2,3,6,7,10,11-Hexacyanotriphenylene | 142857-74-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2,3,6,7,10,11-Hexacyanotriphenylene
• 英文别名: 2,3,6,7,10,11-Triphenylenehexacarbonitrile；triphenylene-2,3,6,7,10,11-hexacarbonitrile
• CAS: 142857-74-7
• 化学式: C₂₄H₆N₆
• 分子量: 378.352
• InChiKey: LIMIPAXRMGOYNG-UHFFFAOYSA-N

物化性质

• 沸点：
  850.1±65.0 °C(Predicted)
• 密度：
  1.52±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  30
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  143
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2,3,6,7,10,11-六溴苯并[9,10]菲 、 氰化钾 在 四(三苯基膦)钯 二苯并-18-冠醚-6 作用下， 以 various solvent(s) 为溶剂， 反应 20.0h， 以41%的产率得到2,3,6,7,10,11-Hexacyanotriphenylene
  参考文献：
  名称：

  Synthesis of Hexacyanotriphenylene and Hexacyanotribenzylene

  摘要：

  描述了三角几何形状的六氰基三苯烯（1）和六氰基三苯烯（2）的合成。这些新的六氰基化合物被视为寡聚、聚合或球形酞菁系统的前体。

  DOI：

  10.1055/s-2000-8207

文献信息

• Electrically Conductive π‐Intercalated Graphitic Metal‐Organic Framework Containing Alternate π‐Donor/Acceptor Stacks
  作者：Ashok Yadav、Shiyu Zhang、Paola A. Benavides、Wei Zhou、Sourav Saha

  DOI：10.1002/anie.202303819

  日期：2023.6.26

  Two‐dimensional graphitic metal–organic frameworks (GMOF) often display impressive electrical conductivity chiefly due to efficient through‐bond in‐plane charge transport, however, less efficient out‐of‐plane conduction across the stacked layers creates large disparity between two orthogonal conduction pathways and dampens their bulk conductivity. To address this issue and engineer higher bulk conductivity in 2D GMOFs, we have constructed via an elegant bottom‐up method the first π‐intercalated GMOF (iGMOF1) featuring built‐in alternate π‐donor/acceptor (π‐D/A) stacks of Cu^II‐coordinated electron‐rich hexaaminotriphenylene (HATP) ligands and non‐coordinatively intercalated π‐acidic hexacyano‐triphenylene (HCTP) molecules, which facilitated out‐of‐plane charge transport while the hexagonal Cu₃(HATP)₂ scaffold maintained in‐plane conduction. As a result, iGMOF1 attained an order of magnitude higher bulk electrical conductivity and much smaller activation energy than Cu₃(HATP)₂ (σ=25 vs. 2 S m⁻¹, E_a=36 vs. 65 meV), demostrating that simultaneous in‐plane (through‐bond) and out‐of‐plane (through πD/A stacks) charge transport can generate higher electrical conductivity in novel iGMOFs.

  摘要二维石墨金属有机框架（GMOF）通常显示出令人印象深刻的导电性，这主要归功于高效的通键面内电荷传输，然而，在堆叠层之间效率较低的面外传导会在两个正交传导路径之间造成巨大差距，从而削弱其体传导性。为了解决这个问题并在二维 GMOF 中设计出更高的体电导率，我们通过一种优雅的自下而上的方法构建了第一个π插层 GMOF（iGMOF1），其特点是内置了由 CuII 配位的富电子六氨基三亚苯（HATP）配体和非配位插层的π酸性六氰基三亚苯（HCTP）分子组成的交替π供体/受体（π-D/A）堆叠、这促进了面外电荷传输，而六角形的 Cu3(HATP)2 支架则保持了面内传导。因此，iGMOF1 的体积电导率比 Cu3(HATP)2 高出一个数量级，而活化能却小得多（σ=25 vs. 2 S m-1，Ea=36 vs. 65 meV），这表明在新型 iGMOF 中，同时进行面内（通过键）和面外（通过 πD/A 堆栈）电荷传输可产生更高的电导率。
• Verfahren zur Herstellung von Heterofullerenen und Fullerenen
  申请人：Keesmann, Till

