1-Phenyl-dithiourazol | 2209-60-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-Phenyl-dithiourazol
• 英文别名: 3,5-Dithio-4-phenyl-1.2.4-triazolidin；4-phenyl-[1,2,4]triazolidine-3,5-dithione；4-Phenyl-[1,2,4]triazolidin-3,5-dithion；4-phenyl-1,2,4-triazolidine-3,5-dithione
• CAS: 2209-60-1
• 化学式: C₈H₇N₃S₂
• 分子量: 209.296
• InChiKey: HHMMSIFWVIWYNN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  91.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-Phenyl-dithiourazol 在 苯胺 作用下， 生成 3-benzylsulfanyl-benzo[4,5]thiazolo[2,3-c][1,2,4]triazole
  参考文献：
  名称：

  Konher,M.V., Indian Journal of Chemistry, 1973, vol. 11, p. 321 - 324

  摘要：

  DOI：
• 作为产物：
  描述：

  4,4'-diphenyl-1,1'-thiocarbonyl-bis-thiosemicarbazide 在 sodium hydroxide 作用下， 生成 1-Phenyl-dithiourazol
  参考文献：
  名称：

  Dornow,A.; Paucksch,H., Chemische Berichte, 1966, vol. 99, p. 81 - 84

  摘要：

  DOI：

文献信息

• Photosensitive composition, and lithographic printing plate precursor and image-recording method using the same
  申请人：FUJIFILM Corporation

  公开号：EP1764650A1

  公开（公告）日：2007-03-21

  A photosensitive composition comprising: a compound having two or more mercapto groups directly connected to a hetero ring; a hexaarylbiimidazole compound; a sensitizing dye; and a polymerizable compound having an ethylenically unsaturated double bond.

  一种光敏组合物，包括：具有两个或两个以上与杂环直接相连的巯基的化合物；六芳基咪唑化合物；感光染料；以及具有乙烯不饱和双键的可聚合化合物。
• A lithographic printing plate precursor and monomer
  申请人：AGFA GRAPHICS NV

  公开号：EP2883699A1

  公开（公告）日：2015-06-17

  A lithographic printing plate precursor is disclosed including (i) a support having a hydrophilic surface or which is provided with a hydrophilic layer, and (ii) a coating including a photopolymerisable layer, characterised in that the photopolymerisable layer comprises a compound comprising at least one moiety having a structure according to Formula (I): wherein X represents O or NR* and R* represents hydrogen, an optionally substituted alkyl, aryl, aralkyl or heteroaryl group; and * denotes the linking positions to the rest of the compound. The application further discloses a monomer including at least one moiety having a structure according to Formula (I) and at least one moiety having a structure according to Formula (VIII): wherein X represents O or NR* and wherein R* represents hydrogen, or an optionally substituted alkyl, aryl, aralkyl or heteroaryl group; R5 represents hydrogen or an optionally substituted alkyl group; and * denotes the linking positions to the rest of the monomer.

  本发明公开了一种平版印刷板前体，包括：(i) 具有亲水性表面或提供亲水层的支撑物；(ii) 包括可光聚合层的涂层、 其特征在于，可光聚合层包括一种化合物，该化合物至少包含一个具有式 (I) 结构的分子： 其中 X 代表 O 或 NR*，R* 代表氢、任选取代的烷基、芳基、芳烷基或杂芳基；以及 * 表示与化合物其余部分的连接位置。 该申请进一步公开了一种单体，包括至少一个具有式（I）结构的分子和至少一个具有式（VIII）结构的分子： 其中 X 代表 O 或 NR*，R* 代表氢或任选取代的烷基、芳基、芳烷基或杂芳基；R5 代表氢或任选取代的烷基；* 表示与单体其余部分的连接位置。
• A LITHOGRAPHIC PRINTING PLATE PRECURSOR AND METHOD FOR MAKING HYDROPHOBIC RESIN PARTICLES
  申请人：AGFA NV

  公开号：EP3815900A1

  公开（公告）日：2021-05-05

  A lithographic printing plate precursor including a support and a coating comprising a polymerisable compound, optionally a sensitizer, a photoinitiator and discrete particles is disclosed wherein the discrete particles comprise a crosslinked hydrophobic polymer backbone and a plurality of hydrophobic pendant grafts and a method for making a particulate resin particle including a hydrophobic backbone and hydrophobic grafts attached thereto.

  本发明公开了一种平版印刷板前驱体，包括支撑物和涂层，涂层包括可聚合化合物、感光剂、光引发剂和离散颗粒，其中离散颗粒包括交联疏水聚合物骨架和多个疏水悬垂接枝，还公开了一种制造颗粒状树脂颗粒的方法，颗粒状树脂颗粒包括疏水骨架和附着其上的疏水接枝。
• Lithographic printing plate precursor
  申请人：AGFA NV

  公开号：US10151975B2

  公开（公告）日：2018-12-11

  A lithographic printing plate precursor includes (i) a support having a hydrophilic surface or which is provided with a hydrophilic layer, and (ii) a coating including a photopolymerisable layer, characterised in that the photopolymerisable layer includes a compound including at least one free radically polymerisable group and at least one moiety having a structure according to Formula (I): wherein X represents O or NR* and R* represents hydrogen, an optionally substituted alkyl, aryl, aralkyl or heteroaryl group; and * denotes the linking positions to the rest of the compound.

  一种平版印刷板前体包括：(i) 具有亲水性表面或具有亲水层的支撑物；(ii) 包括可光聚合层的涂层，其特征在于可光聚合层包括至少一个可自由基聚合的基团和至少一个具有式 (I) 结构的分子的化合物： 其中 X 代表 O 或 NR*，R* 代表氢、任选取代的烷基、芳基、芳烷基或杂芳基； * 表示与化合物其余部分的连接位置。
• Chromatography membranes formed by thiol-ene or thiol-yne click polymerization reactions
  申请人：Natrix Separations Inc.

  公开号：US10357766B2

  公开（公告）日：2019-07-23

  Disclosed are composite materials and methods of making them. The composite materials comprise a support member and a cross-linked gel, wherein the cross-linked gel is a polymer synthesized by thiol-ene or thiol-yne polymerization and cross-linking. The cross-linked gel may be functionalized by a thiol-ene or thiol-yne grafting reaction, either simultaneously with the polymerization or as the second step in a two-step procedure. The composite materials are useful as chromatographic separation media.

  所公开的是复合材料及其制造方法。复合材料包括支撑件和交联凝胶，其中交联凝胶是通过巯基烯或巯基炔聚合和交联合成的聚合物。交联凝胶可以通过巯基烯或巯基炔接枝反应进行功能化，可以与聚合反应同时进行，也可以作为两步法中的第二步。这种复合材料可用作色谱分离介质。