1,1,1-tris(hydroxymethyl)ethane tris(glicidyl ether) | 36366-26-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: 1,1,1-tris(hydroxymethyl)ethane tris(glicidyl ether)
• 英文别名: trimethylol ethane triglycidyl ether；trimethylolethane triglycidylether；2-({2-Methyl-3-(2-oxiranylmethoxy)-2-[(2-oxiranylmethoxy)methyl]propoxy}methyl)oxirane；2-[[2-methyl-3-(oxiran-2-ylmethoxy)-2-(oxiran-2-ylmethoxymethyl)propoxy]methyl]oxirane
• CAS: 36366-26-4
• 化学式: C₁₄H₂₄O₆
• 分子量: 288.341
• InChiKey: YIEBXCCPOCRXRB-UHFFFAOYSA-N

物化性质

• 沸点：
  135 °C(Press: 0.05 Torr)
• 密度：
  1.198±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  20
• 可旋转键数：
  12
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  65.3
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,1,1-tris(hydroxymethyl)ethane tris(glicidyl ether) 在 氢氧化钾 、 硼酸 、 盐酸 作用下， 以 甲醇 、 水 为溶剂， 反应 51.0h， 生成 5-(acetyl-{3-[2,2-bis-(3-{acetyl-[3,5-bis-(2.3-dihydroxy-propylcarbamoyl)-2,4,6-triiodo-phenyl]-amino}-2-hydroxy-propoxymethyl)-propoxy]-2-hydroxy-propyl}-amino)-N,N'-bis-(2,3-dihydroxy-propyl)-2,4,6-triiodo-isophthalamide
  参考文献：
  名称：

  WO2007/94677

  摘要：

  公开号：
• 作为产物：
  描述：

  1,1,1-三(羟甲基)乙烷 、 环氧氯丙烷 在 氢氧化钾 作用下， 以 二甲基亚砜 为溶剂， 反应 6.0h， 以78%的产率得到1,1,1-tris(hydroxymethyl)ethane tris(glicidyl ether)
  参考文献：
  名称：

  Unique interfacial properties of a homologous series of novel triple-chain amphiphiles bearing three anionic head groups derived from 1,1,1-tris(hydroxymethyl)ethane

  摘要：

  在使用Wilhelmy张力计通过常见的表面张力方法获得这些数据时，观察到了一种异常行为：在水中的临界胶束浓度（CMC）值对于标题中的表面活性剂同系物系列，随着亲脂性烷基链碳原数的增加而增加。

  DOI：

  10.1039/c39940001435

文献信息

• MATERIAL FOR FORMING ORGANIC FILM, METHOD FOR FORMING ORGANIC FILM, PATTERNING PROCESS, AND COMPOUND
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20210286266A1

  公开（公告）日：2021-09-16

  The present invention is a material for forming an organic film, including: a compound shown by the following general formula (1); and an organic solvent, where in the general formula (1), X represents an organic group with a valency of “n” having 2 to 50 carbon atoms or an oxygen atom, “n” represents an integer of 1 to 10 , and R 1 independently represents any of the following general formulae (2), where in the general formulae (2), broken lines represent attachment points to X, and Q 1 represents a monovalent organic group containing a carbonyl group, at least a part of which is a group shown by the following general formulae (3), where in the general formulae (3), broken lines represent attachment points, X 1 represents a single bond or a divalent organic group having 1 to 20 carbon atoms optionally having a substituent when the organic group has an aromatic ring, R 2 represents a hydrogen atom, a methyl group, an ethyl group, or a phenyl group, and ** represents an attachment point. An object of the present invention is to provide a material for forming an organic film for forming an organic film having dry etching resistance, and also having high filling and planarizing properties and adhesion to a substrate.

  本发明是一种用于形成有机薄膜的材料，包括：由以下通用式（1）所示的化合物；和有机溶剂，在通用式（1）中，X代表具有2至50个碳原子或一个氧原子的价为“n”的有机基团，“n”表示1到10的整数，R1独立地表示以下通用式（2）中的任何一种，其中在通用式（2）中，虚线表示连接点到X，Q1表示含有羰基的一价有机基团，其中至少部分是以下通用式（3）所示的基团，其中在通用式（3）中，虚线表示连接点，X1表示单键或具有1到20个碳原子的二价有机基团，在有机基团具有芳香环时可选地具有取代基，R2表示氢原子、甲基基团、乙基基团或苯基团，**表示连接点。本发明的目的是提供一种用于形成具有干法刻蚀抗性的有机薄膜的材料，同时具有高填充和平整化性能以及对基底的粘附性。
• A Facile Synthesis of Polyglycidyl Ethers from Polyols and Epichlorohydrin
  作者：Toshiyuki Kida、Masatoshi Yokota、Araki Masuyama、Yohji Nakatsuji、Mitsuo Okahara

  DOI：10.1055/s-1993-25890

  日期：——

  The reaction of 1,1,1-tris(hydroxymethyl)ethane (1a), 2-ethyl-2-(hydroxymethyl)-1, 3-propanediol (1b), pentaerythritol (1c), or 1,2, 6-hexanetriol (1e) with epichlorohydrin in the presence of potassium hydroxide in dimethyl sulfoxide gave the corresponding tri- or tetraglycidyl ethers 3a-c, e in high yields. This procedure was also applicable to the preparation of the phenolic polyglycidyl ethers.

