4'-propyl-1,1'-bi(cyclohexyl)-4-carbaldehyde | 104358-16-9

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: 4'-propyl-1,1'-bi(cyclohexyl)-4-carbaldehyde
• 英文别名: trans-4-(trans-4-propylcyclohexyl)cyclohexanecarbaldehyde
• CAS: 104358-16-9
• 化学式: C₁₆H₂₈O
• 分子量: 236.398
• InChiKey: MDRULEIRSQHRHT-BIAGXBKMSA-N

物化性质

• 沸点：
  333℃ at 101.33kPa
• 密度：
  1.04 at 20.2℃
• LogP：
  4.7 at 23℃

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  17.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  4'-propyl-1,1'-bi(cyclohexyl)-4-carbaldehyde 在 iron(III) chloride 作用下， 以 乙酸乙酯 为溶剂， 反应 4.0h， 生成 1,1'-Bicyclohexyl, 4-ethenyl-4'-propyl-, (trans,trans)-
  参考文献：
  名称：

  2-OXETANONE DERIVATIVE AND PROCESS FOR PRODUCTION THEREOF

  摘要：

  公开号：

  EP2020407B1
• 作为产物：
  描述：

  [4-(4-propylcyclohexyl)cyclohexyl]methanol 在 亚硝酸特丁酯 、 4-amino-2,2,6,6-tetramethylpiperidine-N-oxyl 、 potassium chloride 、 溴 、 氧气 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 2.0h， 以90%的产率得到4'-propyl-1,1'-bi(cyclohexyl)-4-carbaldehyde
  参考文献：
  名称：

  一种反-4-(反-4’-烷基环己基)环己基甲醛的合成方法

  摘要：

  本发明公开了一种反‑4‑(反‑4'‑烷基环己基)环己基甲醛的合成方法，通过将反‑4‑(反‑4'‑烷基环己基)环己基甲醇进行催化氧化反应得到反‑4‑(反‑4'‑烷基环己基)环己基甲醛，其中氧化剂为氧气或空气，催化体系包括催化剂A、催化剂B、催化剂C；催化剂A为哌啶类氮氧自由基及其衍生物，催化剂B为一氧化氮等价物，催化剂C为溴化物、酸或三价铁盐。该合成方法的催化体系高效、环保，整个反应过程清洁、安全，从经济或环保角度考虑都极具优势。

  公开号：

  CN112961042A

文献信息

• Liquid crystalline compound having difluoropropyleneoxy group as bonding group, liquid crystal composition and liquid crystal display element
  申请人：——

  公开号：US20020119260A1

  公开（公告）日：2002-08-29

  The present invention provides a liquid crystalline compound having a difluoropropyleneoxy group as a bonding group, which is represented by Formula (1): 1 wherein R 1 and R 2 each independently represent hydrogen, halogen, a cyano group or an alkyl group having 1 to 20 carbon atoms; rings A 1 to A 5 each independently represent a 1,4-cyclohexylene group, a 1,4-cyclohexenylene group or a 1,4-phenylene group; Z 1 to Z 4 each independently represent a single bond, —CH 2 CH 2 —, —CH 2 13 , —OCH 2 —, —COO—, —OCO—, —CH=CH—, —C—C—, —CF 2 O— or —OCF 2 —; Y 1 , Y 2 , Y 3 and Y 4 each independently represent hydrogen or fluorine; and k, l, m and n each independently represent 0 or 1. This liquid crystalline compound has a large absolute value (|&Dgr;&egr;|) of a dielectric anisotropy and shows a relatively small refractive anisotropy. The present invention further provides a liquid crystal composition comprising this compound which makes it possible to drive display elements of various modes at a low voltage, and a liquid crystal display element containing this liquid crystal composition.

  本发明提供了一种液晶化合物，其具有二氟丙烯氧基作为键合基团，其由式（1）表示：其中R1和R2分别独立表示氢、卤素、氰基或具有1至20个碳原子的烷基基团；环A1至A5分别独立表示1,4-环己基基团、1,4-环己烯基团或1,4-苯基基团；Z1至Z4分别独立表示单键、—CH2CH2—、—CH213、—OCH2—、—COO—、—OCO—、—CH=CH—、—C—C—、—CF2O—或—OCF2—；Y1、Y2、Y3和Y4分别独立表示氢或氟；k、l、m和n分别独立表示0或1。该液晶化合物具有较大的介电各向异性的绝对值（|Δε|）并显示相对较小的折射各向异性。本发明还提供了一种包含该化合物的液晶组合物，可以以低电压驱动各种模式的显示元件，并且包含该液晶组合物的液晶显示元件。
• Chlorofluorobenzene liquid crystal compound, liquid crystal composition, and liquid crystal display device
  申请人：Goto Yasuyuki

