trinol acrylate | 3217-37-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: trinol acrylate
• 英文别名: 3-bromo-2,2-bis(bromomethyl)propyl acrylate；3-Bromo-2,2-bis(bromomethyl)propyl prop-2-enoate；[3-bromo-2,2-bis(bromomethyl)propyl] prop-2-enoate
• CAS: 3217-37-6
• 化学式: C₈H₁₁Br₃O₂
• 分子量: 378.886
• InChiKey: QKESMFKTVDCTOI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2916129000

反应信息

• 作为产物：
  描述：

  三溴新戊醇 、 丙烯酸 在 硫酸 sulfur 作用下， 以 环己烷 为溶剂， 以95%的产率得到trinol acrylate
  参考文献：
  名称：

  [EN] PROCESS FOR THE PREPARATION OF PURE ACRYLATE ESTERS
  [FR] PROCÉDÉ D'ÉLABORATION D'ESTERS D'ACRYLATES À L'ÉTAT PUR

  摘要：

  本发明提供了一种制造三醇丙烯酸酯、二醇丙烯酸酯和二醇二丙烯酸酯的工艺，避免了酯类的不良热聚合，并提供了用于制备塑料透镜的高纯度单体。

  公开号：

  WO2011045780A1

文献信息

• Halogen-containing lens material
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0162550A2

  公开（公告）日：1985-11-27

  A lens material having a refractive index n20D of at least 1.57 and an Abbe's number v of at least 30, comprising: a copolymer comprising (I) 10 to 85% by weight of a halogen-containing monomer represented by the following formula (1), (II) 15to 90% by weight of a halogen-containing monomer represented by the following formula (2), and (III) 0 to 20% by weight of a monomer copolymerizable with the above mentioned monomers, the composition of the copolymer being based on the total quantity of the monomers (I), (II), and (III): wherein: D represents in which n represents an integer selected from the group consisting of 0, 1 and 2; each R' represents hydrogen or a methyl group; Y represents CHOH; and r represents 0 or 1; each of X' and X2 represents, independently from each other, a methyl group in which one through three of the hydrogen atoms are substituted by a member selected from the group consisting of bromine, iodine and a hydroxyl group (OH group), with the proviso that the number of substitution of the OH group is only one; X3 represents a methyl group in which one through three of the hydrogen atoms are substituted by a member selected from the group consisting of bromine, iodine and D, with the proviso that the number of substitution of D is only one; wherein at least one of X', X2, and X3 contains at least one bromine or iodine; wherein: each R2 represents hydrogen or a methyl group: p represents an integer selected from the group consisting of 0. 1. 2. and 3; X4 represents bromine or iodine; and q represents an integer selected from the group consisting of 1, 2.3.4. and 5. An example of the copolymer is 1-methacryloxy-2,2-di (bromomethyl)-3-bromopropane. methacryloxypolyethyoxy-2.4.6- tribromobenzene styrene divinylbenzene having a n20D of 1.596 and a v of 35.3.

  一种透镜材料，其折射率 n20D 至少为 1.57 和阿贝数 v 至少为 30 的镜片材料，包括：共聚物，其中(I) 10 至 85% （按重量计）由下式(1)代表的含卤素单体，(II) 15 至 90% （按重量计）由下式(2)代表的含卤素单体，和(III) 0 至 20% （按重量计）可与上述单体共聚的单体，共聚物的组成基于单体(I)、(II)和(III)的总量： 其中D 代表 其中 n 代表选自 0、1 和 2 所组成的组的整数；每个 R'代表氢或甲基；Y 代表 CHOH；r 代表 0 或 1；X'和 X2 各自独立地代表一个甲基，其中一至三个氢原子被选自溴、碘和羟基（OH 基）所组成的组的成员取代，但羟基的取代数仅为一个；X3 代表甲基，其中一至三个氢原子被选自溴、碘和 D 组成的组的成员取代，但 D 的取代数仅为一个；其中 X'、X2 和 X3 中至少有一个含有至少一个溴或碘； 其中：每个 R2 代表氢或甲基：p 代表选自 0、1、2 和 3 的整数；X4 代表溴或碘；以及 q 代表选自 1、2.3.4 和 5 的整数。 共聚物的一个例子是 1-甲基丙烯酰氧基-2,2-二（溴甲基）-3-溴丙烷。 甲基丙烯酰氧基聚乙氧基-2.4.6-三溴苯苯乙烯二乙烯基苯，其 n20D 为 1.596，v 为 35.3。
• PROCESS FOR THE PREPARATION OF PURE ACRYLATE ESTERS
  申请人：Bromine Compounds Ltd.

  公开号：EP2488480A1

  公开（公告）日：2012-08-22
• FLAME RETARDANT RADIATION CURABLE COMPOSITIONS
  申请人：Allnex Belgium S.A.

  公开号：EP2864117B1

  公开（公告）日：2018-04-11
• ADDITIVE MANUFACTURING OF RADIOLOGICAL PHANTOMS
  申请人：Stratasys Ltd.

  公开号：EP3905956A1

  公开（公告）日：2021-11-10
• LITHIUM SECONDARY BATTERY
  申请人：Iwayasu Norio

  公开号：US20120142880A1

  公开（公告）日：2012-06-07

  In a lithium secondary battery, an overcharge inhibitor is used which includes polymerizable compounds or a polymer, or both as an active component, the polymerizable compounds including a first polymerizable compound having an aromatic functional group and a polymerizable functional group, and a second polymerizable compound having a halogen-containing functional group and a polymerizable functional group, and the polymer including a polymer having the halogen-containing functional group, the aromatic functional group, and residues of the polymerizable functional groups. The present invention allows the lithium secondary battery to form a radical-trapping polymer layer on the cathode upon overcharge.