  1,1,1-三(羟甲基)乙烷(1a)、2-乙基-2-(羟甲基)-1,3-丙二醇(1b)、季戊四醇(1c)或1,2,6-己三醇(1e)与表氯醇在氢氧化钾和二甲基亚砜存在下的反应，高效地得到了相应的三或四缩水甘油醚3a-c、e。此方法同样适用于制备酚类多元缩水甘油醚。
• ALKALI-DEVELOPABLE PHOTOSENSITIVE RESIN COMPOSITION AND BETA-DIKETONE COMPOUND
  申请人：Yamada Takashi

  公开号：US20100129753A1

  公开（公告）日：2010-05-27

  An alkali developable photosensitive resin composition contains (J) a photopolymerizable unsaturated compound having a structure resulting from the addition reaction of (B) a compound having a β-diketone moiety or a compound having a β-ketoester group to the (meth)acryloyl group of (A) a compound having at least two (meth)acryloyl groups and a hydroxyl group and subsequent esterification of the hydroxyl group of the resulting addition product with (C) a polybasic acid anhydride. The compound having a β-diketone moiety is preferably a novel β-diketone compound represented by general formula (I): wherein R 1 is a C1-C20 alkyl group; R 2 represents R 11 , OR 11 , COR 11 , SR 11 , CONR 12 R 13 , or CN; R 11 , R 12 , and R 13 are each hydrogen, a C1-C20 alkyl group, etc.; a is 0 to 3; and b is 0 to 4.

  一种可由碱显影的光敏树脂组合物，含有（J）一种光聚合不饱和化合物，该化合物的结构是由（B）含β-二酮基团或含β-酮酯基团的化合物与（A）含至少两个(甲基)丙烯酰基团和一个羟基的化合物中的(甲基)丙烯酰基团发生加成反应，并随后将所得加成产物的羟基与（C）多元酸酐进行酯化反应得到的。含β-二酮基团的化合物最好是表示为通用公式（I）的一种新型β-二酮化合物：其中R1是C1-C20烷基团；R2代表R11、OR11、COR11、SR11、CONR12R13或CN；R11、R12和R13分别是氢、C1-C20烷基团等；a是0到3；b是0到4。
• METHOD FOR PREPARING A COMPOUND COMPRISING AT LEAST ONE BETA-HYDROXY-URETHANE UNIT AND/OR AT LEAST ONE UPSILON-HYDROXY-URETHANE UNIT
  申请人：Soules Aurélien

  公开号：US20140378648A1

  公开（公告）日：2014-12-25

  The invention relates to a method for preparing a compound comprising at least one β-hydroxy-urethane unit and/or at least one γ-hydroxy-urethane unit, consisting in reacting a compound (A) comprising at least one cyclocarbonate reactive unit with a compound (B) comprising at least one amino reactive unit (—NH2) in the presence of a catalyst. The invention also relates to the use of a catalyst comprising at least one organometallic complex and a co-catalyst chosen from the group of Lewis bases and/or tetra-alkyl ammonium salts, in order to catalyse the method of the invention. The invention relates to the technical field of preparing urethane derivatives.

  该发明涉及一种制备至少含有一个β-羟基脲基和/或至少含有一个γ-羟基脲基的化合物的方法，包括将至少含有一个环碳酸酯反应单元的化合物（A）与至少含有一个氨基反应单元（—NH2）的化合物（B）在催化剂存在下反应。该发明还涉及使用至少含有一个有机金属配合物和从Lewis碱和/或四烷基铵盐组中选择的共催化剂的催化剂，以催化该发明的方法。该发明涉及制备脲基衍生物的技术领域。
• [EN] LATENT ACIDS AND THEIR USE<br/>[FR] ACIDES LATENTS ET LEUR UTILISATION
  申请人：BASF SE

  公开号：WO2016124493A1

  公开（公告）日：2016-08-11

  Compounds of the formula (I) and (IA) wherein X is -O(CO)-; R1 is C1-C12haloalkyl or C6-C10haloaryl; R2 is located in position 7 of the coumarinyl ring and is OR8; R2a, R2b and R2C independently of each other are hydrogen; R3 is C1-C8haloalkyl or C1-C8haloalkyl; R4 is hydrogen; and R8 is C1-C6alkyI; are suitable as photosensitive acid donors in the preparation of photoresist compositions such as used for example in the preparation of spacers, insulating layers, interlayer dielectric films, insulation layers, planarization layers, protecting layers, overcoat layers, banks for electroluminescence displays and liquid crystal displays (LCD).

  化合物的化学式（I）和（IA），其中X为-O(CO)-；R1为C1-C12卤代烷基或C6-C10卤代芳基；R2位于香豆素环的第7位，为OR8；R2a、R2b和R2C彼此独立地为氢；R3为C1-C8卤代烷基或C1-C8卤代烷基；R4为氢；R8为C1-C6烷基，适用于作为感光酸给体，用于制备光刻胶组合物，例如用于制备间隔层、绝缘层、层间介质膜、绝缘层、平坦化层、保护层、覆盖层、电致发光显示器和液晶显示器（LCD）的制备。