  公开号：EP0528214A1

  公开（公告）日：1993-02-24

  Verfahren zur Herstellung von aus geschlossenem Hexagon- und Pentagonnetzwerk bestehenden Hohlmolekülen, dadurch gekennzeichnet, daß durch Pyrolyse aus Edukten Hohlmoleküle hergestellt werden, die a) Kohlenstoff, Bor und Stickstoff als Bestandteile des Hexagon- und Pentagonnetzwerkes enthalten und/oder b) Kohlenstoff, Bor und Stickstoff als Bestandteile des Hexagon- und Pentagonnetzwerkes enthalten und bei denen Molekülsymmetrie- und Molekülabmessungsparameter mit denen von mit Öffnungen im Hexagon- und Pentagonnetzwerk versehenen Hohlmolekülen übereinstimmen, wenn diese als Eduktbestandteile eingesetzt werden oder die c) ausschließlich Kohlenstoff als Bestandteil des Hexagon- und Pentagonnetswerkes enthalten und bei denen Molekülsymmetrie- und Molekülabmessungsparameter mit denen von mit Öffnungen im Hexagon- und Pentagonnetzwerk versehenen Hohlmolekülen übereinstimmen, wenn diese als Eduktbestandteile eingesetzt werden.

  一种生产由封闭的六边形和五边形网络组成的空心分子的工艺，其特征在于空心分子是由起始材料通过热解产生的，这些空心分子是 a) 含碳、硼和氮作为六边形和五边形网络的组分，和/或 b) 含碳、硼和氮作为六角形和五角形网络的组分，其分子对称性和分子尺寸参数 与六角形和五角形网络中开孔的中空分子的分子对称性和分子尺寸参数一致，当这些 分子被用作起始材料组分时，或者是 c) 在六角形和五角形网络中只含有碳，其分子对称性和分子尺寸参数与六角形和五角形 网络中带有开口的中空分子的分子对称性和分子尺寸参数一致（如果这些中空分子被 用作反应物组分）。
• Compound, material for organic electroluminescence device, organic electroluminescence device and electronic apparatus
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10703762B2

  公开（公告）日：2020-07-07

  A compound represented by the following formula (1):

  下式(1)所代表的化合物：
• Display device
  申请人：Kijima Yasunori

  公开号：US20070181887A1

  公开（公告）日：2007-08-09

  In a stacked display device with light-emitting units composed of organic layers and stacked together, the use of a stable material in at least a portion of a charge generation layer makes it possible to achieve improvements in environmental stability and also to attain an improvement in the efficiency of injection of charges from the charge generation layer into the light-emitting units. The display device can be readily fabricated. In a display device ( 11 ) provided with a plurality of light-emitting units ( 14 - 1 )( 14 - 2 ), each of which includes at least an organic light-emitting layer ( 14 c ), stacked together between a cathode ( 16 ) and an anode ( 13 ), and also with a charge generation layer ( 15 ) held between the respective light-emitting units ( 14 - 1 )( 14 - 2 ), at least a portion of the charge generation layer ( 15 ) is composed of an oxide or fluoride which contains at least one of alkali metals and alkaline earth metals.
• DISPLAY AND METHOD FOR MANUFACTURING DISPLAY
  申请人：Matsuda Eisuke

  公开号：US20080018239A1

  公开（公告）日：2008-01-24

  Disclosed herein a display including: a plurality of organic electroluminescent elements configured to be arranged over a substrate and be each obtained by depositing a lower electrode, an organic layer including at least a light-emitting layer, and an upper electrode in that order, the organic layer of each of the organic electroluminescent elements being adjusted to have a film thickness that allows resonance of a wavelength of luminescent light generated in the light-emitting layer, wherein the film thickness of the organic layer in a first organic electroluminescent element that generates luminescent light having a shortest wavelength among the plurality of organic electroluminescent elements is set larger than the film thickness of the organic layer in a second organic electroluminescent element that generates luminescent light having a wavelength longer than the shortest wavelength of luminescent light generated in the first organic electroluminescent element.