Cyclohexylperoxyacetat | 55153-37-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Cyclohexylperoxyacetat
• 英文别名: Cyclohexyl peroxyacetate；cyclohexyl ethaneperoxoate
• CAS: 55153-37-2
• 化学式: C₈H₁₄O₃
• 分子量: 158.197
• InChiKey: KIRQMGOOUCTVMV-UHFFFAOYSA-N

物化性质

• 沸点：
  195.4±23.0 °C(Predicted)
• 密度：
  1.03±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  乙烯酮 、 环己基过氧化氢化物 在 硫酸 作用下， 以 正戊烷 为溶剂， 生成 Cyclohexylperoxyacetat
  参考文献：
  名称：

  Concerted mechanism and phase effects in decompositions of alkyl peroxy esters

  摘要：

  DOI：

  10.1021/ja00839a048

文献信息

• Method of preparing vinylchloride-based copolymer and vinylchloride plastisol composition including vinylchloride-based copolymer prepared using the method
  申请人：Kim Hyun Kyung

  公开号：US20070078217A1

  公开（公告）日：2007-04-05

  Provided is a method of preparing a vinylchloride-based copolymer for plastisol processing. Suspension copolymerization of a vinylchloride monomer with a comonomer having a low glass transition temperature in the presence of a buffer added at an initial stage of the copolymerization can produce a vinylchloride-based copolymer resin with a good low-temperature melting property, a uniform particle size, and a narrow particle size distribution. A plastisol including the vinylchloride-based copolymer resin as a blend resin has low viscosity, and thus, can be easily processed even at a low temperature.

  提供的是一种制备用于塑化剂处理的基于氯乙烯的共聚物的方法。将低玻璃化转变温度的共聚单体与氯乙烯单体在缓冲剂的存在下进行悬浮聚合反应，可以制备出具有良好低温熔融性、均匀粒径和窄粒径分布的基于氯乙烯的共聚物树脂。包括基于氯乙烯的共聚物树脂的混合树脂的塑化剂具有低粘度，因此即使在低温下也可以轻松加工。
• Perfluoroalkyl-iodo norbornane compounds and their use as surfactants
  申请人：CIBA-GEIGY AG

  公开号：EP0002741A2

  公开（公告）日：1979-07-11

  Compounds of the formula and the anhydrides or imides thereof, wherein Rf is a perfluoroalkyl group, Y is oxygen or > NR and R is hydrogen or alkyl. These compounds can be prepared by a free radical catalyzed addition of a perfluoroalkyl iodide to a 5-norbornene diacid or its derivative. They are useful as surfactants.

  式中的化合物 及其酸酐或亚胺，其中 Rf 为全氟烷基，Y 为氧或 > NR，R 为氢或烷基。 这些化合物可以通过将全氟烷基碘化物与 5-降冰片烯二酸或其衍生物进行自由基催化加成来制备。它们可用作表面活性剂。
• Polyolefin products with improved toughness, strength and heat resistance
  申请人：Borealis GmbH

  公开号：EP1167404A1

  公开（公告）日：2002-01-02

  Polyolefin products with high requirements for toughness, strength and heat resistance, produced from modified olefin polymers based on modified propylene polymers which have been modified by reaction with bifunctional monomers in the presence of free-radical generators in the solid phase. The polyolefin products are particularly suitable for shock-absorbing components of motor vehicles, such as bumpers, spoilers and side edge protection elements.

  对韧性、强度和耐热性有较高要求的聚烯烃产品，是以改性丙烯聚合物为基础，通过在固相自由基发生器存在的情况下与双官能团单体发生反应而改性的改性烯烃聚合物制成的。 这种聚烯烃产品尤其适用于机动车辆的减震部件，如保险杠、扰流板和侧缘保护元件。
• Semi-finished products or moulded materials of improved toughness made from propylene polymers
  申请人：Borealis GmbH

  公开号：EP1211284A1

  公开（公告）日：2002-06-05

  The invention relates to semi-finished products or moulded materials of improved toughness made from propylene polymers and from polymeric C8-C14-vinylaromatics and/or polymethyl methacrylate in the form of embedded nanoparticles. The semi-finished products or moulded materials can be produced by sorption of mixtures made from C8-C14-vinylaromatics and/or methyl methacrylate with thermally decomposing free-radical generators by semi-finished products, moulded materials or pellets made from propylene polymers, and then polymerization of the absorbed monomers present in the semi-finished products, moulded materials or pellets made from propylene polymers, where appropriate with processing of the modified pellets to give semi-finished products or moulded materials. The semi-finished products or moulded materials are suitable for use as highly stressed components in the sectors of vehicle construction, household devices, mechanical engineering, electrical devices or electronics.

  本发明涉及由丙烯聚合物和嵌入纳米颗粒形式的聚合 C8-C14-乙烯基芳烃和/或聚 甲基丙烯酸甲酯制成的韧性更好的半成品或模塑材料。半成品或模塑材料可通过丙烯聚合物制成的半成品、模塑材料或颗粒吸附由 C8-C14-vinylaromatics 和/或甲基丙烯酸甲酯与热分解自由基发生器制成的混合物，然后聚合存在于丙烯聚合物制成的半成品、模塑材料或颗粒中的被吸收单体，在适当的情况下，对改性颗粒进行加工，得到半成品或模塑材料。 这些半成品或模塑材料适用于车辆制造、家用设备、机械工程、电气设备或电子产品等领域的高强度部件。
• Polypropylene composition with improved stiffness and toughness
  申请人：Borealis GmbH

  公开号：EP1382638A1

  公开（公告）日：2004-01-21

  The invention refers to a polypropylene composition with improved stiffness and improved toughness, comprising a component A which is comprised of a propylene homopolymer or a propylene copolymer with up to 50 mol% of at least one of ethylene and C4-C8 α-olefins or mixtures of such propylene homo- and copolymers, a component B which is comprised of a propylene polymer having strain hardening behaviour, and a component C which comprises a β-nucleating agent.

  本发明涉及一种具有更高硬度和韧性的聚丙烯组合物，它包括由丙烯均聚物或丙烯共聚物（乙烯和 C4-C8 α-烯烃中至少一种的含量不超过 50 摩尔）或丙烯均聚物和丙烯共聚物混合物组成的 A 组分、由具有应变硬化特性的丙烯聚合物组成的 B 组分和由β-成核剂组成的 C 组分。