1,4,5,8-tetrakis(4-methylphenyl)-9,10-anthracenedione | 1060639-04-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 1,4,5,8-tetrakis(4-methylphenyl)-9,10-anthracenedione
• 英文别名: 1,4,5,8-Tetra(4-tolyl)anthraquinone；1,4,5,8-tetrakis(4-methylphenyl)anthracene-9,10-dione
• CAS: 1060639-04-4
• 化学式: C₄₂H₃₂O₂
• 分子量: 568.715
• InChiKey: RFOCMPUYSVWOKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.8
• 重原子数：
  44
• 可旋转键数：
  4
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,4,5,8-tetrakis(4-methylphenyl)-9,10-anthracenedione 在 氢碘酸 、 溶剂黄146 作用下， 反应 96.0h， 以83%的产率得到1,4,5,8-tetrakis(4-methylphenyl)anthracene
  参考文献：
  名称：

  Convenient Synthesis of Tetra- and Hexaarylanthracenes by Means of RuH₂(CO)(PPh₃)₃-Catalyzed C−H Arylation of Anthraquinone with Arylboronates

  摘要：

  A new method for the synthesis of multiarylanthracenes was developed by means of the RuH2(CO)(PPh3)(3)-Catalyzed arylation of anthraquinone with arylboronates. This method consists of short and straightforward sequences starting with an easily accessible anthraquinone and is applicable to the syntheses of various multiarylanthracenes including those bearing twisted backbones.

  DOI：

  10.1021/ol900393x
• 作为产物：
  描述：

  蒽醌 、 4-甲基苯硼酸新戊基二醇酯 在 频哪酮 、 RuH₂(CO)(PPh₃)₃ 作用下， 反应 24.0h， 以77%的产率得到1,4,5,8-tetrakis(4-methylphenyl)-9,10-anthracenedione
  参考文献：
  名称：

  Convenient Synthesis of Tetra- and Hexaarylanthracenes by Means of RuH₂(CO)(PPh₃)₃-Catalyzed C−H Arylation of Anthraquinone with Arylboronates

  摘要：

  A new method for the synthesis of multiarylanthracenes was developed by means of the RuH2(CO)(PPh3)(3)-Catalyzed arylation of anthraquinone with arylboronates. This method consists of short and straightforward sequences starting with an easily accessible anthraquinone and is applicable to the syntheses of various multiarylanthracenes including those bearing twisted backbones.

  DOI：

  10.1021/ol900393x

文献信息

• Convenient Synthesis of Tetra- and Hexaarylanthracenes by Means of RuH₂(CO)(PPh₃)₃-Catalyzed C−H Arylation of Anthraquinone with Arylboronates
  作者：Kentaroh Kitazawa、Takuya Kochi、Mitsuo Sato、Fumitoshi Kakiuchi

  DOI：10.1021/ol900393x

  日期：2009.5.7

  A new method for the synthesis of multiarylanthracenes was developed by means of the RuH2(CO)(PPh3)(3)-Catalyzed arylation of anthraquinone with arylboronates. This method consists of short and straightforward sequences starting with an easily accessible anthraquinone and is applicable to the syntheses of various multiarylanthracenes including those bearing twisted backbones.