  公开号：US20060198968A1

  公开（公告）日：2006-09-07

  Such a liquid crystal compound is provided that has stability to heat, light and so forth, has a nematic phase in a wide temperature range, has a small viscosity, a suitable optical anisotropy, and suitable elastic constants K 33 and K 11 (K 33 : bend elastic constant, K 11 : splay elastic constant), and has suitable negative dielectric anisotropy and excellent compatibility with other liquid crystal compounds. A liquid crystal composition containing the liquid crystal compound, and a liquid crystal display device containing the liquid crystal composition are also provided. The liquid crystal compound is represented by one of formulas (a) to (d), the liquid crystal composition contains the liquid crystal compound, and the liquid crystal display device contains the liquid crystal composition: wherein Ra and Rb are independently linear alkyl or linear alkoxy, rings A 1 , A 2 , B and C are independently trans-1,4-cyclohexylene or 1,4-phenylene, Z 11 , Z 12 , Z 2 and Z 3 are independently a single bond or alkylene, and one of X 1 and X 2 is fluorine, and the other thereof is chlorine.

  提供一种液晶化合物，具有对热、光等稳定性，在广泛温度范围内具有向列相，粘度小，适当的光学各向异性，适当的弹性常数K33和K11（K33：弯曲弹性常数，K11：扭曲弹性常数），并具有适当的负介电各向异性以及与其他液晶化合物的优良相容性。还提供一种含有该液晶化合物的液晶组合物和一种含有该液晶组合物的液晶显示装置。该液晶化合物由以下公式（a）至（d）中的一种表示，液晶组合物含有该液晶化合物，液晶显示装置含有该液晶组合物：其中Ra和Rb分别是线性烷基或线性烷氧基，环A1、A2、B和C分别是反式-1,4-环己亚烷或1,4-苯基，Z11、Z12、Z2和Z3分别是单键或烷基，X1和X2中的一个是氟，另一个是氯。
• 3E-cyclohexylalkoxy derivatives
  申请人：Hoffmann-La Roche Inc.

  公开号：US05032312A1

  公开（公告）日：1991-07-16

  Compounds of the formula ##STR1## wherein R.sup.1 denotes a group R.sup.3 or R.sup.3 --A.sup.4 --Z.sup.3 -- and R.sup.2 denotes a group R.sup.4 or --Z.sup.4 --A.sup.5 --R.sup.4 ; m and n each individually stand for the number 0 or 1; A.sup.1, A.sup.2, A.sup.3, A.sup.4 and A.sup.5 each independently represent unsubstituted or halogen-, cyano- and/or methyl-substituted 1,4-phenylene in which optionally 1 CH group or 2 CH groups is/are replaced by nitrogen, trans-1,4-cyclohexylene in which optionally 2 non-adjacent methylene groups are replaced by oxygen and/or sulphur, 1-cyano-trans-1,4-cyclohexylene, bicyclo[2.2.2]octane-1,4-diyl, naphthalene-2,6-diyl, tetralin-2,6-diyl or trans-decalin-2,6-diyl; Z.sup.1, Z.sup.2, Z.sup.3 and Z.sup.4 each independently signify a single covalent bond, --COO--, --OOC--, --CH.sub.2 O--, --OCH.sub.2 --, --CH.sub.2 CH.sub.2, --C.tbd.C--, --(CH.sub.2).sub.3 O--, --O(CH.sub.2).sub.3 -- or the trans form of --CH.dbd.CH--CH.sub.2 O-- or --OCH.sub.2 --CH.dbd.CH--; R.sup.3 and R.sup.4 each independently denote halogen, cyano, --NCS, --CF.sub.3, --OCF.sub.3 or alkyl in which optionally one <CH--CH> is replaced by <C.dbd.C> and/or optionally one methylene group or two non-adjacent methylene groups is/are replaced by --O--, --COO-- and/or --OOC-- and/or optionally one methylene group is replaced by --CHX--; and X signifies halogen, cyano or methyl, as well as liquid crystalline mixtures and their use for electro-optical purposes.

