3,6-dihydroxy-o-benzenequinone | 315685-54-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3,6-dihydroxy-o-benzenequinone
• 英文别名: 3,6-dihydroxy-o-benzoquinone；hydroquinone-quinone
• CAS: 315685-54-2
• 化学式: C₆H₄O₄
• 分子量: 140.095
• InChiKey: PZXRCGGBZOBKKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.02
• 重原子数：
  10.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.6
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  3,6-二氟-1,2-苯二酚 在 tyrosinase Agaricus bisporus 、 氧气 作用下， 生成 3,6-Difluorocyclohexa-3,5-diene-1,2-dione 、 3,6-dihydroxy-o-benzenequinone 、 、 4-(3,6-Difluoro-2-hydroxyphenoxy)-3,6-difluorobenzene-1,2-diol
  参考文献：
  名称：

  儿茶酚结构对酪氨酸酶自杀灭活的影响

  摘要：

  3,6-二氟邻苯二酚不能用作单加氧酶酪氨酸酶的底物，是氧化酶的底物，与其他邻苯二酚相反，氧化不会导致自杀灭活，为涉及从活性位点还原性消除Cu 0的灭活机制提供了实验证据。

  DOI：

  10.1039/b910500j

文献信息

• [EN] METHINE DYES WITH LARGE ORGANIC COUNTER ANION FOR DYE SENSITIZED SOLAR CELLS<br/>[FR] COLORANTS À BASE DE MÉTHINE COMPRENANT UN CONTRE-ANION ORGANIQUE DE GRANDE TAILLE POUR CELLULES SOLAIRES À PIGMENT PHOTOSENSIBLE
  申请人：BASF SE

  公开号：WO2015011638A1

  公开（公告）日：2015-01-29

  The present invention relates to an electrode layer comprising a porous film made of oxide semiconductor fine particles sensitized with a methine dye having a counter anion capable of absorbing electromagnetic radiation having a wavelength in the range of from 400 nm to 1000 nm. Moreover the present invention relates to a photoelectric conversion device comprising said electrode layer, a dye sensitized solar cell comprising said photoelectric conversion device, an organic electronic device comprising said photoelectric conversion device and to novel methine dyes having a counter anion capable of absorbing electromagnetic radiation having a wavelength in the range of from 400 nm to 1000 nm.

  本发明涉及一种电极层，该电极层包括由氧化物半导体细颗粒制成的多孔薄膜，该薄膜被一种具有能够吸收波长在400纳米至1000纳米范围内电磁辐射的反离子敏化的偏亚甲基染料。此外，本发明涉及一种包括所述电极层的光电转换装置，一种包括所述光电转换装置的染料敏化太阳能电池，一种包括所述光电转换装置的有机电子器件，以及一种具有能够吸收波长在400纳米至1000纳米范围内电磁辐射的新型偏亚甲基染料。
• ORGANIC DYE FOR A DYE-SENSITIZED SOLAR CELL
  申请人：ENI S.P.A.

  公开号：US20160264782A1

  公开（公告）日：2016-09-15

  Organic dye for a dye-sensitized solar cell (DSSC) comprising at least one electron-acceptor unit and at least one π-conjugated unit. Said organic dye is particularly useful in a dye-sensitized photoelectric transformation element which, in its turn, can be used in a dye-sensitized solar cell (DSSC).

  一种用于染料敏化太阳能电池（DSSC）的有机染料，包括至少一个电子受体单元和至少一个π-共轭单元。所述有机染料特别适用于染料敏化光电转换元件，该元件又可用于染料敏化太阳能电池（DSSC）。
• ORGANIC METAL DYE, AND PHOTOELECTRIC ELEMENT AND DYE-SENSITIZED SOLAR CELL USING THE ORGANIC METAL DYE
  申请人：Je Jongtae

  公开号：US20120247546A1

  公开（公告）日：2012-10-04

  The present invention relates to an organic metal dye comprising fused heterocyclic derivatives, and to a photoelectric element and to a dye-sensitized solar cell using the organic metal dye.

  本发明涉及一种包括融合杂环衍生物的有机金属染料，以及使用该有机金属染料的光电元件和染料敏化太阳能电池。
• MALEIMIDE-BASED COMPOUND, AND TAUTOMER OR STEREOISOMER THEREOF, DYE FOR PHOTOELECTRIC CONVERSION, AND SEMICONDUCTOR ELECTRODE, PHOTOELECTRIC CONVERSION ELEMENT AND PHOTOELECTROCHEMICAL CELL USING THE SAME
  申请人：Maeda Katsumi

  公开号：US20130056690A1

  公开（公告）日：2013-03-07

  It is an object to provide a maleimide-based compound having excellent photoelectric conversion characteristics, and a tautomer or a stereoisomer thereof, a dye for photoelectric conversion, a semiconductor electrode, a photoelectric conversion element, and a photoelectrochemical cell. In order to accomplish the above-described objects, a dye for photoelectric conversion including at least one compound represented by the following general formula (1) is provided. (In the formula (1), R 1 represents a direct bond, or a substituted or unsubstituted alkylene group. X represents an acidic group. D represents an organic group containing an electron-donating substituent. Z represents a linking group that has at least one hydrocarbon group selected from aromatic rings or heterocyclic rings).

  提供一种具有优异光电转换特性的基于马来酰亚胺的化合物，以及其互变体或立体异构体，用于光电转换的染料，半导体电极，光电转换元件和光电化学电池。为了实现上述目标，提供了一种用于光电转换的染料，其中至少包括由以下通式（1）表示的化合物之一。（在通式（1）中，R1表示直接键，或取代或未取代的烷基。X表示酸性基团。D表示含有给电子取代基的有机基团。Z表示具有至少一个选自芳香环或杂环的碳氢基团的连接基团）。
• INDOLE COMPOUND, AND PHOTOELECTRIC CONVERSION DYE USING SAME, SEMICONDUCTOR ELECTRODE, PHOTOELECTRIC CONVERSION ELEMENT, AND PHOTOELECTROCHEMICAL CELL
  申请人：Maeda Katsumi

  公开号：US20130167932A1

  公开（公告）日：2013-07-04

  Provided is an indole compound represented by the following general formula (1): wherein in formula (1), R 1 and R 2 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group; R 3 to R 6 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, an alkoxy group or a hydroxy group; X represents an organic group having an acidic group; and Z represents a linking group including at least one selected from the group consisting of a substituted or unsubstituted aromatic ring, a substituted or unsubstituted heterocyclic ring, a vinylene group and an ethynylene group.

  提供的是由以下一般式（1）表示的吲哚化合物：在式（1）中，R1和R2分别独立地表示氢原子、取代或未取代的烷基基团、取代或未取代的芳基团或取代或未取代的杂环基团；R3到R6分别独立地表示氢原子、取代或未取代的烷基基团、取代或未取代的芳基团、烷氧基或羟基；X表示具有酸性基团的有机基团；Z表示包括取代或未取代的芳香环、取代或未取代的杂环环、乙烯基团和乙炔基团中至少一种的连接基团。