acrylic acid-(β,γ-epoxy-isobutyl ester) | 19900-46-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: acrylic acid-(β,γ-epoxy-isobutyl ester)
• 英文别名: Acrylsaeure-(β,γ-epoxy-isobutylester)；β-methylglycidyl acrylate；2-Methylglycidyl acrylate；(2-methyloxiran-2-yl)methyl prop-2-enoate
• CAS: 19900-46-0
• 化学式: C₇H₁₀O₃
• 分子量: 142.155
• InChiKey: ARYIITVULFDIQB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  38.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  acrylic acid-(β,γ-epoxy-isobutyl ester) 、 天然橡胶 在 二氯二茂锆 盐酸 、 lithium hydroxide 、 silver perchlorate 作用下， 生成 4-甲基环己-3-烯-1-羧酸
  参考文献：
  名称：

  锆茂催化的阳离子Diels-Alder反应

  摘要：

  原位制备的Cp 2的ZrCl ⊕催化从α，β不饱和环氧酯dioxolenium离子的形成。作为该活化过程的结果，丙烯酸酯，甲基丙烯酸酯和巴豆酸酯衍生物经历了具有广泛二烯的快速且立体选择性的阳离子[4 + 2]环加成。中间体二醇酯皂化后，在0–21°C下于1–7 h内形成扩环的羧酸衍生物，产率为50–90％。通过简单的Cp路易斯酸催化2的ZrCl ⊕可以被排除的实验结果的基础上。

  DOI：

  10.1016/0040-4020(94)01140-u
• 作为产物：
  描述：

  丙烯酸乙酯 在 tetrabutoxytitanium 、 丙酮 作用下， 生成 acrylic acid-(β,γ-epoxy-isobutyl ester)
  参考文献：
  名称：

  Synthesis of Some Epoxy Vinyl Monomers by Epoxidation with Peracetic Acid¹

  摘要：

  DOI：

  10.1021/ja01522a048

文献信息

• ALPHA-SUBSTITUTED ACRYLATE ESTERS, COMPOSITION CONTAINING THEREOF, AND METHOD FOR PRODUCING THOSE
  申请人：Kawamoto Takahiro

  公开号：US20130072712A1

  公开（公告）日：2013-03-21

  A method for producing α-substituted acrylate esters is provided which can be suitably used as an industrial method for producing α-substituted acrylate esters because the method does not have problems of apparatus corrosion or does not require waste detoxification and allows reaction in a short time with high yield. The method for producing an α-substituted acrylate ester includes a step of carrying out a reaction of a compound having a specific structure and an active hydrogen-containing compound under a condition where a tertiary amine and an acid and/or a salt thereof coexist.

  提供了一种生产α-取代丙烯酸酯的方法，该方法可适当用作工业生产α-取代丙烯酸酯的方法，因为该方法不存在设备腐蚀问题或不需要废物解毒，并允许在短时间内高产率反应。生产α-取代丙烯酸酯的方法包括在三级胺和酸和/或其盐共存的条件下，进行具有特定结构和含有活性氢的化合物的反应的步骤。
• Phosphorus containing materials, their preparation and use
  申请人：——

  公开号：US20040026671A1

  公开（公告）日：2004-02-12

  There is described a co-polymerisable phosphorus containing polymer precursor which comprises: a) a polymerisable unsaturated bond; b) a oxycarbonyl or iminocarbony group; and c) a free hydroxy group or a functional group obtainable by reaction of a free hydroxy group with a suitable electrophile; and d) a terminal phosphorus and oxygen containing group located at the end of a carbon chain and comprising at least one group selected from: hydroxy phosphorus and an optionally substituted hydrocarbyl group attached to a phosphorus atom through an oxy group; where the polymer precursor: is substantially free of halo comprising species; has a molecular weight (Mn if a polymer) of from about 200 to about 5,000 daltons; and optionally, has a Hoppler viscosity measured at 25° C. of less than about 14,000 mPa.s. These polymer precursors are obtainable as the product of a reaction between an optionally substituted terminal phosphate or H-phosphonate ester and compound comprising at least one oxiranyl, preferably epoxy, ring adjacent an alkylidenylcarbonyloxy group. The polymer precursors can be copolymerised with other monomers to produce copolymers such as phosphorus containing polyurethanes which for example have use as flame retardants, anti-corrosives, pigment dispersants and/or adhesion promoters.

