hexahydro-1H-indene-1,3(2H)-dione | 16385-56-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: hexahydro-1H-indene-1,3(2H)-dione
• 英文别名: Hexahydro-indan-1,3-dion；Hexahydro-1,3-indandione；3a,4,5,6,7,7a-hexahydroindene-1,3-dione
• CAS: 16385-56-1
• 化学式: C₉H₁₂O₂
• 分子量: 152.193
• InChiKey: ZNPBIUPPEFUWIT-UHFFFAOYSA-N

物化性质

• 熔点：
  86-86.5 °C
• 沸点：
  290.5±13.0 °C(Predicted)
• 密度：
  1.138±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  hexahydro-1H-indene-1,3(2H)-dione 在 吡啶 、 碘 、 magnesium 作用下， 以 乙醚 、 甲苯 为溶剂， 反应 5.58h， 生成
  参考文献：
  名称：

  由六氢-1H-茚-1,3(2H)-二酮合成的光刻胶树脂单体及其合成方法

  摘要：

  本发明公开了一种由六氢‑1H‑茚‑1,3(2H)‑二酮合成的光刻胶树脂单体及其合成方法，属于化学合成和光刻技术领域。该光刻胶树脂单体的结构通式为式I：式I中，R1为饱和烷烃或者环烷烃，R2为氢或者甲基，其合成方法包括以下步骤：在惰性气体保护下，将六氢‑1H‑茚‑1,3(2H)‑二酮与烷基格氏试剂或者环烷基格氏试剂进行格氏反应，格氏反应结束后加水淬灭，并经后处理纯化，得到中间体；将上述中间体与丙烯酰氯或者甲基丙烯酰氯进行酯化反应，酯化反应结束后，经后处理纯化，得到所述的树脂单体。本发明提供的树脂单体为可降解型树脂单体，含该树脂单体的聚合物树脂具有更好的耐刻蚀性能且能够够提高光刻胶光刻图案的分辨率。

  公开号：

  CN111138287A

文献信息

• Achieving Record External Quantum Efficiency of 11.5 % in Solution‐Processable Deep‐Blue Organic Light‐Emitting Diodes Utilizing Hot Exciton Mechanism
  作者：Wenhui Wang、Jinkun Bian、Kaijin Chen、Chuying Li、Yubo Long、Haitao Huang、Long Jiang、Juan Zhao、Siwei Liu、Zhenguo Chi、Jiarui Xu、Yi Zhang

  DOI：10.1002/anie.202318782

  日期：2024.7

  An ingenious strategy is for the first time proposed to develop solution-processable deep-blue HLCT emitters by attaching rigid imide aliphatic rings onto the HLCT emitting core. With outstanding characteristics of these emitters, the unprecedented OLED performances with a record-breaking efficiency of 11.5 % and high colour purity are achieved, showing competitive superiority for ultrahigh-definition

  首次提出了一种巧妙的策略，通过将刚性酰亚胺脂肪族环附着到 HLCT 发射核上来开发可溶液加工的深蓝色 HLCT 发射器。凭借这些发射器的出色特性，OLED 实现了前所未有的性能，破纪录的 11.5% 效率和高色纯度，显示出超高清显示器的竞争优势。
• Primer composition for high temperature belts
  申请人：Chen Jiann-Hsing

  公开号：US20070026225A1

  公开（公告）日：2007-02-01

  A fuser belt comprising in order a substrate comprising a high temperature thermoset polymer, an epoxy primer layer comprising an epoxy resin having the following structure: where R 1 and R 2 are each independently H or an alkyl group containing 1 to about 4 carbon atoms, and R 3 and R 4 are each independently H, F, or an alkyl group containing 1 to about 4 carbon atoms, Z is a carbonyl cross-linking group, and x is an integer from 1 to about 10 and said epoxy priming layer also comprising an anhydride crosslinking agent cyclic mono anhydride or dianhydride having the following structure: and mixture thereof where R is an alkyl group containing 6 to about 8 carbon atoms and a low surface energy polymeric release coating.
• Epoxy primer layer for fuser belts
  申请人：Chen Jiann-Hsing

  公开号：US20070026226A1

  公开（公告）日：2007-02-01

  A fuser belt comprising in order a substrate comprising a polyimide substrate, an epoxy primer layer comprising an epoxy resin having the following structure: where R 1 and R 2 are each independently H or an alkyl group containing 1 to about 4 carbon atoms, and R 3 and R 4 are each independently H, F, or an alkyl group containing 1 to about 4 carbon atoms, Z is a carbonyl cross-linking group, and x is an integer from 1 to about 10 and said epoxy priming layer also comprising an anhydride crosslinking agent cyclic mono anhydride or dianhydride having the following structure: and mixture thereof where R is an alkyl group containing 6 to about 8 carbon atoms and a toner release layer comprising a silsesquioxane.
• TOCOPHEROL-MODIFIED THERAPEUTIC DRUG COMPOUND FORMULATIONS
  申请人：Zhang Yuehua

  公开号：US20070207196A1

  公开（公告）日：2007-09-06

  Tocopherol-modified therapeutic drug compounds; emulsion, microemulsion, and micelle formulations that include the compounds; methods for making the compounds and formulations; methods for administering the compounds and formulations; and methods for treating conditions using the compounds and formulations.
• Optoelectronic device
  申请人：Haitko Deborah Ann

  公开号：US20080160317A1

  公开（公告）日：2008-07-03

  The present invention provides an optoelectronic device comprising a light emitting semiconductor and an encapsulant. The encapsulant is made from an encapsulant formulation comprising a silicone epoxy and a curing agent. The present invention also provides a method of preparing such optoelectronic device.