(E)-2,2,6,8,8-pentamethyl-non-5-en-4-one | 53378-92-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (E)-2,2,6,8,8-pentamethyl-non-5-en-4-one
• 英文别名: (E)-2,2,6,8,8-pentamethylnon-5-en-4-one
• CAS: 53378-92-0
• 化学式: C₁₄H₂₆O
• 分子量: 210.36
• InChiKey: DEYDTOGLSWENFV-DHZHZOJOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4,4-二甲基-2-戊酮 在 异丙基氯化镁 作用下， 生成 (E)-2,2,6,8,8-pentamethyl-non-5-en-4-one
  参考文献：
  名称：

  异丙基氯无氯乙烯重复取向

  摘要：

  DOI：

  10.1016/s0040-4039(00)75160-4

文献信息

• [EN] CONJUGATED DIENE PHOSPHINATE COMPOUNDS, PREPARATION METHOD AND USE THEREOF<br/>[FR] COMPOSÉS PHOSPHINATE DE DIÈNE CONJUGUÉ, LEUR PROCÉDÉ DE PRÉPARATION ET LEUR UTILISATION
  申请人：RHODIA CHINA CO LTD

  公开号：WO2011050537A1

  公开（公告）日：2011-05-05

  This invention relates to conjugated diene phosphinate compounds for making halogen free phosphinate-containing flame retardants, inimer and metal extractants, method for preparing said compounds from unsaturated ketones or aldehydes, and the 5 use thereof. The compounds of the present invention having the following formula (III), wherein R 1, R 2, R 3, R 4, R 5 and R 6 represent, independently, hydrogen, alkyl, aryl, alkaryl, aralkyl, cycloalkyl, heterocycloalkyl, or alkenyl groups; R 7 represents hydrogen, alkyl, aryl, alkaryl, aralkyl, cycloalkyl, alkenyl groups, or metals selected from the group consisting of Na, Li, Ca.

  这项发明涉及制备含有膦酸酯基团的无卤膦酸酯阻燃剂、缩聚二烯膦酸酯基团化合物、金属萃取剂的方法以及从不饱和酮或醛制备上述化合物的方法。本发明的化合物具有以下公式（III）所示结构，其中R1、R2、R3、R4、R5和R6分别表示氢、烷基、芳基、烷芳基、芳烷基、环烷基、杂环烷基或烯基；R7表示氢、烷基、芳基、烷芳基、芳烷基、环烷基、烯基或从Na、Li、Ca等金属中选择的金属。
• [EN] METHOD FOR PREPARING CONJUGATED DIENE PHOSPHONATE COMPOUNDS<br/>[FR] PROCÉDÉ DE PRÉPARATION DE COMPOSÉS PHOSPHONATE DE DIÈNE CONJUGUÉ
  申请人：RHODIA CHINA CO LTD

  公开号：WO2011050533A1

  公开（公告）日：2011-05-05

  It is provided a method for preparing conjugated diene phosphonate compounds with high reactivity, which can be used to prepare a variety of phosphonate-bearing conjugated dienes. Some of those dienes will become reactive monomers to make polymers and co-polymers. The said method comprises the step of reacting α, β- or β, γ- unsaturated ketones or aldehydes with phosphorous acid or its derivates optionally in a mixture of acetic anhydride and/or acetic acid, to obtain a conjugated diene phosphonate compound having the formula (III)

  提供了一种制备具有高反应性的共轭二烯磷酸酯化合物的方法，可用于制备各种含磷酸酯的共轭二烯。其中一些二烯将成为反应单体，用于制备聚合物和共聚物。所述方法包括将α、β-或β、γ-不饱和酮或醛与磷酸或其衍生物在乙酸酐和/或乙酸的混合物中反应，以获得具有化合物（III）式的共轭二烯磷酸酯。
• METHOD OF COATING AN INORGANIC SUBSTRATE WITH A STABLE ORGANIC LAYER
  申请人：Bellenger Fabien

  公开号：US20130122213A1

  公开（公告）日：2013-05-16

  A method for coating a metallic or inorganic substrate is described, such as metal or glass supports, with an organic layer comprising conjugated diene phosphinate or phosphonate compounds.

  本文描述了一种用于在金属或无机基底上涂层的方法，例如金属或玻璃支撑物，采用含有共轭二烯基膦酸盐或膦酸酯化合物的有机层。
• UTILISATION D'UNE SILICE PRECIPITEE CONTENANT DU TITANE ET D'UN AGENT DE COUPLAGE SPECIFIQUE DANS UNE COMPOSITION D'ELASTOMERE(S)
  申请人：Rhodia Operations

  公开号：EP2912111B1

  公开（公告）日：2019-03-13
• CONJUGATED DIENE PHOSPHINATE COMPOUNDS, PREPARATION METHOD AND USE THEREOF
  申请人：Liu Zhaoqing

  公开号：US20120208975A1

  公开（公告）日：2012-08-16

  This invention relates to conjugated diene phosphinate compounds for making halogen free phosphinate-containing flame retardants, inimer and metal extractants, method for preparing said compounds from unsaturated ketones or aldehydes, and the 5 use thereof. The compounds of the present invention having the following formula (III), wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 represent, independently, hydrogen, alkyl, aryl, alkaryl, aralkyl, cycloalkyl, heterocycloalkyl, or alkenyl groups; R 7 represents hydrogen, alkyl, aryl, alkaryl, aralkyl, cycloalkyl, alkenyl groups, or metals selected from the group consisting of Na, Li, Ca.