  描述了一种共聚磷含量聚合物前体，其包括：a）可聚合不饱和键；b）氧羰基或亚氨基羰基团；c）自由羟基或可通过与适当电子亲合剂反应获得的功能基团；以及d）位于碳链末端的含磷氧基团，包括至少一种从羟基磷和可选取代的烃基团通过氧基连接到磷原子的团；其中，聚合物前体：基本上不含卤素物种；分子量（如果是聚合物，则为Mn）为约200至约5,000道尔顿；可选地，在25℃下测得的霍普勒黏度小于约14,000mPa.s。这些聚合物前体可作为可选取代的末端磷酸盐或H-膦酸酯与至少一个邻接烷基烯基羰酰氧基团的化合物之间反应的产物获得。聚合物前体可以与其他单体共聚，以产生诸如含磷聚氨酯等共聚物，例如用作阻燃剂、防腐剂、颜料分散剂和/或粘接剂。
• Resin composition for powder coating
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP0038635A1

  公开（公告）日：1981-10-28

  A resin composition for powder coating consists essentially of (A) 60 to 97% by weight of a polyester resin having an acid value of 15to 200 mgKOH/g and a softening pointof80to 150°C, and (B) 40 to 3% by weight of a glycidyl-containing acrylic polymer unmodified or modified with a monobasic acid, and provides cured film coatings having good surface characteristics and weatherability.

  粉末涂料用树脂组合物主要包括 (A) 60% 至 97% （以重量计）的聚酯树脂，其酸值为 15 至 200 mgKOH/g，软化点为 80 至 150°C，以及 (B) 40% 至 3% （按重量计）的含缩水甘油的丙烯酸聚合物，未经改性或经单盐基酸改性，可提供具有良好表面特性和耐候性的固化涂膜。
• Image-transmitting synthetic resin rod and process for producing the same
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP0108420A2

  公开（公告）日：1984-05-16

  An improved image-transmitting synthetic resin rod comprising a reaction product of an acrylic resin ① containing epoxy groups with a material ② having a refractive index 0.15 - 0.35 lower than that of said acrylic resin ①, and distributed in said rod so as to satisfy equation (1):wherein r is the radial distance from the center axis of the rod (0 ≦ r # ro), ro is the radius of the rod, nr is the refractive index at point r, n. is the refractive index at the center of the rod, g is the distribution constant of the refractive index, and h4 and h6 are high order coefficients, and a process for producing the same.

  一种改进的图像传输合成树脂棒，包括含有环氧基团的丙烯酸树脂①与折射率比所述丙烯酸树脂①低 0.15 - 0.35 的材料②的反应产物，并分布在所述棒中，以满足等式 (1)：其中 r 为从棒的中心轴开始的径向距离（0 ≦ r # ro）、 ro 是杆的半径、 nr 是 r 点的折射率、 n. 是棒中心的折射率、 g 是折射率的分布常数，以及 h4 和 h6 是高阶系数，以及产生高阶系数的工艺。
• Resin composition for use in powder paint
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP0242714A2

  公开（公告）日：1987-10-28

  A resin composition for use in a powder paint. The composition is either a composition (I) comprising (A) a polyester resin containing both carboxyl and hydroxyl groups, (B-1) a vinyl monomer containing both (beta- methyl)glycidyl and hydroxyl groups and (C) a blocked isocyanate in a weight ratio of 60-96:3-40:1-20, or a composition (II) comprising (A) a polyester resin containing both carboxyl and hydroxyl groups, (B-2) a (beta- methyl)glycidyl group-containing vinyl polymer, (B-3) a hydroxyl group-containng vinyl polymer, and (C) a blocked isocyanate in a weight ratio of 60-96:3-40:1-20.

  一种用于粉末涂料的树脂组合物。该组合物是一种组合物 (I)，包括 (A) 含有羧基和羟基的聚酯树脂、(B-1) 含有(β-甲基)缩水甘油基和羟基的乙烯基单体和 (C) 嵌段异氰酸酯，重量比为 60-96:3-40：1-20，或组合物(II)，包括(A)含有羧基和羟基的聚酯树脂、(B-2)含有(β-甲基)缩水甘油基的乙烯基聚合物、(B-3)含有羟基的乙烯基聚合物和(C)重量比为 60-96:3-40:1-20 的封端异氰酸酯。