5-(isonicotinamido)isophthalic acid | 158520-85-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-(isonicotinamido)isophthalic acid
• 英文别名: 5-(pyridine-4-carbonylamino)benzene-1,3-dicarboxylic acid
• CAS: 158520-85-5
• 化学式: C₁₄H₁₀N₂O₅
• 分子量: 286.244
• InChiKey: POMFMMSRVMERFN-UHFFFAOYSA-N

物化性质

• 沸点：
  480.0±45.0 °C(Predicted)
• 密度：
  1.534±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  117
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  5-(isonicotinamido)isophthalic acid 在 bipyridine 、 NaOH 作用下， 以 水 为溶剂， 生成 (5-(isonicotinamido)isophthalate)copper(II)
  参考文献：
  名称：

  Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(ii) frameworks

  摘要：

  独特的四重互穿（10,3）-b铜（II）框架在单晶到单晶（SC-SC）过程中表现出可逆的脱水与复水，脱水后的材料可以再次以SC-SC的方式包裹CH3OH分子，并表现出对H2和CO2的选择性吸附。

  DOI：

  10.1039/c0cc04689b
• 作为产物：
  描述：

  异烟酸 在 氯化亚砜 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 生成 5-(isonicotinamido)isophthalic acid
  参考文献：
  名称：

  Self-assemblies formed by isonicotinic acid analogues axially coordinating with zinc porphyrin via pyridyl unit: synthesis and application in dye sensitized solar cells

  摘要：

  A novel zinc porphyrin ZnP bearing a 1,3,5-triazine-2,4-diamine unit has been designed and synthesized in good yields to construct axial-coordinated assemblies (denoted as ZnP-Ai, i = 1, 2, 3 and 4) with different isonicotinic acid analogues (assigned as Al, A2, A3 and A4) through zinc-to-ligand axial coordination approach. Then these assemblies were grafted onto TiO2 electrode surface to build dye sensitized solar cells. The performance of these cells also was examined. Photoelectrochemical measurements illustrate that all the assembly based cells have certain capabilities to export photocurrent. Especially, the ZnP-A2 assembly with a cyanoacrylic acid group based solar cell has the highest conversion efficiency of 0.81% with J(SC) of 3.0 mA/cm(2), a V-OC of 0.38 V, and a FF of 0.71 among these assembly based solar cells. Additionally, the UV-vis absorption, fluorescence spectra, density functional theory (OFT) calculations, transmission electron microscopy (TEM) and electrochemical impedance spectra (EIS) were performed to determine the photoelectric behavior as well as morphological structure on the TiO2 surface modified by these assemblies. (C) 2016 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2016.03.054

文献信息

• Hydrothermal syntheses, crystal structures and properties of two cobalt(II) complexes constructed from 5-(isonicotinamido)isophthalic acid
  作者：Man-Sheng Chen、Yi-Fang Deng、Chun-Hua Zhang、Jin-Sheng Xu、Zheng-Ji Yi、Fu-Pei Liang

  DOI：10.1007/s11243-014-9874-1

  日期：2014.11

  Two Co(II) complexes, [Co(INAIP)(dib)]·4H2O and [Co(INAIP)(phen)(H2O)]·H2O have been synthesized by the reaction of 5-(isonicotinamido)isophthalic acid (H2INAIP) and CoSO4·7H2O, as well as N-donor ligands, namely 1,4-di(1-imidazolyl)benzene (dib) and 1,10-phenanthroline (phen) under hydrothermal conditions. Single-crystal X-ray diffraction analysis indicates that [Co(INAIP)(dib)]·4H2O has a two-dimensional (2D) double-layer network structure with a (4, 4) topology, while [Co(INAIP)(phen)(H2O)]·H2O displays a one-dimensional chain structure, extending to a 2D net through the π–π interactions. In addition, the photoluminescence and degradation of methyl orange in a Fenton-like process using the complexes as catalysts were investigated.

  通过水热条件下5-(异烟酰胺基)间苯二甲酸(H2INAIP)和CoSO4·7H2O以及N供体配体(即1,4-双(1-咪唑基)苯(dib)和1,10-菲罗啉(phen))的反应，合成了两种Co(II)配合物[Co(INAIP)(dib)]·4H2O和[Co(INAIP)(phen)(H2O)]·H2O。单晶X射线衍射分析表明，[Co(INAIP)(dib)]·4H2O具有(4, 4)拓扑结构的二维双层网络结构，而[Co(INAIP)(phen)(H2O)]·H2O显示出通过π–π相互作用延伸成二维网的一维链状结构。此外，研究了将这些配合物作为催化剂在类芬顿过程中对甲基橙的光致发光和降解的影响。
• 一种5-异烟酰胺吡啶基异钛酸多孔铜配合物及 其制备方法和应用
  申请人：衡阳师范学院

