Dimethyl 1,1,5,5,7,7,11,11-octafluoro-3,9-bis(trifluoromethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane-3,9-dicarboxylate | 934521-80-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Dimethyl 1,1,5,5,7,7,11,11-octafluoro-3,9-bis(trifluoromethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane-3,9-dicarboxylate
• CAS: 934521-80-9
• 化学式: C₁₃H₆F₁₄O₈
• 分子量: 556.163
• InChiKey: ZFXOJKLUVXZVSR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  35
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  89.5
• 氢给体数：
  0
• 氢受体数：
  22

反应信息

• 作为反应物：
  描述：

  Dimethyl 1,1,5,5,7,7,11,11-octafluoro-3,9-bis(trifluoromethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane-3,9-dicarboxylate 在 氢氧化钾 、 水 作用下， 以 甲醇 为溶剂， 反应 2.0h， 以93%的产率得到
  参考文献：
  名称：

  NOVEL FLUORINE-CONTAINING ETHER COMPOUND

  摘要：

  一种含氟醚化合物，其氟含量增加，氟含量通过对包括由以下式（I）表示的重复单元的聚合物进行氟化而增强：其中Rh1表示二价连接基团；Rf2表示全氟烷基烯基团；Rf3和Rf4中的每一个独立地表示氟原子、全氟烷基团或全氟烷氧基团，Rf2、Rf3和Rf4中的任意两个可以结合在一起形成环。

  公开号：

  US20090018350A1
• 作为产物：
  描述：

  甲醇 、 1,1,5,5,7,7,11,11-Octafluoro-3,9-bis(trifluoromethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane-3,9-dicarbonyl fluoride 反应 3.0h， 以51%的产率得到Dimethyl 1,1,5,5,7,7,11,11-octafluoro-3,9-bis(trifluoromethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane-3,9-dicarboxylate
  参考文献：
  名称：

  WO2007/43672

  摘要：

  公开号：

文献信息

• NOVEL CROSSLINKABLE FLUORINE-CONTAINING ETHER COMPOUND
  申请人：ITO Takayuki

  公开号：US20080255337A1

  公开（公告）日：2008-10-16

  A crosslinkable fluorine-containing compound, which is an adduct compound having a crosslinkable group, wherein the adduct compound is an adduct of a fluorine-containing compound having, per molecule, 2 or more terminal fluorine-containing vinyl groups each directly bonded to an oxygen atom, and a compound having 2 or more groups represented by —XH, where X represents an oxygen atom or a sulfur atom.
• NOVEL FLUORINE-CONTAINING SPIROACETAL COMPOUND AND METHOD OF PRODUCING THE SAME
  申请人：Ito Takayuki

  公开号：US20090149664A1

  公开（公告）日：2009-06-11

  A fluorine-containing spiroacetal compound represented by the following formula (A): wherein X represents >C(CF 3 )(Y) or >C═CF 2 , in which Y represents —CF 2 OCOR 1 , —COOR 2 , —COF, or —CH 2 OR 3 , R 1 represents an alkyl or cycloalkyl group having at least one fluorine atom, R 2 represents a hydrogen atom, an alkali metal, an alkaline earth metal, an alkyl group, or a cycloalkyl group and R 3 represents a hydrogen atom or an acyl group; wherein the alkyl or cycloalkyl group for R 1 may have a substituent other than fluorine atom; the alkyl or cycloalkyl group for R 2 may have a substituent; and the acyl group for R 3 may have a substituent.
• NOVEL FLUORINE-CONTAINING POLYMER AND METHOD OF PRODUCING FLUORINE-CONTAINING POLYMER
  申请人：Ito Takayuki

  公开号：US20090318650A1

  公开（公告）日：2009-12-24

  A method of producing a fluorine-containing polymer, containing conducting an addition polymerization of a fluorine-containing compound having 2 or more terminal fluorine-containing vinyl groups each directly bonded to an oxygen atom per molecule, and a compound having 2 or more groups represented by —XH, where X represents an oxygen atom or a sulfur atom; and a fluorine-containing polymer comprising a repeating unit represented by formula (i): wherein Rf 1 represents a perfluoroalkylene group; each of Rf 2 and Rf 3 independently represents a fluorine atom, a perfluoroalkyl group or a perfluoroalkoxy group; at least two among Rf 1 , Rf 2 and Rf 3 may bond to each other to form a ring structure; X represents an oxygen atom or a sulfur atom; and L represents a divalent organic group.
• US7919637B2
  申请人：——

  公开号：US7919637B2

  公开（公告）日：2011-04-05
• US8119765B2
  申请人：——

  公开号：US8119765B2

  公开（公告）日：2012-02-21