Decaethylene glycol methyl vinyl ether | 1451212-92-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Decaethylene glycol methyl vinyl ether
• 英文别名: 1-[2-[2-[2-[2-[2-[2-[2-[2-(2-ethenoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]-2-methoxyethane
• CAS: 1451212-92-2
• 化学式: C₂₃H₄₆O₁₁
• 分子量: 498.612
• InChiKey: UVPLTAFRFJIULD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.7
• 重原子数：
  34
• 可旋转键数：
  31
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  102
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  十甘醇单甲醚 、 乙烯基乙醚 在 1,10-菲罗啉 、 palladium diacetate 作用下， 以 二氯甲烷 为溶剂， 以71%的产率得到Decaethylene glycol methyl vinyl ether
  参考文献：
  名称：

  新型低聚环氧乙烷侧链交替氟化共聚物的合成与表征

  摘要：

  介绍了新型聚（CTFE- g- oligoEO）接枝共聚物[三氟氯乙烯（CTFE）和环氧乙烷（EO）]的合成和表征。首先，通过用钯配合物催化的ω-羟基低聚（EO）与乙基乙烯基醚的醚交换反应，制备了带有低聚（EO）的乙烯基醚单体，产率为70-84％。由此获得了两种不同分子量的乙烯基醚（三个和10个EO单元）。然后，上述乙烯基醚与CTFE的自由基共聚导致交替生成带有低聚（OE）侧链的聚（CTFE- alt- VE）共聚物，并具有令人满意的收率（65％）。这些原始的聚（CTFE- g- oligoEO）接枝共聚物的特征是1 H，19 F和1313 C NMR光谱。它们的分子量达到19,000 g mol -1，并且在玻璃化转变温度介于-42和-36°C的范围内研究了它们的热性能。他们在空气中的热重分析显示分解温度为270°C，失重10％（T d，10％）。这些新型共聚物作为锂离子电池中的聚合物电

  DOI：

  10.1002/pola.26463

文献信息

• ELECTROLYTE MATERIAL, AND BATTERY MATERIAL AND SECONDARY BATTERY USING SAID ELECTROLYTE MATERIAL
  申请人：Hashimoto Masashi

  公开号：US20120244427A1

  公开（公告）日：2012-09-27

  The present invention provides a stable electrolyte material that provides high safety, exhibits favorable ionic conductivity not only at room temperature but also in the low temperature range at or below room temperature, has excellent reduction resistance, and can be suitably used as a material of a lithium ion cell. The electrolyte material includes, as essential components, a specific polymer having an ether bond in a side chain thereof, and a specific electrolyte salt.

  本发明提供了一种稳定的电解质材料，具有高安全性，在室温下和低于室温的低温范围内表现出良好的离子导电性，具有优异的还原电阻，可适当用作锂离子电池的材料。电解质材料包括具有侧链中的醚键的特定聚合物和特定电解质盐作为必要组分。
• Electrolyte material, and battery material and secondary battery using said electrolyte material
  申请人：Hashimoto Masashi

  公开号：US09065150B2

  公开（公告）日：2015-06-23

  The present invention provides a stable electrolyte material that provides high safety, exhibits favorable ionic conductivity not only at room temperature but also in the low temperature range at or below room temperature, has excellent reduction resistance, and can be suitably used as a material of a lithium ion cell. The electrolyte material includes, as essential components, a specific polymer having an ether bond in a side chain thereof, and a specific electrolyte salt.

  本发明提供了一种稳定的电解质材料，具有高安全性，在室温和低于室温的低温范围内表现出良好的离子导电性，具有优异的还原抗性，并可适当地用作锂离子电池的材料。该电解质材料包括具有侧链中醚键的特定聚合物和特定电解质盐作为必要组分。
• BIO-ELECTRODE COMPOSITION, BIO-ELECTRODE, METHOD FOR MANUFACTURING THE BIO-ELECTRODE, AND POLYMER COMPOUND
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20180223133A1

  公开（公告）日：2018-08-09

  The present invention provides a bio-electrode composition capable of forming a living body contact layer for a bio-electrode that is excellent in conductivity and biocompatibility, is light-weight, can be manufactured at low cost, and can control significant reduction in conductivity even though the bio-electrode is soaked in water or dried. The present invention is accomplished by a bio-electrode composition including an (A) ionic material and a (B) resin other than the component (A), in which the component (A) has both a repeating unit “a” of a sodium salt, a potassium salt, or an ammonium salt including a partial structure represented by the following general formula (1) and a repeating unit “b” having a silicon atom. —R 1 —SO 2 —N − —SO 2 —Rf 1 M + (1)
• US9065150B2
  申请人：——

  公开号：US9065150B2

  公开（公告）日：2015-06-23
• Synthesis and characterization of novel alternating fluorinated copolymers bearing oligo(ethylene oxide) side chains
  作者：Ali Alaaeddine、Andrew Hess、Frédéric Boschet、Harry Allcock、Bruno Ameduri

  DOI：10.1002/pola.26463

  日期：2013.2.15

  units) were thus obtained. Then, radical copolymerization of the above vinyl ethers with CTFE led to alternating poly(CTFE‐alt‐VE) copolymers that bore oligo(OE) side chains in satisfactory yields (65%). These original poly(CTFE‐g‐oligoEO) graft copolymers were characterized by 1H, 19F, and 13C NMR spectroscopy. Their molecular weights reached 19,000 g mol−1, and their thermal properties were investigated

  介绍了新型聚（CTFE- g- oligoEO）接枝共聚物[三氟氯乙烯（CTFE）和环氧乙烷（EO）]的合成和表征。首先，通过用钯配合物催化的ω-羟基低聚（EO）与乙基乙烯基醚的醚交换反应，制备了带有低聚（EO）的乙烯基醚单体，产率为70-84％。由此获得了两种不同分子量的乙烯基醚（三个和10个EO单元）。然后，上述乙烯基醚与CTFE的自由基共聚导致交替生成带有低聚（OE）侧链的聚（CTFE- alt- VE）共聚物，并具有令人满意的收率（65％）。这些原始的聚（CTFE- g- oligoEO）接枝共聚物的特征是1 H，19 F和1313 C NMR光谱。它们的分子量达到19,000 g mol -1，并且在玻璃化转变温度介于-42和-36°C的范围内研究了它们的热性能。他们在空气中的热重分析显示分解温度为270°C，失重10％（T d，10％）。这些新型共聚物作为锂离子电池中的聚合物电