1,5-diphenyl-4-pentene-1,3-dione | 6271-22-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,5-diphenyl-4-pentene-1,3-dione
• 英文别名: (benzoyl)(cinnamoyl)methane；1,5-Diphenyl-4-penten-1,3-dion；Cinnamoyl-benzoyl-methan；1,5-diphenylpent-4-ene-1,3-dione
• CAS: 6271-22-3
• 化学式: C₁₇H₁₄O₂
• 分子量: 250.297
• InChiKey: MLNVBUQTXITYPT-UHFFFAOYSA-N

物化性质

• 熔点：
  108.5-109.5 °C
• 沸点：
  429.4±28.0 °C(Predicted)
• 密度：
  1.137±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,5-diphenyl-4-pentene-1,3-dione 在 乙醇 、 盐酸羟胺 作用下， 生成 3-phenyl-5-styrylisoxazole
  参考文献：
  名称：

  Ryan; Dunlea, Chemisches Zentralblatt, 1913, vol. 84, # II, p. 2040

  摘要：

  DOI：
• 作为产物：
  描述：

  二苄叉丙酮 在 氢氧化钾 、 乙醇 、 sodium acetate 作用下， 生成 1,5-diphenyl-4-pentene-1,3-dione
  参考文献：
  名称：

  THE DREAM'S NAVEL BETWEEN CHAOS AND THOUGHT

  摘要：

  The authors begin by drawing attention to the problem of the transition from the biological to the psychic, noting that Freud himself, with his background in the neurosciences, grappled with it throughout his career. Certain recent paradigms more commonly applied to the natural sciences, such as in particular chaos and complexity theory, can in their view prove fruitful in psychoanalysis too, and it is shown how these notions are inherent in some of Freud's conceptions. The unconscious is stated to operate like a neural network, performing the kind of parallel processing used in the computing of highly complex situations, whereas the conscious mind is sequential. Dreams, in the authors' opinion, are organisers of the mind, imparting order to the turbulence of the underlying wishes and unconscious fantasies and structuring them through the dream work. Through dreams, the structured linearity of conscious thought can emerge out of the non-linear chaos of the drives. The dream's navel can be seen as the chaotic link, or interface, between the unconscious wish, which constitutes an attractor, and the conscious thought. The attractor may be visualised as having an hourglass or clepsydra shape, the narrow section being the dream's navel, and, being the same at any scale of observation, has the property of fractality.

  DOI：

  10.1516/0020757011600812

文献信息

• Catalytic Asymmetric Conjugate Arylation of γ,δ-Unsaturated β-Dicarbonyl Compounds
  作者：Jian Yao、Long Yin、Yue Shen、Tao Lu、Tamio Hayashi、Xiaowei Dou

  DOI：10.1021/acs.orglett.8b03021

  日期：2018.11.2

  asymmetric conjugate addition to γ,δ-unsaturated β-dicarbonyl compounds was developed. With a chiral diene–rhodium(I) μ-chloro dimer as the catalyst in toluene/H2O, asymmetric conjugate arylation of γ,δ-unsaturated β-dicarbonyl compounds with arylboronic acids proceeded in high efficiency with excellent enantioselectivities. The generated β-dicarbonyl products are versatile chiral synthons, which can

  研发了向γ，δ-不饱和β-二羰基化合物中的第一个催化不对称共轭加成物。用手性二烯-铑（I）μ-氯二聚体作为甲苯/ H 2 O的催化剂，γ，δ-不饱和β-二羰基化合物与芳基硼酸的不对称共轭芳基化反应高效进行，具有出色的对映选择性。生成的β-二羰基产物是通用的手性合成子，可以容易地转化为多种重要的手性结构。
• 基于两个不同第一配体的铕配合物红光材料 及制备方法
  申请人：广州工程技术职业学院

  公开号：CN108586505B

  公开（公告）日：2020-12-04

  本发明属于发光材料技术领域，公开了一种基于两个不同第一配体的铕配合物红光材料及制备方法，本发明合成了两种新的β‑二酮配体并用这两种新配体作为第一配体，邻菲啰啉作为第二配体合成了铕稀土配合物，在技术上突破了传统的β‑二酮稀土铕配合物的结构，为发展新型性能优良的稀土铕配合物开拓了新的途径。
• 一种铕配合物、其配体及铕配合物掺杂的聚丙烯发光材料
  申请人：广州工程技术职业学院

  公开号：CN110407682A

  公开（公告）日：2019-11-05

  本发明公开了一种铕配合物及铕配合物掺杂的聚丙烯发光材料。所述的铕配合物及其配体的结构如式Ⅱ和式Ⅰ所示。所述铕配合物的长共轭配体的制备方法为：将乙醇钠、四氢呋喃、苯乙酮以及肉桂酸混合后在惰性气体保护下进行回流反应，反应完毕后分离纯化产物即得铕配合物的长共轭配体。所述的铕配合物的制备方法为：将铕配合物的长共轭配体以及硝酸铕加入到有机溶剂中进行加热搅拌溶解，然后滴加邻菲罗啉溶液，滴加完毕后进行加热回流反应，反应结束后分离纯化产物即得铕配合物。采用上述铕配合物掺杂到聚丙烯中得到的铕配合物掺杂的聚丙烯发光材料，既具有小分子铕配合物的发光特性，也具有聚丙烯高分子材料的良好的力学性能。
• Nucleophilic acylation of α-haloketones with aldehydes: an umpolung strategy for the synthesis of 1,3-diketones
  作者：Santosh Singh、Pankaj Singh、Vijai K. Rai、Ritu Kapoor、Lal Dhar S. Yadav

  DOI：10.1016/j.tetlet.2010.10.175

  日期：2011.1

  The first example of N-heterocyclic carbene (NHC)-promoted intermolecular acylation of alpha-haloketones with aldehydes and alpha,beta-unsaturated aldehydes (enals) is reported. The protocol involves carbonyl umpolung reactivity of aldehydes and enals in which the carbonyl carbon attacks nucleophilically on electrophilic terminal of alpha-haloketones to afford 1,3-diketones and alpha,beta-unsaturated 1,3-diketones, respectively. Short reaction time, ambient temperature, operational simplicity, and high yields are the salient features of the present procedure. (C) 2010 Elsevier Ltd. All rights reserved.
• Giua, Gazzetta Chimica Italiana, 1919, vol. 49 II, p. 171
  作者：Giua

  DOI：——

  日期：——