  公开号：CN104072525B

  公开（公告）日：2016-02-03

  本发明公开了一种5-异烟酰胺吡啶基异钛酸多孔铜配合物及其制备方法和应用，该多孔铜配合物具有(3，6)双节点三维拓扑网络结构，化学表达式为[Cu(L)]·DMAc·H2O(L为5-异烟酰胺吡啶基异钛酸根离子)；制备方法是将5-异烟酰胺吡啶基异钛酸和铜盐通过溶剂热反应制备得到，经洗涤，烘干后，即得到结构稳定的新型多孔铜配合物；该制备方法过程简单、操作方便，产率高；制备得到的5-异烟酰胺吡啶基异钛酸多孔铜配合物对苯甲醛和丙二腈之间的Knovevenagel缩合反应具有催化作用，且催化选择性好、催化活性高，催化剂可以有效回收并重复使用。
• WATER CAPTURE METHODS, DEVICES, AND COMPOUNDS
  申请人：University of Limerick

  公开号：US20200030737A1

  公开（公告）日：2020-01-30

  A method of capturing water from a gaseous composition comprising water vapour (e.g., air), the method comprising: (a) providing a metal-organic material; and (b) contacting the metal-organic material with water and/or water vapour; wherein upon contact with water and/or water vapour the material switches from a first state to a second state wherein the second state is able to retain a higher amount of water than the first state.

  一种从含水蒸气（例如空气）中捕获水的方法，包括以下步骤：(a) 提供金属有机材料；和(b) 将金属有机材料与水和/或水蒸气接触；其中，在接触水和/或水蒸气时，该材料从第一状态切换到第二状态，第二状态能够比第一状态更多地保留水。
• Structural Transformation and Spatial Defect Formation of a Co(II) MOF Triggered by Varied Metal-Center Coordination Configuration
  作者：Xiao-Qing Meng、Xiao-Ting Liu、Na Li、Jia Zhao、Ze Chang、Jin-Yu Zheng、Xian-He Bu

  DOI：10.1021/acs.inorgchem.0c00845

  日期：2020.7.6

  structural transformation to give a new crystalline phase with larger pore dimension. Moreover, the new phase features a mesoporous structure originating from the spatial defect that formed with the transformation process, which indicates that the modulation of dynamic behavior of the MOF could be a potential method for the engineering of a spatial defect. In addition, the gas sorption investigation results

  尽管金属-有机骨架（MOF）的动态行为和缺陷具有潜在的吸引力应用，但实现这些功能仍是MOF研究领域中具有挑战性的目标。在此，我们报道了Co（II）MOF，即[Co 3（L）2（4-PTZ）2（H 2 O）2 ] n ·溶剂（H 2 L = 5-（异烟酰胺基）间苯二甲酸4 -PTZ = 5-（4-吡啶基）-1 H-四唑），具有动态的结构转变行为。通过去除配位的水分子来改变金属中心的配位构型，多孔化合物可以进行结构转变，以产生具有较大孔径的新晶相。此外，新相的特征在于介孔结构，该介孔结构源于通过转换过程形成的空间缺陷，这表明MOF的动态行为的调制可能是工程化空间缺陷的潜在方法。此外，气体吸附研究结果表明，新相具有更高的CO 2 / N 2，CO 2 / CH 4和C 2 H选择性。2 / C 2 H 4系统与原始相相比，表明空间缺陷工程对MOF气体吸附性能的调节潜力。
• Two 2D multiresponsive luminescence coordination polymers for selective sensing of Fe³⁺, Cr^VI anions and TNP in aqueous medium
  作者：Ai-Mei Zhou、Han Wei、Wei Gao、Jie-Ping Liu、Xiu-Mei Zhang

  DOI：10.1039/c9ce01045a

  日期：——

  Two luminescence coordination polymers (CPs) formulated as [Zn(L)(H2O)2]·H2O}n (1) and [Cd(L)(H2O)2]·4H2O}n (2) are successfully prepared by solvothermal reactions between the corresponding metal(II) ions and 5-(4-pyridylamino)isophthalic acid (H2L). Crystallographic studies reveal that 1 and 2 exhibit similar 2D honeycomb layer networks, but have different numbers of lattice water molecules. The

  配制为[Zn（L）（H 2 O）2 ]·H 2 O} n（1）和[Cd（L）（H 2 O）2 ]·4H 2 O}的两种发光配位聚合物（CPs）通过相应的金属（II）离子与5-（4-吡啶基氨基）间苯二甲酸（H 2 L）之间的溶剂热反应成功地制备了n（2）。晶体学研究表明1和2表现出相似的2D蜂窝层网络，但具有不同数量的晶格水分子。这些层通过氢键连接以产生3D超分子骨架。CP 1和2具有配位的水分子和未配位的氧原子以及富含电子的酰胺基，这些基团易于识别各种分析物。此外，它们在pH范围为3至12的水性体系中显示出相当高的稳定性。发光传感实验表明，它们可以被视为检测Fe 3+离子，Cr VI阴离子（CrO 4 2-和Cr 2）的高灵敏度传感器。O 7 2−）和2,4,6-三硝基苯酚（TNP）通过发光淬灭。另外，已经详细研究了CP 1和CP 2对Fe 3+离子，Cr VI阴离子和TNP的发光响应的机理。此外，CP