8,9,10-Trinorborn-5-ene-2-spiro-1'-cyclohexan-2'-ol | 277318-64-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 8,9,10-Trinorborn-5-ene-2-spiro-1'-cyclohexan-2'-ol
• 英文别名: Spiro[bicyclo[2.2.1]hept-2-ene-5,2'-cyclohexane]-1'-ol
• CAS: 277318-64-6
• 化学式: C₁₂H₁₈O
• 分子量: 178.274
• InChiKey: YAAUJBKJPLNOMU-UHFFFAOYSA-N

物化性质

• 沸点：
  290.7±29.0 °C(Predicted)
• 密度：
  1.08±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  丙酰氯 、 8,9,10-Trinorborn-5-ene-2-spiro-1'-cyclohexan-2'-ol 在 吡啶 作用下， 以 苯 为溶剂， 反应 3.0h， 以94%的产率得到8,9,10-Trinorborn-5-ene-2-spiro-1'-cyclohexan-2'-yl propionate
  参考文献：
  名称：

  Skumov; Balbolov, Russian Journal of Organic Chemistry, 1999, vol. 35, # 9, p. 1301 - 1307

  摘要：

  DOI：
• 作为产物：
  描述：

  8,9,10-Trinorborn-5-ene-2-spiro-1'-cyclohexan-2'-one 在 sodium tetrahydroborate 作用下， 以 异丙醇 为溶剂， 以66%的产率得到8,9,10-Trinorborn-5-ene-2-spiro-1'-cyclohexan-2'-ol
  参考文献：
  名称：

  Skumov; Balbolov, Russian Journal of Organic Chemistry, 1999, vol. 35, # 9, p. 1301 - 1307

  摘要：

  DOI：

文献信息

• CYCLIC OLEFIN POLYMER, OPTICAL MATERIAL, POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY
  申请人：WATANABE Saisuke

  公开号：US20080299329A1

  公开（公告）日：2008-12-04

  A cyclic olefin polymer is provided and includes a repeating unit represented by formula (1A) and a repeating unit represented by the formula (1B): R 1 and R 3 each independently represents a substituent, L 1 and L 2 each independently represents a single bond or a divalent linking group, m and p each independently represents an integer of 0 or 1, and n and q each independently represents an integer of 1 to 4; and A represents COOR 2 or OCOR 2 , and R 2 represents a linear alkyl group having a carbon number of 1 to 10. The cyclic olefin polymer has a copolymerization ratio of x and y satisfying 0.03≦y/(x+y)≦0.50, a number average molecular weight of from 70,000 to 300,000, and a weight average molecular weight of from 200,000 to 700,000.

  提供了一种环状烯烃聚合物，包括由公式（1A）表示的重复单元和由公式（1B）表示的重复单元：R1和R3各自独立地表示取代基，L1和L2各自独立地表示单键或二价连接基，m和p各自独立地表示0或1的整数，n和q各自独立地表示1到4的整数；A表示COOR2或OCOR2，R2表示具有1到10个碳原子的线性烷基。该环状烯烃聚合物具有x和y的共聚比满足0.03≦y/(x+y)≦0.50，数量平均分子量为70,000至300,000，重量平均分子量为200,000至700,000。
• Cyclic Olefin-Based Polymer, and Optical Material, Polarizing Plate and Liquid Crystal Display Device Using the Same
  申请人：Suzuki Ryo

  公开号：US20090040436A1

  公开（公告）日：2009-02-12

  A cyclic olefin-based polymer containing a repeating unit represented by formula (1), an optical material containing the cyclic olefin-based polymer, a polarizing plate containing the optical material, and a liquid crystal display device containing the polarizing plate: in which R 1 represents a substituent; L represents a single bond or a divalent linking group, and forms an alcohol together with the —OH group; p represents an integer of 0 or 1; q represents an integer of from 0 to 3; r represents an integer of from 1 to 4; and R 1 and L may be combined with each other to form a 5- to 7-membered ring.
• US7838088B2
  申请人：——

  公开号：US7838088B2

  公开（公告）日：2010-11-23
• Skumov; Balbolov, Russian Journal of Organic Chemistry, 1999, vol. 35, # 9, p. 1301 - 1307
  作者：Skumov、Balbolov

  DOI：——

  日期：——