  化合物的公式为## STR1 ##，其中R.sup.1表示R.sup.3或R.sup.3--A.sup.4--Z.sup.3--基团，R.sup.2表示R.sup.4或--Z.sup.4--A.sup.5--R.sup.4基团; m和n分别代表数字0或1; A.sup.1，A.sup.2，A.sup.3，A.sup.4和A.sup.5各自独立地表示未取代或卤素，氰基和/或甲基取代的1,4-苯撑基，其中可选地1个CH基团或2个CH基团被氮取代，可选地2个非相邻亚甲基基团被氧和/或硫取代，1-氰基-反式-1,4-环己撑基，双环[2.2.2]辛烷-1,4-二基，萘-2,6-二基，四氢萘-2,6-二基或反-癸烷-2,6-二基; Z.sup.1，Z.sup.2，Z.sup.3和Z.sup.4各自独立地表示单个共价键，--COO--，--OOC--，--CH.sub.2O--，--OCH.sub.2--，--CH.sub.2CH.sub.2，--C.tbd.C--，--(CH.sub.2).sub.3O--，--O(CH.sub.2).sub.3--或--CH.dbd.CH--CH.sub.2O--或--OCH.sub.2--CH.dbd.CH--的反式形式; R.sup.3和R.sup.4各自独立地表示卤素，氰基，--NCS，--CF.sub.3，--OCF.sub.3或烷基，其中可选地一个<CH-CH>被<C.dbd.C>取代，和/或可选地一个亚甲基基团或两个非相邻亚甲基基团被--O--，--COO--和/或--OOC--取代，和/或可选地一个亚甲基基团被--CHX--取代; X表示卤素，氰基或甲基，以及液晶混合物及其用于电光目的的用途。
• CHLOROFLUOROBENZENE LIQUID CRYSTAL COMPOUND, LIQUID CRYSTAL COMPOSITION, AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：GOTO YASUYUKI

  公开号：US20090264683A1

  公开（公告）日：2009-10-22

  Such a liquid crystal compound is provided that has stability to heat, light and so forth, has a nematic phase in a wide temperature range, has a small viscosity, a suitable optical anisotropy, and suitable elastic constants K 33 and K 11 (K 33 : bend elastic constant, K 11 : splay elastic constant), and has suitable negative dielectric anisotropy and excellent compatibility with other liquid crystal compounds. A liquid crystal composition containing the liquid crystal compound, and a liquid crystal display device containing the liquid crystal composition are also provided. The liquid crystal compound is represented by one of formulas (a) to (d), the liquid crystal composition contains the liquid crystal compound, and the liquid crystal display device contains the liquid crystal composition: wherein Ra and Rb are independently linear alkyl or linear alkoxy, rings A 1 , A 2 , B and C are independently trans-1,4-cyclohexylene or 1,4-phenylene, Z 11 , Z 12 , Z 2 and Z 3 are independently a single bond or alkylene, and one of X 1 and X 2 is fluorine, and the other thereof is chlorine.

  提供一种液晶化合物，具有对热、光等的稳定性，在广泛的温度范围内具有向列相，具有较小的粘度，适当的光学各向异性和适当的弹性常数K33和K11(K33：弯曲弹性常数，K11：扭曲弹性常数)，并具有适当的负介电各向异性和与其他液晶化合物的良好相容性。还提供了一种含有该液晶化合物的液晶组合物和一种含有该液晶组合物的液晶显示装置。该液晶化合物由公式(a)到(d)中的一种表示，液晶组合物含有该液晶化合物，液晶显示装置含有该液晶组合物：其中Ra和Rb独立地是线性烷基或线性烷氧基，环A1、A2、B和C独立地是trans-1,4-环己基或1,4-苯基，Z11、Z12、Z2和Z3独立地是单键或烷基，X1和X2中的一个是氟，另一个是氯。
• A liquid crystal compound and a mixture containing the same
  申请人：Chisso Corporation

  公开号：EP0325796A1

  公开（公告）日：1989-08-02

  A liquid crystalline compound and a liquid crystal composition containing the compound usable for liquid crystal display devices are provided, which liquid crystalline compound is expressed by the formula wherein R1 is H or 1-20C alkyl or alkenyl wherein one -CH2- group or two -CH2- groups not adjacent to each other may be substituted by -0-; the position and number of the double bond may be optionally chosen; A1, A2 and A3 each are and the H of the may be substituted by F, Cℓ or methyl; B1 and B2 each are -CH2CH2-, -CH20-, -OCH2 or a single bond; n is 0 or 1; and m is 0-20.

  本发明提供了一种可用于液晶显示设备的液晶化合物和含有该化合物的液晶组合 物，该液晶化合物由式表示 其中 R1 为 H 或 1-20C 烷基或烯基，其中一个 -CH2- 基团或两个不相邻的 -CH2- 基团可被 -0- 取代；双键的位置和数目可任选；A1、A2 和 A3 分别为 的 H B1 和 B2 分别为-CH2CH2-、-CH20-、-OCH2 或单键；n 为 0 或 1；m 为 0-20。