1-chlorodec-1-ene

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1-chlorodec-1-ene
• 英文别名: 1-chloro-1-decene
• 化学式: C₁₀H₁₉Cl
• 分子量: 174.714
• InChiKey: FBECTVVCBRAZRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-chlorodec-1-ene 在 bis(1,5-cyclooctadiene)nickel (0) 、 sodium iodide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以60%的产率得到1-iodo-1-decene
  参考文献：
  名称：

  Procedures for the Nickel-Catalyzed Conversion of Olefinic and Cycloolefinic Chlorides Into Iodides

  摘要：

  A number of olefinic and cycloolefinic chlorides have been converted into the corresponding iodides by treatment with an excess of sodium iodide in dimethylformamide in the presence of bis(1,5-cyclooctadienyl)nickel or a mixture of nickel bromide and zinc powder.

  DOI：

  10.1080/00397919408011726
• 作为产物：
  描述：

  1-碘壬烷 在 六甲基磷酰三胺 、 对苯二酚 、 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 xylene 为溶剂， 生成 1-chlorodec-1-ene
  参考文献：
  名称：

  氯甲基苯基亚砜的烷基化和热解：乙烯基氯的简单合成

  摘要：

  DOI：

  10.1016/s0040-4039(01)86017-2

文献信息

• Iron Thiolate Complexes: Efficient Catalysts for Coupling Alkenyl Halides with Alkyl Grignard Reagents
  作者：Gérard Cahiez、Olivier Gager、Julien Buendia、Cindy Patinote

  DOI：10.1002/chem.201200184

  日期：2012.5.7

  Ironing out the kinks: Efficient new catalytic systems based on iron thiolates are described for the iron‐catalyzed cross‐coupling of alkyl Grignard reagents with alkenyl halides (see scheme). The reaction is highly chemo‐ and stereoselective. With this new procedure, the use of N‐methylpyrrolidone as a co‐solvent is no longer required.

  解决问题：描述了基于硫醇铁的高效新型催化体系，用于烷基格氏试剂与链烯基卤化物的铁催化交叉偶联（参见方案）。该反应是高度化学和立体选择性的。通过此新程序，不再需要使用N-甲基吡咯烷酮作为助溶剂。
• [EN] METATHESIS CATALYSTS AND METHODS THEREOF<br/>[FR] CATALYSEURS DE MÉTATHÈSE ET PROCÉDÉS ASSOCIÉS
  申请人：MASSACHUSETTS INST TECHNOLOGY

  公开号：WO2016073750A1

  公开（公告）日：2016-05-12

  The present application provides, among other things, compounds and methods for metathesis reactions. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and/or stereoselectivity. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and Z-selectivity. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and E-selectivity. In some embodiments, provided technologies are particularly useful for preparing alkenyl fluorides. In some embodiments, a provided compound useful for metathesis reactions has the structure of formula II-a. In some embodiments, a provided compound useful for metathesis reactions has the structure of formula II-b.

  本申请提供了化合物和用于交换反应的方法，其中包括用于制备烯烃卤化物的具有区域选择性和/或立体选择性的方法。在某些实施例中，本公开提供了用于具有区域选择性和Z-选择性的烯烃卤化物的制备方法。在某些实施例中，本公开提供了用于具有区域选择性和E-选择性的烯烃卤化物的制备方法。在某些实施例中，提供的技术特别适用于制备烯烃氟化物。在某些实施例中，用于交换反应的提供的化合物具有II-a式的结构。在某些实施例中，用于交换反应的提供的化合物具有II-b式的结构。
• Liquid-crystalline polymer composition
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：US05271866A1

  公开（公告）日：1993-12-21

  A liquid-crystalline polymer composition comprising a ferroelectric liquid-crystalline polymer and a low molecular weight liquid-crystalline compound which exhibits smectic C phase or chiral smectic C phase. Such liquid-crystalline polymer compositions have not only excellent moldabilities such as ease of orientation, but also exhibit chiral smectic C phase at wide temperature range within room temperatures and exhibit high speed response to changes of external fields and high contrast ratios when they are used for optical display elements.

  一种液晶聚合物组合物，包括铁电液晶聚合物和低分子量液晶化合物，该低分子量液晶化合物表现出smectic C相或手性smectic C相。这种液晶聚合物组合物不仅具有出色的成型性，如方向易，而且在室温范围内表现出手性smectic C相，并且当它们用于光学显示元件时，对外部场的变化具有高速响应和高对比度比。
• Baudin, J. B.; Hareau, G.; Julia, S. A., Bulletin de la Societe Chimique de France, 1993, vol. 130, p. 856 - 878
  作者：Baudin, J. B.、Hareau, G.、Julia, S. A.、Lorne, R.、Ruel, O.

  DOI：——

  日期：——
• Exact and approximate sum representations for the Dirichlet process
  作者：Hemant Ishwaran、Mahmoud Zarepour

  DOI：10.2307/3315951

  日期：2002.6

  AbstractThe Dirichlet process can be regarded as a random probability measure for which the authors examine various sum representations. They consider in particular the gamma process construction of Ferguson (1973) and the “stick‐breaking” construction of Sethuraman (1994). They propose a Dirichlet finite sum representation that strongly approximates the Dirichlet process. They assess the accuracy of this approximation and characterize the posterior that this new prior leads to in the context of Bayesian nonpara‐metric hierarchical models.