3-ethyl-1-butyl-imidazolium; iodide | 65039-17-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 3-ethyl-1-butyl-imidazolium; iodide
• 英文别名: 3-Aethyl-1-butyl-imidazolium; Jodid；1-n-butyl-3-ethylimidazolium iodide；1-Ethyl-3-butyl-imidazolium-jodid；1-Butyl-3-ethylimidazol-1-ium;iodide
• CAS: 65039-17-0
• 化学式: C₉H₁₇N₂*I
• 分子量: 280.152
• InChiKey: IMUKNVHHESPWAO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.4
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  8.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-ethyl-1-butyl-imidazolium; iodide 生成 1-乙基咪唑 、 N-丁基咪唑 、 1-碘丁烷 、 碘乙烷
  参考文献：
  名称：

  v. Auwers; Mauss, Chemische Berichte, 1928, vol. 61, p. 2415,2416, 2417

  摘要：

  DOI：

文献信息

• Method for producing haloalkanes from alcohols
  申请人：Stegmann Viet

  公开号：US20070055084A1

  公开（公告）日：2007-03-08

  The invention relates to a process for preparing haloalkanes by reaction of alcohol with hydrogen halide, wherein the reaction of the alcohol with the hydrogen halide occurs in the presence of an ionic liquid at a temperature which is above 100° C. for at least part of the time and, at least at the time of the commencement of the reaction, the water content is not more than 25 mol % based on the amount of liquid, where the ionic liquid is not octyltrimethylammonium chloride.

  该发明涉及一种通过醇与氢卤化物反应制备卤代烷的方法，其中醇与氢卤化物的反应在存在离子液体的条件下进行，反应温度在100°C以上至少一部分时间，并且至少在反应开始时，水含量不超过液体总量的25摩尔％，其中所述离子液体不是辛基三甲基铵氯化物。
• HYDROCARBOXYLATION PROCESS
  申请人：Zoeller Joseph Robert

  公开号：US20070299280A1

  公开（公告）日：2007-12-27

  Disclosed is a hydrocarboxylation process for the production of carboxylic acid from olefins wherein an olefin, water, a Group VIII metal hydrocarboxylation catalyst, an onium salt compound are combined in a reaction zone and contacted with carbon monoxide under hydrocarboxylation conditions of pressure and temperature The process does not require or utilize the addition of a hydrogen halide or an alkyl halide exogenous or extraneous to the hydrocarboxylation process.

  揭示了一种从烯烃生产羧酸的羟基羧化过程，其中在反应区域中将烯烃、水、第VIII族金属羟基羧化催化剂和一个胞离子盐化合物结合，并在压力和温度的羟基羧化条件下与一氧化碳接触。该过程不需要或利用氢卤化物或烷基卤化物作为羟基羧化过程的外部添加物。
• Functionalized ionic liquids, and methods of use thereof
  申请人：——

  公开号：US20040035293A1

  公开（公告）日：2004-02-26

  One aspect of the present invention relates to ionic liquids comprising a pendant Bronsted-acidic group, e.g., a sulfonic acid group. Another aspect of the present invention relates to the use of an ionic liquid comprising a pendant Bronsted-acidic group to catalyze a Bronsted-acid-catalyzed chemical reaction. A third aspect of the present invention relates to ionic liquids comprising a pendant nucleophilic group, e.g., an amine. Still another aspect of the present invention relates to the use of an ionic liquid comprising a pendant nucleophilic group to catalyze a nucleophile-assisted chemical reaction. A fifth aspect of the present invention relates to the use of an ionic liquid comprising a pendant nucleophilic group to remove a gaseous impurity, e.g., carbon dioxide, from a gas, e.g., sour natural gas.

  本发明的一个方面涉及含有挂链Brønsted酸性基团的离子液体，例如磺酸基团。本发明的另一个方面涉及使用含有挂链Brønsted酸性基团的离子液体来催化Brønsted酸催化的化学反应。本发明的第三个方面涉及含有挂链亲核基团的离子液体，例如胺。本发明的另一个方面涉及使用含有挂链亲核基团的离子液体来催化亲核辅助的化学反应。本发明的第五个方面涉及使用含有挂链亲核基团的离子液体来去除气态杂质，例如二氧化碳，从气体中，例如酸性天然气。
• COMPOUNDS FOR USE IN ELECTROLYTE FOR SOLAR CELL, METHOD FOR PREPARING THE SAME, AND ELECTROLYTE AND SOLAR CELL HAVING THE SAME
  申请人：Lee Yu-Hui

  公开号：US20130056075A1

  公开（公告）日：2013-03-07

  Provided is a compound of formula (I): wherein A is C 2-3 alkylene; m is an integer ranging from 2 to 25; and n is an integer ranging from 3 to 10. An electrolyte for a dye-sensitized solar cell having the compound of formula (I) and/or a compound of formula (II) is further provided for increasing photoelectric conversion efficiency.

  提供的是化合物的公式(I)：其中A是C2-3烷基; m是一个范围在2到25之间的整数; n是一个范围在3到10之间的整数。进一步提供了一种用于增加光电转换效率的染料敏化太阳能电池的电解质，其中包含公式(I)和/或公式(II)的化合物。
• Functionalized Ionic Liquids, and Methods of Use Thereof
  申请人：Davis, JR. James Hillard

  公开号：US20100228035A1

  公开（公告）日：2010-09-09

  One aspect of the present invention relates to ionic liquids comprising a pendant Bronsted-acidic group, e.g., a sulfonic acid group. Another aspect of the present invention relates to the use of an ionic liquid comprising a pendant Bronsted-acidic group to catalyze a Bronsted-acid-catalyzed chemical reaction. A third aspect of the present invention relates to ionic liquids comprising a pendant nucleophilic group, e.g., an amine. Still another aspect of the present invention relates to the use of an ionic liquid comprising a pendant nucleophilic group to catalyze a nucleophile-assisted chemical reaction. A fifth aspect of the present invention relates to the use of an ionic liquid comprising a pendant nucleophilic group to remove a gaseous impurity, e.g., carbon dioxide, from a gas, e.g., sour natural gas.

  本发明的一个方面涉及离子液体，其中包含一个侧链布朗斯特酸性基团，例如磺酸基团。本发明的另一个方面涉及使用包含侧链布朗斯特酸性基团的离子液体来催化布朗斯特酸催化的化学反应。本发明的第三个方面涉及离子液体，其中包含一个侧链亲核基团，例如胺基团。本发明的另一个方面涉及使用包含侧链亲核基团的离子液体来催化亲核助剂化学反应。本发明的第五个方面涉及使用包含侧链亲核基团的离子液体从气体中去除气态杂质，例如二氧化碳，从酸性天然气中去除。