts. At the same tune, research front across the globe reports an alarming increase in the occupational stress experienced by university staff. We report on the first phase of a longitudinal investigation of occupational stress. A total of 22 focus groups were conducted with a representative sample of 178 academic and general staff from 15 Australian universities. The groups focused on understanding staff's experience of occupational stress, and perceptions of the sources, consequences and moderators of stress. Both general and academic staff reported a dramatic increase in stress during the previous 5 years. As a group, academic staff reported higher levels of stress than general staff. Five major or sources of stress were identified including: insufficient funding and resources; work overload; poor management practice; job insecurity; and insufficient recognition and reward. The majority of groups reported that job-related stress was having a deleterious impact on their professional work and personal welfare. Aspects of the work environment (support front co-workers and management, recognition and achievement, high morale, flexible working conditions), and personal coping strategies (stress management techniques, work/non-work balance, tight role boundaries and lowering standards), were reported to help staff cope with stress. The findings provide a timely insight into the experience of stress within universities.

  DOI：

  10.1080/02678370117944

文献信息

• Exciplexes
  申请人：——

  公开号：US20030108892A1

  公开（公告）日：2003-06-12

  Compounds capable of forming an intramolecular exciplex on photoirradiation of the compound in water comprise two exciplex forming partners, one being a donor moiety and the other an acceptor moiety, each having at least one aromatic nucleus and being connected by a saturated aliphatic chain having the flexibility to allow said partners to come into exciplex forming relationship. The compounds may be used as labels for oligonucleotides. Certain of the compounds display pH sensitive emission.

  在水中光照条件下能够形成分子内激发态络合物的化合物包括两个激发态络合物形成合作伙伴，一个是给体基团，另一个是受体基团，每个基团至少具有一个芳香环，并通过具有足够柔韧性的饱和脂肪链连接，使这些合作伙伴能够形成激发态络合物关系。这些化合物可用作寡核苷酸的标记。其中一些化合物显示出pH敏感的发射特性。
• EXCIPLEXES
  申请人：THE VICTORIA UNIVERSITY OF MANCHESTER

  公开号：EP1242360A2

  公开（公告）日：2002-09-25
• [EN] EXCIPLEXES<br/>[FR] EXCIPLEXES
  申请人：UNIV MANCHESTER

  公开号：WO2001046121A2

  公开（公告）日：2001-06-28

  Compounds capable of forming an intramolecular exciplex on photoirradiation of the compound in water comprise two exciplex forming partners, one being a donor moiety and the other an acceptor moiety, each having at least one aromatic nucleus and being connected by a saturated aliphatic chain having the flexibility to allow said partners to come into exciplex forming relationship. The compounds may be used as labels for oligonucleotides. Certain of the compounds display pH sensitive emission.
• Occupational stress in universities: Staff perceptions of the causes, consequences and moderators of stress
  作者：N. A. Gillespie、M. Walsh、A.H. Winefield、J. Dua、C. Stough

  DOI：10.1080/02678370117944

  日期：2001.1

  In recent years, the Australian university sector has undergone large-scale organizational change, including restructuring, downsizing and government funding cuts. At the same tune, research front across the globe reports an alarming increase in the occupational stress experienced by university staff. We report on the first phase of a longitudinal investigation of occupational stress. A total of 22 focus groups were conducted with a representative sample of 178 academic and general staff from 15 Australian universities. The groups focused on understanding staff's experience of occupational stress, and perceptions of the sources, consequences and moderators of stress. Both general and academic staff reported a dramatic increase in stress during the previous 5 years. As a group, academic staff reported higher levels of stress than general staff. Five major or sources of stress were identified including: insufficient funding and resources; work overload; poor management practice; job insecurity; and insufficient recognition and reward. The majority of groups reported that job-related stress was having a deleterious impact on their professional work and personal welfare. Aspects of the work environment (support front co-workers and management, recognition and achievement, high morale, flexible working conditions), and personal coping strategies (stress management techniques, work/non-work balance, tight role boundaries and lowering standards), were reported to help staff cope with stress. The findings provide a timely insight into the experience of stress within universities.
• Photosensitized synthesis of phenanthrene heterocycles from 1- and 9-(aminoalkyl)phenanthrenes
  作者：Frederick D. Lewis、G.Dasharatha Reddy、Bliss E. Cohen

  DOI：10.1016/s0040-4039(00)75831-x

  日期：1994.1

  The photosensitized electron transfer reactions of several 1- and 9-(aminoalkyl)phenanthrenes with metadicyanobenzene have been investigated. These reactions provide an efficient method of synthesis for the skeletal structures of the aporphine, phenanthropiperidine, and phenanthroazepine alkaloids.