methyl 11-methyl octadecanoate | 74484-77-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: methyl 11-methyl octadecanoate
• 英文别名: 10-Methyloctadecansaeuremethylester；11-methyl-octadecanoic acid methyl ester；11-Methyl-octadecansaeure-methylester；Octadecanoic acid, 11-methyl-, methyl ester；methyl 11-methyloctadecanoate
• CAS: 74484-77-8
• 化学式: C₂₀H₄₀O₂
• 分子量: 312.536
• InChiKey: OHEUQJSREGQWEP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  22
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  methyl 11-methyl octadecanoate 在 氢氧化钾 、 氯化亚砜 作用下， 生成 11-methyl-octadecanoic acid amide
  参考文献：
  名称：

  BRANCHED-CHAIN FATTY ACIDS. XIII. PREPARATION OF BRANCHED AND NORMAL ACIDS FOR USE IN THE STUDY OF MELTING POINTS OF BINARY MIXTURES. COMPLETION OF THE METHYLOCTADECANOIC ACID SERIES

  摘要：

  DOI：

  10.1021/jo01147a023
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 氢氧化钾 、 一水合肼 、 二乙二醇 作用下， 生成 methyl 11-methyl octadecanoate
  参考文献：
  名称：

  BRANCHED-CHAIN FATTY ACIDS. XIII. PREPARATION OF BRANCHED AND NORMAL ACIDS FOR USE IN THE STUDY OF MELTING POINTS OF BINARY MIXTURES. COMPLETION OF THE METHYLOCTADECANOIC ACID SERIES

  摘要：

  DOI：

  10.1021/jo01147a023

文献信息

• Enzymes for producing non-straight-chain fatty acids
  申请人：WISCONSIN ALUMNI RESEARCH FOUNDATION

  公开号：US10273511B2

  公开（公告）日：2019-04-30

  Enzymes for producing non-straight-chain fatty acids, microorganisms comprising the enzymes, and in vivo and in vitro uses of the enzymes. Provided are enzymes capable of producing various non-straight-chain fatty acids, including branched-chain fatty acids, cyclic fatty acids, and furan-containing fatty acids. The enzymes include RSP2144, RSP1091, and RSP1090 from Rhodobacter sphaeroides and homologs thereof. The enzymes can be purified to produce non-straight-chain fatty acids in vitro or expressed in microorganisms to produce non-straight-chain fatty acids in vivo. The microorganisms can be fine-tuned to produce a specific type of non-straight-chain fatty acid by expressing, overexpressing, or deleting the enzymes in various combinations.

  用于生产非直链脂肪酸的酶，包含这些酶的微生物，以及这些酶在体内和体外的用途。所提供的酶能够生产各种非直链脂肪酸，包括支链脂肪酸、环脂肪酸和含呋喃脂肪酸。这些酶包括Rhodobacter SPhaeroides的RSP2144、RSP1091和RSP1090及其同源物。这些酶可以纯化，在体外产生非直链脂肪酸，或在微生物中表达，在体内产生非直链脂肪酸。可以通过表达、过表达或删除酶的各种组合，对微生物进行微调，以生产特定类型的非直链脂肪酸。
• ENZYMES FOR PRODUCING NON-STRAIGHT-CHAIN FATTY ACIDS
  申请人：WISCONSIN ALUMNI RESEARCH FOUNDATION

  公开号：US20150376659A1

  公开（公告）日：2015-12-31

  Enzymes for producing non-straight-chain fatty acids, microorganisms comprising the enzymes, and in vivo and in vitro uses of the enzymes. Provided are enzymes capable of producing various non-straight-chain fatty acids, including branched-chain fatty acids, cyclic fatty acids, and furan-containing fatty acids. The enzymes include RSP2144, RSP1091, and RSP1090 from Rhodobacter sphaeroides and homologs thereof. The enzymes can be purified to produce non-straight-chain fatty acids in vitro or expressed in microorganisms to produce non-straight-chain fatty acids in vivo. The microorganisms can be fine-tuned to produce a specific type of non-straight-chain fatty acid by expressing, overexpressing, or deleting the enzymes in various combinations.