all-trans-9,12,15-octadecatrienoic acid methyl ester | 14202-25-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: all-trans-9,12,15-octadecatrienoic acid methyl ester
• 英文别名: (9E,12E,15E)-methyl octadeca-9,12,15-trienoate；9,12,15-octadecatrienoic acid methyl ester；methyl 9,12,15-octadecatrienoate；methyl elaidolinolenate；methyl linolenate；methyl ester 9,12,15-octadecatrienoic acid；methyl (9E,12E,15E)-octadeca-9,12,15-trienoate
• CAS: 14202-25-6
• 化学式: C₁₉H₃₂O₂
• 分子量: 292.462
• InChiKey: DVWSXZIHSUZZKJ-JSIPCRQOSA-N

物化性质

• 熔点：
  -3.5 °C
• 沸点：
  364.4±0.0 °C(Predicted)
• 密度：
  0.895±0.06 g/cm3(Predicted)
• 保留指数：
  2079;2077.5

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  21
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.63
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2916190090

反应信息

• 作为反应物：
  描述：

  all-trans-9,12,15-octadecatrienoic acid methyl ester 生成 甲基(3Z)-3-己烯酸酯
  参考文献：
  名称：

  MITTELBACH, MARTIN;POKLUKAR, NORBERT, CHEM. AND PHYS. LIPIDS , 55,(1990) N, C. 67-72

  摘要：

  DOI：
• 作为产物：
  描述：

  (9E,12E,15E)-octadeca-9,12,15-trienoate;tetramethylazanium 生成 all-trans-9,12,15-octadecatrienoic acid methyl ester
  参考文献：
  名称：

  VASILCHENKO, S. A.;DRYUK, L. F.;LEBEDEVA, O. N., VOPR. XIMII I XIM. TEXNOL.,(1988) N8, S. 37-40

  摘要：

  DOI：

文献信息

• Novel Class Of Olefin Metathesis Catalysts, Methods Of Preparation, And Processes For The Use Thereof
  申请人：Holtcamp Matthew W.

  公开号：US20120077945A1

  公开（公告）日：2012-03-29

  This invention relates to a metathesis catalyst comprising (i) a Group 8 metal hydride-dihydrogen complex represented by the formula: wherein M is a Group 8 metal; X is an anionic ligand; and L 1 and L 2 are neutral donor ligands; and (ii) a ligand exchange agent represented by the formula J-Y, wherein J is selected from the group consisting of hydrogen, a C 1 to C 30 hydrocarbyl, and a C 1 to C 30 substituted hydrocarbyl; and Y is selected from the group consisting of halides, alkoxides, aryloxides, and alkyl sulfonates.

  本发明涉及一种化学反应催化剂，包括(i) 由以下公式表示的第8族金属氢化物-二氢复合物：其中，M是第8族金属，X是阴离子配体，L1和L2是中性给体配体；以及(ii) 一种配体交换剂，由以下公式表示：J-Y，其中J选择自氢、C1至C30烃基和C1至C30取代烃基组成的群体，而Y选择自卤化物、烷氧基、芳氧基和烷基磺酸盐组成的群体。
• Novel Class of Olefin Metathesis Catalysts, Methods of Preparation, and Processes For the Use Thereof
  申请人：HOLTCAMP Matthew W.

  公开号：US20120309998A1

  公开（公告）日：2012-12-06

  This invention relates to a metathesis catalyst comprising a Group 8 metal complex represented by the formula: wherein: M is a Group 8 metal; each X is independently an anionic ligand; R 1 and R 2 are independently selected from the group consisting of hydrogen, a C 1 to C 30 hydrocarbyl, and a C 1 to C 30 substituted hydrocarbyl; R 3 and R 4 are independently selected from the group consisting of hydrogen, C 1 to C 12 hydrocarbyl groups, substituted C 1 to C 12 hydrocarbyl groups, and halides; and L is a neutral donor ligand. This invention also relates to processes for performing a metathesis reaction, in particular ring opening cross metathesis reactions and ring opening metathesis polymerization reactions, using the Group 8 metal complexes.

  本发明涉及一种包括8族金属配合物的交换催化剂，其化学式为：其中，M是8族金属；每个X独立地为一个阴离子配体；R1和R2独立地选自氢、C1到C30烃基和C1到C30取代烃基的群体；R3和R4独立地选自氢、C1到C12烃基、取代C1到C12烃基和卤素的群体；L是一个中性给体配体。本发明还涉及使用8族金属配合物进行交换反应的过程，特别是环开口交换反应和环开口交换聚合反应。
• Simple and Versatile Nitrooxylation: Noncyclic Hypervalent Iodine Nitrooxylating Reagent
  作者：Xuan Cheng、Quan Yin、Yu‐Xuan Jiang、Ling‐Feng Jiang、Si‐Yuan Li、Yi‐Fei Cheng、Xin‐Chang Sun、Lujun Peng、Cheng Zhong、Qing‐Hai Deng

  DOI：10.1002/anie.202302521

  日期：——

  noncyclic hypervalent iodine nitrooxylating reagent is prepared from aryliodine diacetate and HNO3. This reagent facilitates the zinc-catalyzed regioselective nitrooxylation of cyclopropyl silyl ethers with broad scope, and also can be used in the nitrooxylation of various enolizable C−H bonds.

  一种稳定且高反应性的非环状高价碘硝基氧基化试剂由芳基碘二乙酸酯和 HNO 3制备。该试剂促进了锌催化的环丙基甲硅烷基醚的区域选择性硝基酰化反应，适用范围广，也可用于各种可烯醇化的C-H键的硝基酰化反应。
• Viscoelastic surfactant composition having improved rheological properties and method of using for treating subterranean formations
  申请人：Treybig S. Duane

  公开号：US20060025321A1

  公开（公告）日：2006-02-02

  A viscoelastic surfactant composition having improved rheological performance comprising one or more quaternized amidoamine surfactants, one or more tertiary amine amides, one or more polymeric acids and one or more electrolytes, viscosified aqueous fluids comprising the surfactant composition and methods of making and using the viscosified aqueous fluid for treating subterranean formations.

  一种具有更佳流变性能的粘弹性表面活性剂组合物，包含一种或多种季铵化氨基胺表面活性剂、一种或多种叔胺酰胺、一种或多种聚合酸和一种或多种电解质；包含该表面活性剂组合物的粘化水性流体；以及制造和使用该粘化水性流体处理地下地层的方法。
• Kass; Nichols; Burr, Journal of the American Chemical Society, 1941, vol. 63, p. 1061
  作者：Kass、Nichols、Burr

  DOI：——

  日期：——

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